• Title/Summary/Keyword: Sr(II)

Search Result 134, Processing Time 0.029 seconds

Hollandite-rich Synroc for Immobilization of Sr/Cs Separated from HLW Liquid

  • Zhao Yulong;Ii Baojun;xu Jianhua;Zhang Chuanzhi
    • Proceedings of the Korean Radioactive Waste Society Conference
    • /
    • 2005.11b
    • /
    • pp.329-337
    • /
    • 2005
  • Synroc which comprises hollandite-rich ($Ba_{1-x}Cs_{2x}\;(Al_yTi_{2-y})\;Ti_{6}O_{16},\;75wt\%$), perovskite ($Ca_{1-x}Sr_xTiO_3,\;15wt\%$) and rutile ($TiO_2,\;10wt\%$) is devised for the immobilization of Sr/Cs (1:3, wt$\%$) separated from HLW liquid. Especially, hollandite-rich Synroc with different contents of Al element is fabricated, and its mineral phase assemblage and microstructure are determined by using XRD and SEM/EDS. The durability test is carried out by using MCC-1 method, leachate is analyzed by using ICP/MS and ICP/ AES. The results indicate that hollandite-rich Synroc variants is a suitable host for Immobilization of Sr/Cs separated from HLW liquid.

  • PDF

The study on Dielectric and Strain Properties of $Pb(Mg_{1/3}Nb_{2/3})O_3-PbTiO_3-SrTiO_3$ Ceramics. ($Pb(Mg_{1/3}Nb_{2/3})O_3-PbTiO_3-SrTiO_3$ 세라믹의 유전 및 변위 특성에 관한 연구(II))

  • Lee, H.Y.;Lee, J.;Jung, H.D.;Paek, Y.C.;Lee, H.K.;Lee, D.C.
    • Proceedings of the KIEE Conference
    • /
    • 1994.07b
    • /
    • pp.1466-1468
    • /
    • 1994
  • In this paper Dielectric and strain properties of (1-x-y)PMN-yPT-xST Ceramics have been investigated as a function of the amount of $SrTiO_3(ST)$. The $SrTiO_3$ content is ranged from 0.01-0.06(wt%). As the amount of ST is increased, dielectric constant has a maximum value at 0.05 mol composition. The Curie temperature is decreased linearly with increasing ST composition and Polarization properties have been investigated. Coercive field and ramnant polarization has a maximum value at 0.01mol composition.

  • PDF

The Effect of Ginseng on Heart Contraction and Sarcoplasmic Reticulum Function(II) The Effect of Ginseng on $^{45}Ca^{2+}$ Uptake by Sarcoplasmic Reticulum Fragments of Rat Heart

  • Sung, Baek-Yeon;Kim, Nak-Doo
    • Archives of Pharmacal Research
    • /
    • v.6 no.1
    • /
    • pp.69-73
    • /
    • 1983
  • It was reported from our laboratory that the rate of deterioration of the force of contraction was slower in heart from Panax ginseng extract treated rats. Present investigation was designed to elucidate the mechanism of the slow deterioration of contractility of ginseng treated hearts. Therefore, $^{45}Ca^{2+}$ Uptake by sarcoplasmic reticulum (SR) isolated from ginseng treated rate and control rats was studied. Rate weighing 150-250g were administered orally with ginseng ethanol extract (100mg/kg) for 10 days. Cardiac SR was isolated by differential centrifugation and $^{45}Ca^{2+}$ uptake was assessed by the Millipore method. Freshly isolated SR from treated as well as control animals did not show any differences, but after incubation for 30 and 60 min at 37.deg.C, $^{45}Ca^{2+}$ uptake of control animal SR was found to be greatly depressed. The SR of treated animal possessed a greater degree of resistance to incubation. Thus it can be concluded that ginseng may have an ability to sustain the normal function of the heart by sustaining Ca accumulation by SR involved with the excitationcontraction coupling processes.

  • PDF

The analysis of alkaline earth metal and its alloy by using of cation exchanger (양이온교환수지에 의한 알칼리 토금속 및 합금의 분리정량)

  • Myon-Yong Park;Byong Cho Lee;Kee Chae Park
    • Journal of the Korean Chemical Society
    • /
    • v.15 no.2
    • /
    • pp.45-48
    • /
    • 1971
  • The various eluents have been used for the separations of alkaline earth metals by elutions through cation exchange resin column by many investigators. We find, the mixed solution of 1M HAc and 1M NaAc (pH 4.75) is the best eluent for this purpose, becouse the one step elution through 7cm Dowex 50w${\times}$8(100~200mesh) resin column with this eluent, gives the quantitative separation. When 2M NaAc is used as a eluent Sr(II) and Ba(II) is separated easily without any contamination of Mg(II) andCa(II). The Ca-Pb alloy which is composed of Cu, Ca, Sr, Ba and abundance of Pb metal is separated quantitatively into its components by the two step elution with 0.3M HAc + 0.3M NaAc(PH 4.75) and 0.5M HAc + 0.5M NaAc(PH 4.75) as eluents through 10cm resin column.

