• Title/Summary/Keyword: SrO

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Microwave Dielectric Properties of the (1-x)MgxSr$TiO_3$(x=0.03~0.04) ceramics ((1-x)MgxSr$TiO_3$(x=0.03~0.04) 세라믹스의 마이크로파 유전특성)

  • 최의선;이문기;류기원;배선기;이영희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.547-550
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    • 2000
  • The (1-x)MgTiO$_3$-xSrTiO$_3$(x=0.03~0.04) ceramics were fabricated by the conventional mixed oxide method. The sintering temperature and time were 125$0^{\circ}C$~135$0^{\circ}C$, 2hr., respectively. From the X-ray diffraction patterns, it was found that the perovskite SrTiO$_3$ and ilmenite MgTiO$_3$ structures coexisted in the (1-x)MgTiO$_3$-xSrTiO$_3$(x=0.03~0.04) ceramics. The dielectric constant($\varepsilon$$_{r}$) was increased with addition of SrTiO$_3$. The temperature coefficient of resonant frequency($\tau$$_{f}$) was gradually varied from negative value to the positive value with increasing the SrTiO$_3$. The negative temperature coefficient of resonant frequency of the magnesium titanate was adjusted to near zero at x=0.036, where the dielectric constant, quality factor, and $\tau$$_{f}$ were 20.65, 95120, and +1.3ppm/$^{\circ}C$, respectively. The temperature stability of qualify factor in (1-x)MgTiO$_3$-xSrTiO$_3$(x=0.03~0.04) ceramics increased as the amount of MgTiO$_3$./TEX>.

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Preparation and Luminescent Properties of SrTiO3 : Al, Pr Red Phosphors for the FED (FED용 Al 및 Pr 첨가 SrTiO3 적색 형광체의 제조와 발광특성)

  • Park, Chang-sub;Lee, Jeng-Un;Yu, Il
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.9
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    • pp.846-850
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    • 2005
  • [ $SrTiO_3$ ]:Al, Pr red phosphors for FED were synthesized by solid state reaction method. The dependence of their luminescent properties on Sr and Al concentration was investigated. The $SrTiO_3$: Al, Pr phosphors showed the characteristic X-ray diffraction patterns of the perovskite structure. Photoluminescence intensity and lattice constant in $SrTiO_3$: Al, Pr phosphors changed in quite a similar manner with Sr concentration. Photoluminescence intensity increased with increasing lattice constant, and the decrease of photoluminescence intensity and lattice constant occurred in the vicinity of 1 mol Sr concentration.

Preparation of SrTiO3: Pr3+ Phosphors Using Supercritical Fluid Method and its Luminescence Properties (초임계 유체법에 의한 SrTiO3: Pr3+ 형광체 분말 제조 및 발광특성)

  • Choi, Keun-Mook;Hong, Seok-Hyoung;Lim, Dae-Young;Nho, Jun-Seok;Cho, Seung-Beom
    • Journal of the Korean Ceramic Society
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    • v.39 no.11
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    • pp.1023-1027
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    • 2002
  • In this paper, we have prepared phase-pure $SrTiO_3:\;Pr^{3+}$ phosphor powder by Supercritical Fluid Mixing using $Sr(OH)_2{\cdot}8H_2O$ and $TiO_2$ powders as starting materials. Its luminescent properties were investigated in comparison with $SrTiO_3:\;Pr^{3+}$ powders prepared by solid-state method with conventional mixing. $SrTiO_3:\;Pr^{3+}$ phosphor powders by Supercritical Fluid Mixing have spherical shapes and narrow particle size distribution. We have investigated the luminescent properties of $SrTiO_3:\;Pr^{3+}$ phosphor using $Al^{3+}$ and $Ga^{3+}$ as sensitizer.

Resistive Switching Properties of Cr-Doped SrZrO3 Thin Film on Si Substrate (실리콘 기판위에서의 Cr-Doped SrZrO3 박막의 저항변화 특성)

  • Yang, Min-Kyu;Ko, Tae-Kuk;Park, Jae-Wan;Lee, Jeon-Kook
    • Korean Journal of Materials Research
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    • v.20 no.5
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    • pp.241-245
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    • 2010
  • One of the weak points of the Cr-doped SZO is that until now, it has only been fabricated on perovskite substrates, whereas NiO-ReRAM devices have already been deposited on Si substrates. The fabrication of RAM devices on Si substrates is important for commercialization because conventional electronics are based mainly on silicon materials. Cr-doped ReRAM will find a wide range of applications in embedded systems or conventional memory device manufacturing processes if it can be fabricated on Si substrates. For application of the commercial memory device, Cr-doped $SrZrO_3$ perovskite thin films were deposited on a $SrRuO_3$ bottom electrode/Si(100)substrate using pulsed laser deposition. XRD peaks corresponding to the (112), (004) and (132) planes of both the SZO and SRO were observed with the highest intensity along the (112) direction. The positions of the SZO grains matched those of the SRO grains. A well-controlled interface between the $SrZrO_3$:Cr perovskite and the $SrRuO_3$ bottom electrode were fabricated, so that good resistive switching behavior was observed with an on/off ratio higher than $10^2$. A pulse test showed the switching behavior of the Pt/$SrZrO_3:Cr/SrRuO^3$ device under a pulse of 10 kHz for $10^4$ cycles. The resistive switching memory devices made of the Cr-doped $SrZrO_3$ thin films deposited on Si substrates are expected to be more compatible with conventional Si-based electronics.

Studies of the Crystallization through Volume Change from Bi-Sr-(Ca, Cd)-Cu-O Amorphous Materials (Bi-Sr-(Ca, Cd)-Cu-O 비정질체의 체적변화에 따른 결정화 과정 연구)

  • 한영희;성태현;한상철;이준성;정상진
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 1999.02a
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    • pp.51-53
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    • 1999
  • The crystallization mechanism of an amorphous $Bi_{2}$$Sr_{2}$$Ca_{2 x}$$Cd_{x}$$Cu_{3}$$O_{y}$ phase were studied from the relations between crystallization and volume changes by dilatometry. Further, the effect of addition of CdO on the crystallization mechanism and superconductivity was discussed. The shrinkage of the amorphous $Bi_{2}$$Sr_{2}$$Ca_{2 x}$$Cd_{x}$$Cu_{3}$$O_{y}$ occurred with the crystallization of $Bi_{2}$$Sr_{2}$Cu$O_{6}$ phase decrease with increasing CdO content with a minimum at x=0.4. Better superconductivity was obtained in the specimens formation less amount of the$Bi_{2}$$Sr_{2}$Cu$O_{6}$ phase during the crystallization process.

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Preparation and Luminescent Properties of (Sr1Ca)TiO3:Pr1Al Phosphors ((Sr1Ca)TiO3:Pr1Al 형광체의 제조와 발광특성)

  • Park Chang-Sub;Lee Jeng-Un;Yu Il
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.5
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    • pp.422-426
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    • 2006
  • [ $Sr_xCa_{(1-x)}TiO_3$ ] red phosphors doped with Pr(0.13 mol%) and Al(0.23 mol%) were synthesized by solid state reaction method. Change of crystal structure occurred in $Sr_xCa_{(1-x)}TiO_3:Pr,Al$ phosphors with increasing value of x. Green and red luminescence were observed from $SrTiO_3:Pr,Al$ phosphors at low temperature. However, only red luminescence in the case of $CaTiO_3:Pr,Al$ phosphors was measured at low temperature. The main cause of green luminescence was explained by the bandgap reduction.