• Title/Summary/Keyword: SrTiO3

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Reliability Evaluation of the Partial Discharge Measuring Sensor for Hydro Generator (대용량 수차발전기 부분방전 검출용 센서의 신뢰성 평가)

  • Byun, Doo-Gyoon;Hong, Jin-Woong
    • Journal of the Korean Society of Safety
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    • v.21 no.5 s.77
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    • pp.40-45
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    • 2006
  • In the operation of large capacity hydro generators, it's a very important thing that to minimize several kind of electrical trouble and accident. In order to overcome these problems, the on-line and off-line partial discharge (PD) measuring method has become an important one. Nowadays, epoxy mica coupler(EMC) has been the most widely used sensors for on-line PD detection in rotating machines. This time, we have made a ceramic coupling sensor using $SrTiO_{3}$, because at present, most of sensors has high cost and difficult procedure to making. This paper deals with the electrical characteristics of a ceramic coupling sensor, which has been made to continuously measure PD activity during the operation condition for 13kV class hydro generator. And we have performed the evaluation of sensor life and reliability based on the characteristic testing. The experimental results confirm that the sensor has satisfied at electrical required performance and output characteristic for simulated input signal.

Study of Dispersibility and Dielectric Properties in $SrTiO_3$/COP Composites as the kind/content of Dispersants (분산제의 종류와 함량에 따른 $SrTiO_3$/사이클로올레핀폴리머 복합재료의 분산성 및 유전특성에 대한 연구)

  • Kim, Jun-Young;Lee, Jin-Won;Yoo, Myong-Jae;Lee, Woo-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.261-262
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    • 2008
  • 분산제의 종류와 함량이 무기물-유기물 복합재료의 레올로지 특성 및 유전특성에 미치는 영향에 대하여 고찰하였다. 먼저 Multiple light scattering 방법을 통하여 용액의 입자 이동속도와 용액의 맑은층의 두께변화를 살펴보았으며 이를 통해 적정한 분산제의 선정 및 선정된 분산제의 함량비에 따른 무기물 분말의 분산 특성을 고찰하였다. 그리고 테이프 캐스팅을 통하여 테이프를 제작한 후 1GHz에서 유전특성을 측정하였다. 위 결과들을 통하여 분산제의 종류와 함량비에 따라 용액 및 슬러리의 특성이 다르며 적정한 분산제를 사용하여 유전상수 16.5에 유전손실 0.0058의 복합재료를 제작할 수 있었다.

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Etching Characteristics BST Thin Film in $CF_4$/Ar Plasma ($CF_4$/Ar 플라즈마에 의한 BST 박막 식각 특성)

  • 김동표;김창일;서용진;이병기;장의구
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.866-869
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    • 2001
  • In this study, (Ba,Sr)TiO$_3$(BST) thin films were etched with a magnetically enhanced inductively coupled plasma(MEICP). Etching characteristics of BST thin films including etch rate and selectivity were evaluated as a function of the etching parameters such as gas mixing ratio, rf power, dc bias voltage and chamber pressure. The maximum etch rate of the BST films was 1700 $\AA$/min at Ar(90)/CF$_4$(10), 600 W/350 V and 5 mTorr. The selectivity of BST to PR was 0.6, 0.7, respectively. To analyze the composition of surface residue remaining after the etching, samples etched with different CF$_4$/Ar gas mixing ratio were investigated with X-ray photoelectron spectroscopy (XPS) and secondary ion mass spectrometry (SIMS). From the results of XPS and SIMS, there are chemical reaction between Ba, Sr, Ti and C, F radicals during the etching and remained on the surface.

