• Title/Summary/Keyword: Spectrum wavelength range

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Synthesis and Photovoltaic Performance of NIR Absorption Dyes for the Dye Sensitized Solar Cell (NIR 흡수 염료를 이용한 염료감응형 태양전지)

  • Kim, Sangah;Jung, Miran;Lee, Minkyung;Kim, Jaehong
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.118.1-118.1
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    • 2011
  • The dye-sensitized solar cell (DSSC) is a device for the conversion of visible light into electricity, based on the sensitization of wide bandgap semiconductors. The performance of the cell mainly depends on a dye used as sensitizer. The absorption spectrum of the dye and the anchorage of the dye to the surface of TiO2 are important parameters determining the efficiency of the cell. Generally, transition metal coordination compounds(ruthenium polypyridyl complexes) are used as the effective sensitizers, due to their intense charge-transfer absorption in the whole visible range and highly efficient metal-to ligand charge transfer. However, ruthenium polypyridyl complexes contain a heavy metal, which is undesirable from point of view of the environmental aspects. Moreover, the process to synthesize the complexes is complicated and costly. Alternatively, organic dyes can be used for the same purpose with an acceptable efficiency. The advantages of organic dyes include their availability and low cost. We designed and synthesized a series of organic sensitizers containing long wavelength absorption-chromophores for the dye sensitized solar cell. The DSSC composed of Blue-chromophores for the sensitization absorbed long wavelength region which is different also applied into the dye-cocktail (mixing) system. The photovoltaic property of DSSCs organic long wavelength absorption-chromophores were measured and evaluated by comparison with that of individual chromophores.

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Spectroscopy of Visible Light Emitted from Plasma Occurred by Pulse Discharge (펄스형 방전플라스마에서 발생하는 가시광선의 분광특성 연구)

  • Choi, Woon Sang
    • Journal of Korean Ophthalmic Optics Society
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    • v.3 no.1
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    • pp.27-31
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    • 1998
  • We investigated visible light radiated from Plasma focus device by time-resolved analyzed method and time-integrated analyzed method. Plasma focus consisted of two coaxial electrodes is a device that translated from electric energy of maximum 40 kV/20 kJ in capacitor banks into visible light by electric discharge. Spectral analysis is using Monochromator(f =0.5m). Time-resolved spectrum is analyzed with a oscilloscope the light pulse of constant wavelength and time-integrated spectrum does with densitometer the film which developed a constant range of wavelength. The optimum condition of visible emission was that the discharging voltage was 17kV and the gas pressure 0.5 torr Ar.

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Thermal Characteristics of an Optical Add/Drop Multiplexer Using Fiber Bragg Grating Filter (파이버 브래그 격자 필터를 이용한 전광 다중화기의 온도 특성)

  • Son, Yong-Hwan;Jung, Jin-Ho
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.18 no.12
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    • pp.1383-1390
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    • 2007
  • In this paper, we study an optical add-drop multiplexer which consists of the fiber Bragg grating filter and investigate the temperature characteristics of it. To resolve the characteristics, we find and analyze numerically its temperature response, and fabricate an optical add/drop multiplexer and measure its output spectrum. From the obtained results, they show that the center wavelength of output spectrum shifts approximately 0.01230 nm/$^{\circ}C$ within a temperature range $-30{\sim}90^{\circ}C$.

Concentration Range Analysis for Fluorescence Expression of Indocyanine Green (Indocyanine green 형광조영제의 형광발현을 위한 농도 범위 분석)

  • Kim, Yong Jae;Lee, Da Ae;Yoon, Ki-Cheol;Kim, Kwang Gi
    • Journal of Korea Multimedia Society
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    • v.22 no.12
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    • pp.1339-1346
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    • 2019
  • In the characteristic of the brain malignant, the blood vessels and tumors have the same color and shape, and the boundary distinction is not clear, Therefore, it is difficult to observe the naked eye. Because of the high invasiveness, the risk of recurrence is high. Therefore, complete resection of the tumor is essential. The method for distinguishing the boundary between blood vessels and tumors is a fluorescence contrast method using indocyanine green (ICG), a fluorescence contrast agent. In ICG, the concentration range analysis is very important because the fluorescence expression state varies depending on the concentration. However, since the analysis result of the fluorescence expression condition is insufficient according to the current concentration, this paper proposes by analyzing the initial protocol of the concentration range. 780 nm infrared light was irradiated to the ICG sample to observe the fluorescence expression through a near infrared (NIR) camera. The wavelength is measured by using a spectrum instrument (ocean view) to observe the fluorescence expression wavelength of 811nm. As a result of analyzing the mol concentration according to each sample, the fluorescence expression range was found to be 16.15-0.16M and the optimum fluorescence concentration on the brightest part was found to be 3.23-0.81M.

