• Journal of the Korean Electrochemical Society
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• v.19 no.2
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• pp.50-56
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• 2016

Spherical lithium manganese oxide spinel, $Li_{1.10}Mn_{1.86}Al_{0.02}Mg_{0.02}O_4$ was prepared by wet-milling, spray-drying, and sintering process. In the spray-drying process, solid content in slurry was varied from 20 to 30 wt%. In the sintering process, the precursors have been sintered under air or $O_2$ atmosphere. While the as-prepared samples exhibit excellent electrochemical properties at room temperature, the discharge voltage profiles at 5.0C are very different one from another. The origin for the difference especially at initial state of discharge is oxygen defect. The sample prepared in air has larger capacity related to the plateau at 3.3 V (vs. $Li/Li^+$) which is caused by the oxygen defects than the one prepared in $O_2$. The difference of discharge voltage profiles especially at the final state of discharge comes from different diffusion rate of $Li^+$ ions. The sample prepared from 30 wt% solid content of slurry shows twice higher diffusion rate than the samples prepared from 20 wt% solid content, which is attributed to better compactness between primary particles for the sample prepared from 30wt % solid content than the one prepared by 20 wt%.

• Korean Journal of Agricultural Science
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• v.14 no.1
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• pp.81-97
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• 1987

Two nozzles with different size (Figure 2) were particularly designed to supply air through the swirl core into the central part of the liquid stream in the same parallel direction to produce a well-mixed air and water in the whirl chamber as spray liquid in bubble formation. Atomization was attempted to improve by using both the preliminary break-up process with less viscosity and less surface tension in the whirl chamber and the effects of increased frequency of the band of drops with the raised ambient air density in front of the nozzle orifice. The volumetric ratio between spray liquid and air on four levels was used to investigate the effects of air as a component of the mixture on atomization. The results of the experiment were summarized as follows; Droplet size became progressively finer as the operating pressure was increased in the range of $0.70kg/cm^2$ to $6.33kg/cm^2$, which was similar to the previous works. The new atomizing mechanism so-called 'air-center nozzle' gave a narrower range in droplet size distribution with smaller volumetric median diameter (VMD) than that of the existing spray system at a given pressure, which showed the possibility of improvement of atomization in a certain limit. The volumetric median diameter produced by the new atomizing mechanism was decreased from the central region toward the exterior edges across the spray pattern.

• Economic and Environmental Geology
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• v.52 no.2
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• pp.119-128
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• 2019

About 300,000 tones of oyster shell are annually produced in Korea and, thus, a massive recycling plan is required. Many desulfurizing studies using oyster shells with chemical composition of $CaCO_3$ have been performed so far; however, most of them have focused on dry desulfurization. This study investigates the possibility of using oyster shells for wet desulfurization after calcination. For this, a simulated wet desulfurization facility of spray type was devised and compared the SOx-stripping characteristics of calcined oyster shell with those of limestone. The calcined oyster shell slurry indicate a better desulfurizability than the slurries of raw shell or limestone because the oyster shell transformed to a more reactive phase ($Ca(OH)_2$) by the calcination and hydration. Because of this reason, when the calcined oyster shell slurries were used, the reaction residue showed the higher gypsum ($CaSO_4{\cdot}2H_2O$) contents than any other cases. In the continuous desulfurization experiments, calcined oyster shell slurry showed a wider pH variation than limestone or raw oyster shell slurries, another clear indication of high reactivity of calcined oyster shells for $SO_2$ absorption. Our study also shows that the efficiency of wet desulfurization can be improved by the use of calcined oyster shells.

• Applied Chemistry for Engineering
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• v.32 no.4
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• pp.409-416
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• 2021

Dimensionally stable electrodes are one of the important components in electrochemical water treatment processes. In the manufacturing of the dimensionally stable electrodes, the type of metal catalyst coated on the surface of the metal substrate, the coating and sintering methods substantially influence their performance and durability. In this study, using Ir-Ru-Ta ternary metal coating, various electrodes were prepared depending on the coating method under the same pre-treatment and sintering conditions, and its performance and durability were studied. As a coating method, brush and spray coating were used. As a result, the reduction in the amount of catalyst ink was achieved because more amount of metal could be coated for the electrode using spraying with the same amount of catalyst ink. In addition, the spray_2.0_3.0 electrode prepared by a specific spray coating method shows the phenomenon of cracking and the uniform coating of the ternary metal on the surface of the coating layer, and results in a high electrochemically active specific surface area, and the decomposition performance of 4-chlorophenol was superior to the other electrodes. However, it was found that there was no significant difference in durability depending on the coating method.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2006.11a
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• pp.59-63
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• 2006