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A Study on BST Thin Films by MOD Process (MOD법에 의한 BST 박막의 특성에 대한 연구)

  • 송재훈
    • Journal of the Microelectronics and Packaging Society
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    • v.3 no.1
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    • pp.33-40
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    • 1996
  • MOD법에 의해 BST박막을 제조하고 전기적 특성을 측정함으로써 마이크로 회로에 적용가능성을 타진하였다. MOD 공정의 선구물질로서 barium neodecanoate, strontium 2-ethylhexanoate 및 titanium dimethoxy 야-2-ethylheanoate를 합성하였다, 합성된 선구물 질들을 Ba0.5Sr0.5TiO3가 되도록 화학양론적으로 혼합하여 공통용매인 p-xylene에 녹인다음 기판위에 spin coating 방법으로 박막을 형성하여 건조하고 소성하였다. 사용된 기판은 ITO/glass, Pt/SiO2/Si, Pt/Ti/SiO2/Si 및 Pt foil을 사용하였다. 소성 속도를 빨리했을 경우 소성속도를 느리게 했을때에 비하여 훨씬 균일하고 치밀한 박막을 얻을수 있었다, 여러 가 지 제조조건의 변화에 따른 유전상수 I-V 특성 및 C-V 측성 등의 전기적 특성을 측정하고 고찰하였다.

Structural Properties of SCT Thin Film with Deposition and Annealing Temperature (증착 및 열처리온도에 따른 SCT 박막의 구조적인 특성)

  • Kim, Jin-Sa
    • Journal of the Semiconductor & Display Technology
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    • v.6 no.3
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    • pp.41-45
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    • 2007
  • The (SrCa)$TiO_3$(SCT) thin films were deposited on Pt-coated electrode(Pt/TiN/$SiO_2$/Si) using RF sputtering method according to the deposition condition. The crystallinity of SCT thin films were increased with increase of deposition temperature in the temperature range of $100{\sim}500[^{\circ}C]$. The optimum conditions of RF power and Ar/$O_2$ ratio were 140[W] and 80/20, respectively. Deposition rate of SCT thin films was about $18.75[{\AA}/min]$ at the optimum condition. The composition of SCT thin films deposited on Si substrate is close to stoichiometry (1.081 in A/B ratio). The maximum dielectric constant of SCT thin film was obtained by annealing at $600[^{\circ}C]$.

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Microwave Dielectric Properties of the BSST Ceramics doped with Nd. (Nd가 첨가된 BSST 세라믹스의 마이크로파 유전 특성)

  • Park, In-Gil;Lee, Young-Hie;Ryu, Ki-Won;Bae, Seon-Gi
    • Proceedings of the KIEE Conference
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    • 1994.07b
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    • pp.1254-1256
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    • 1994
  • 0.15$(Ba_{0.95}Sr_{0.05})$O-0.15$(Sm_{2(1-x)}Nd-{2x})O_3-0.7TiO_2 (x=0{\sim}10[m/o])$ ceramics were fabricated by mixed-oxide method. Microwave dielectric properties was investigated with the contents of $Nd_2O_3$. Increasing the contents of $Nd_2O_3$ from 0 to 6[m/o], sintered density was increased 5.53 to $5.68[g/ cm^3]$. In the specimen with contents of $Nd_2O_3$(6[m/o]), dielectric content was maximum value of 78.14 and decreased with increasing the contents of $Nd_2O_3$. Quality factor was increased with the contents of $Nd_2O_3$.

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The Surface Image Properties of BST Thin Film by Depositing Conditions (코팅 조건에 따른 BST 박막의 표면 이미지 특성)

  • Hong, Kyung-Jin;Ki, Hyun-Cheol;Ooh, Soo-Hong;Cho, Jae-Cheol
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05b
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    • pp.107-110
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    • 2002
  • The optical memory devices of BST thin films to composite $(Ba_{0.7}\;Sr_{0.3})TiO_{3}$ using sol-gel method were fabricated by changing of the depositing layer number on $Pt/Ti/SiO_{2}/Si$ substrate. The structural properties of optical memory devices to be ferroelectric was investigated by fractal analysis and 3-dimension image processing. The thickness of BST thin films at each coating numbers 3, 4 and 5 times was $2500[\AA]$, $3500[\AA]$ and $3800[\AA]$. BST thin films exhibited the most pronounced grain growth. The surface morphology image was roughness with coating numbers. The thin films increasing with coating numbers shows a more textured and complex configuration.