  • PDF

Electrical Properties of $(x)BaTiO_3-(1-x)SrTiO_3$ Ceramic with Variation of $SrTiO_3$ Substitution ($SrTiO_3$ 고용에 따른 $(x)BaTiO_3-(1-x)SrTiO_3$ 세라믹의 전기적 특성)

  • Jang, Dong-Hwan;Ki, Hyun-Chul;Hong, Hyung-Jin;Jung, Woo-Sung;Kim, Tae-Sung
    • Proceedings of the KIEE Conference
    • /
    • 1998.11c
    • /
    • pp.795-797
    • /
    • 1998
  • A $BaTiO_3$, ferroelectric material, was mixed $SrTiO_3$, $(x)BaTiO_3-(1-x)SrTiO_3$($0.7{\leq}x{\leq}1$) ceramic capacitor with stable electrical properties in high voltage was fabricated. And microstructure, electrical property were investigated with $SrTiO_3$ mol ratio. The shrinkage, open porosity, sintering density were predominated at $9BaTiO_3-0.1SrTiO_3$. Increasing $SrTiO_3$ mol ratio, curie temperature was shifted at low temperature and maximum permittivity was increased. Also, $0.9BaTiO_3-0.1SrTiO_3$ was showed stable dielectric properties at $25{\sim}80[^{\circ}C]$. V-I properties of specimen were observed in the temperature range of $21{\sim}143[^{\circ}C]$, were divided into three regions. The region I below 10[kV/cm] was shown Ohmic conduction, the region II from 10 to 30[kV/cm] was explained by the Poole-Frenkel emission theory and the region III above 30[kV/cm] was analysed by the tunneling effect.

  • PDF

Fabrication and Properties of ferroelectric BST thin films prepared by sol-gel method (II) - effect of ultrasound on properties of thin film (졸-겔법에 의한 강유전 BST 박막의 제조 및 특성(II) - 초음파의 효과)

  • 이진홍;박병옥;이승엽
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.11 no.6
    • /
    • pp.252-258
    • /
    • 2001
  • ($Ba_{0.7}Sr_{0.3})TiO_3$thin films were perpared on ITO-coated glass substrate by spin-coating method. The sol was sonicated in an ultrasonic bath to promote homogenization and the results were compared with untreated case. By application of the sonication process, crystallization temperatures of films were reduced, microstructers of films were more uniform and denser and the surface roughness of the films was lower from 8.4nm to 5.6nm. In addition, optical transmittances and electrical properties of films prepraed from sonicated sol were superior to those of films from untreated.

  • PDF

Sr-Nd-Pb Isotopic Compositions of Lavas from Cheju Island, Korea (제주도 화산암류의 Sr-Nd-Pb 동위원소 연구)

  • 박준범;박계헌;정창식
    • The Journal of the Petrological Society of Korea
    • /
    • v.5 no.1
    • /
    • pp.89-107
    • /
    • 1996
  • Sr, Nd and Pb isotopic characteristics of alkaline lavas and tholeiites in Cheju Island show that the isotopic compositions of the former slightly overlap, but have relatively more depleted than the latter. However, in viewpoint of the two eruptional stratigraphies of tholeiites, the isotopic compositon of the older one is similar to those of alkaline rocks in Lava Plateau Stage after Lee (1982). These suggest that the parental magmas of alkaline lavas and tholeiites might have originated from the homogenous mantle sourve and that the characteristics of the mantle source to be partially melted might be different between the eruption stages. The isotopic signatures of the bolcanic rocks in Cheju Island overlap with those in Samoa Islands and South China Basin, indicating the DMM-EM IImixing trend. This is distingushed from the DMM-EM I trend of the Cenozoic volcanic rocks in Korea except for cheju Island and Northeastern China. The modelled binary mixing calculation between MM and EM IImaterials indicates that the mantle source of the volcanic rocks in Cheju Island has been mixed about less than 10% of enriched mantle material (EM II) with depleted mantle material (DMM). Concerned with the indentation model between North China Block (NCB) and South China Block (SCB) after Yin an Nie (1993), we suggest that the distinct isotopic features of DMM-EM I and DMM-EM IIof the Cenozoic volcanic rock in Korea as well as China can be explained by the difference of the nature of subcontinental lithospheric mantle as enriched mantle materials, i.e. EM I of NCB, while EM II of SCB.

  • PDF

Synthesis and Luminescent Characterization of Eu2+/Dy3+-Doped Sr2MgSi2O7 Powders (Eu2+/Dy3+ 이온이 도핑된 Sr2MgSi2O7 분말 합성 및 발광 특성)

  • Park, Jaehan;Kim, Young Jin
    • Korean Journal of Materials Research
    • /
    • v.24 no.12
    • /
    • pp.658-662
    • /
    • 2014
  • $Eu^{2+}/Dy^{3+}$-doped $Sr_2MgSi_2O_7$ powders were synthesized using a solid-state reaction method with flux ($NH_4Cl$). The broad photoluminescence (PL) excitation spectra of $Sr_2MgSi_2O_7:Eu^{2+}$ were assigned to the $4f^7-4f^65d$ transition of the $Eu^{2+}$ ions, showing strong intensities in the range of 375 to 425 nm. A single emission band was observed at 470 nm, which was the result of two overlapping subbands at 468 and 507 nm owing to Eu(I) and Eu(II) sites. The strongest emission intensity of $Sr_2MgSi_2O_7:Eu^{2+}$ was obtained at the Eu concentration of 3 mol%. This concentration quenching mechanism was attributable to dipole-dipole interaction. The $Ba^{2+}$ substitution for $Sr^{2+}$ caused a blue-shift of the emission band; this behavior was discussed by considering the differences in ionic size and covalence between $Ba^{2+}$ and $Sr^{2+}$. The effects of the Eu/Dy ratios on the phosphorescence of $Sr_2MgSi_2O_7:Eu^{2+}/Dy^{3+}$ were investigated by measuring the decay time; the longest afterglow was obtained for $0.01Eu^{2+}/0.03Dy^{3+}$.