A direct photograph measurement technique was used to determine the spatial distribution of the spray droplet diameter in subsonic crossflow and it also obtain that SMD distribution by using PLLIF technique. The injector internal flow was classified as three modes such as a normal, cavitation, and hydraulic flip. The objectives of this research are getting a droplet distribution and drop size measurement of normal flow and compare with the other flow effects. Although the study showed visually that drop size were spatially dependent of Air-stream velocity, fuel injection velocity, and normalized distance from the injector exit length.(x/d, y/d) There are also difference characteristics between cavitation, hydraulic flip and the normal flow.

• Journal of ILASS-Korea
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• v.8 no.1
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• pp.9-15
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• 2003

The liquid phase LPG injection (LPLI) system is considered as one of the next generation fuel supply systems for LPG, vehicles, since it can accomplish the higher power, higher efficiency, and lower emission characteristics than the existing mixer type fuel supply system. However, during the injection of liquid LPG fuel into the inlet duct of an engine, a large quantity of heat is extracted due to evaporation of fuel. A problem is that the moisture in the air freezes around the outlet of a nozzle, which is called icing Phenomenon. It may cause damage to the outlet nozzle of an injector. The frozen ice deposit detached from the nozzle also may cause a considerable damage to the inlet valve or valve seat. In this work, the experimental investigation of the icing phenomenon was carried out. The results showed that the icing phenomenon and process were mainly affected by humidity of inlet air instead of the air temperature in the inlet duct. Also, it was observed that the icing occurs first in the inlet of a nozzle, and grows considerably at the upper part of the nozzle inlet and the opposite side of the nozzle entrance. An LPG fuel, mainly consisting of butane, has lower latent heat of vaporization than that of propane, which is an advantage in controlling the icing phenomenon.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.22 no.8
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• pp.1064-1072
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• 1998

The evaporation of sludge particles in a sludge dryer has been numerically investigated with commercial CFX4.1 code. Gas flow field, gas temperature field, sludge particle trajectories, and the moisture content variation of sludge particles are calculated fort various influencing factors, i. e., gas swirl velocity, initial particle distribution, gas temperature. Evaporation of sludge particles increases with gas swirl velocity, several supplying positions, and gas temperature, respectively due to increased residence time, increased contacting surface area, and increased temperature difference between gas and particle.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 1997.10a
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• pp.591-595
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• 1997

In analysis of piping vibration of petrochemical plant, the forcing functions mainly depend upon the equipment working mechanism and vibration resources in the piping systems. In general, harmonic function is used for the system with rotary equipments. Mechanical driving frequencies, wave functions, and response spectrum are used for reciprocating compressors, surge vibration of long transfer piping, and seismic/wind vibration, respectively. In this study, for the spray injection case inside the pipe, forcing function was modeled, in which two different fluids are distributed uniformly. To confirm the results, the scheme used for the forcing function was applied for real piping system. The vibration mode of the real system was consistent with the 4th mode obtained by simulation using the forcing function formulated in this study.

• Journal of Ocean Engineering and Technology
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• v.23 no.1
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• pp.60-66
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• 2009

This study presents an experimental investigation of the shallow water impact of a box type structure. The analysis was done based on the video images captured by a high speed camera, the flow field obtained by PIV (Particle Image Velocimetry), and pressure measurements in the divided region. The video images showed quite good agreement with the description given by Korobkin. The PIV measurements of the velocity field provided a clear view of the flow pattern for all three stages. The pressure was measured at the bottom of the tank with strain gauge type pressure gauges. The pressure measurements showed the characteristics of divided regions.

• Journal of ILASS-Korea
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• v.3 no.1
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• pp.10-18
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• 1998

To investigate the in-cylinder phenomena in a SI engine with 3 valves and pent-roof type combustion chamber, flow fields, fuel distributions, and flame propagations were measured in a single c!'tinder visualized engine. Flow fields were visualized by PTV system during the intake and compression process. Fuel distributions were measured by PLIF at the various engine conditions including the cold and hot engine conditions and the effect of air-shrouded injector on the fuel distribution was investigated also. In addition, flame propagation patterns were characterized.