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Effects of Sr on the Characteristics of PZT Ceramics Prepared by Hydrothermal Process (수열합성법에 의해 제조된 PZT의 특성에 미치는 Sr의 영향)

  • Yang, Beom-Seok;Shin, Chang-Yun;Won, Chang-Whan
    • Journal of the Korean Ceramic Society
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    • v.45 no.11
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    • pp.681-687
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    • 2008
  • The sintering and electrical properties of the hydrothermal PSZT powders obtained by substituting 4, 6 and 8mol% Sr for Pb in PZT lattice structure were investigated. The lattice constant and particle size decreased in proportion to a quantity of Sr. The sintering properties of PSZT powders showed $7.754g/cm^3$ of sintered density and $4{\mu}m$ of grain size at sintering temperature of $1250^{\circ}C$. Curie temperature lowered gradually from $363.6^{\circ}C\;to\;319.2^{\circ}C$ and relative dielectric constants increased rapidly by a quantity of Sr. In comparison to PZT, moreover, the quality factor of PSZT was increased more than three times with increase of Sr mole ratio, and piezoelectric constant $(d_{31}\;and\;g_{31})$ was decreased. It was found that dielectric loss of PSZT was decreased by 0.574% which was half of PZT.

나노$TiO_2$계 화합물과 응용

  • Hwang, Yong-Gil;Gil, Sang-Cheol
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.57.1-57.1
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    • 2009
  • 나노이산화티타늄은 인체에는 화장품, 의약, 식품분야 등에 쓰이고 외부 환경 재료에는 광촉매로서 유독가스 정화제, 옥내 외 항균, 수소발생 가시광 응답형 촉매 및 멤브레인 필터 등과 전자소재용 유전재료, 발광 재료 등 용도가 다양하다. 나노 산화티타늄 화합물의 제조법은 수열합성법, 기상법 등 여러 방법이 있다. 이들에 대한 리뷰의 목적은 2009년도 정부의 투자 계획 중에서 본제목에 관련되는 핵심 산업 재원 원천기술 개발, 태양광, 풍력 등의 신재생 에너지 개발, 록색 기술 개발을 통한 에너지절약형 LED 개발, 차세대 핵심환경 기술 개발, 핵심나노기반기술개발 등의 개발을 위하여 4,363억 원의 예산을 편성하고 연구자와 기술자들이 참여하여 유익한 실적이 창출되기를 원하고 있으므로 본 발표자들은 이 분야에서 연구하는 연구자와 기술자들에게 이 분야에 관련되는 자료를 참고로 제시하는데 있다. 페로브스카이트형 산화물인 유전재료($BaTiO_3$), 발광재료(CaTiO3:Pr3+적색), 박막형 반응기재료($Ca0.8Sr0.2TiO_3$), 등의 여러 가지 산화물은 류통식 급속 승온 수열 합성법, 겔 졸 법, 수열 합성법 등 여러 방법에 의하여 페로브스카이트형 산화물 입자 직경이 약 20nm~100nm 범위까지 합성된다. 태양광을 조사하여 물을분해 해서 수소를 생산하는 산화티타늄계 가시광 응답형 Vis-$TiO_2$ 박막은 기상법으로 제조하는데 한 예로써 RF 스퍼터링법으로 박막을 제조하여 수소와 산소를 회수하였으며, 황도프산화티타늄, 질소 도프 산화티타늄은 유기물 분해에 의한 공해제거, $NO_x$ 제거 등 환경정화에 사용되고, 고온 고압수법/산화티타늄 복합기술에 의해서는 바이오매스 분해 하고, 일종의 수열법인 개량형 HyCOM 법은 가시광 응답성 산화티타늄을 합성하여 NO가스 제거에 사용한다. 이들 여러 방법에 관한 것을 소개하고저 한다.

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