A Compact Tunable VCSEL and a Built-in Wavelength Meter for a Portable Optical Resonant Reflection Biosensor Reader

  • Ko, Hyun-Sung;Kim, Bong-Kyu;Kim, Kyung-Hyun;Huh, Chul;Kim, Wan-Joong;Hong, Jong-Cheol;Park, Seon-Hee;Yang, Seong-Seok;Jang, Ho-Jin;Sung, Gun-Yong
    • Journal of the Optical Society of Korea
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    • v.14 no.4
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    • pp.395-402
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    • 2010
  • This study reports a portable and precision photonic biosensor reader that can measure the concentration of a particular antigen using an optical resonant reflection biosensor (ORRB). To create a compact biosensor reader, a compact tunable vertical-cavity surface-emitting laser (VCSEL) and a compact built-in wavelength meter were manufactured. The wavelength stability and accuracy of the compact built-in wavelength meter were measured to be less than 0.02 nm and 0.06 nm, respectively. The tunable VCSEL emission wavelength was measured with the compact built-in wavelength meter, it has a fast sweep time (~ 10 seconds) and a wide tuning range (> 4 nm) that are sufficient for biosensor applications based on ORRB. The reflection spectrum of a plastic based ORRB chip was measured by the fabricated portable photonic biosensor reader using the VCSEL and wavelength meter. Although the reader is the size of a palmtop device, it could make a precise measurement of the peak wavelength on equal terms with a conventional bulky optical spectrometer.

Studies on the Natural dyes( I ) -extraction and UV, VIS spectrum of coloring matter of gromwell- (천연염료에 관한 연구 ( I ) -자근색소의 추출 및 자외가시분광특성-)

  • Cho Kyung Rae
    • Journal of the Korean Society of Clothing and Textiles
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    • v.11 no.3 s.25
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    • pp.25-32
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    • 1987
  • The purpose of this study is to investigate optical behaviour of coloring matter of gromwell -extracted by water, acetic acid/methanol, and the other solvents. The results were as following: UV, VIS spectra of the solution of coloring matter of gromwell extracted by water at below $80^{\circ}C$ did not reveal in the range of the visible light wavelength and coloring matter of gromwell decomposed to blue particle at $95^{\circ}C$. The solution extracted by acetic acid/methanol was tinged with reddish purple and its spectra shifted to the longer wavelength according to increase of the solvent temperature. The color of the solution extracted by water became extinct as time went by, but that extracted by acetic acid/methanol kept up original color. In case of dried gromwell, extraction by acetic acid/methanol was easier than by water, and variation of spectra did not appear but showed hypochromic shift.

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Optoelectronic Characteristics of Transparent Cu2O Films Spin-coated on Glass Substrates (스핀코팅으로 제작된 Cu2O 필름의 광전기적 특성)

  • Kwak, Ki-Yeol;Cho, Kyoung-Ah;Kim, Sang-Sig
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.1
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    • pp.123-126
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    • 2010
  • $Cu_2O$ nanoparticles-based films are fabricated by spin-coating on glass substrates and their optoelectronic characteristics are investigated in this study. The $Cu_2O$ films are nearly all-transparent as high as 98% in a wavelength range from 400 nm to 900 nm and three exciton peaks associated with the sublevels in the conduction band are observed at the wavelengths shorter than 400 nm in the absorption spectrum. Under the illumination of the 325 nm wavelength light, the photocurrent efficiency of the $Cu_2O$ film is $1.8\times10^5 {\mu}A/W$ at a voltage of 2.5 V in air.

A Study on the New Widely Tunable Optical Filter for Ring Laser (링 레이저를 위한 새로운 광대역 파장 가변 필터에 대한 연구)

  • Kim, Kwang-Yoo;Lee, Jung-Ryul;Eom, Jin-Seob
    • Journal of Industrial Technology
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    • v.26 no.A
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    • pp.95-99
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    • 2006
  • In this paper, we proposed the new wavelength tunable filter for wide tunability of fiber ring laser. The proposed filter consists of the cascaded connection of Fiber Reflection Mach-Zehnder Interferometer and Sagnac filter or of hybrid filter and Fiber Reflection Mach-Zehnder Interferometer. The simulation shows that the continuous tunable range of 50nm can be obtained and that more stable single mode operation of ring laser can be expected due to narrow FWHM. of filter spectrum.

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PREPROCESSING EFFECTS ON ON-LINE SSC MEASUREMENT OF FUJI APPLE BY NIR SPECTROSCOPY

  • Ryu, D.S.;Noh, S.H.;Hwang, I.G.
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2000.11c
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    • pp.560-568
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    • 2000
  • The aims of this research were to investigate the preprocessing effect of spectrum data on prediction performance and to develop a robust model to predict SSC in intact apple. Spectrum data of 320 Fuji apples were measured with the on-line transmittance measurement system at the wavelength range of 550∼1100nm. Preprocess methods adopted for the tests were Savitzky Golay, MSC, SNV, first derivative and OSC. Several combinations of those methods were applied to the raw spectrum data set to investigate the relative effect of each method on the performance of the calibration model. PLS method was used to regress the preprocessed data set and the SSCs of samples, and the cross-validation was to select the optimal number of PLS factors. Smoothing and scattering corection were essential in increasing the prediction performance of PLS regression model and the OSC contributed to reduction of the number of PLS factors. The first derivative resulted in unfavorable effect on the prediction performance. MSC and SNV showed similar effect. A robust calibration model could be developed by the preprocessing combination of Savitzky Golay smoothing, MSC and OSC, which resulted in SEP= 0.507, bias=0.032 and R$^2$=0.8823.

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Internal Quality Estimation of Korean Red Ginseng Using VIS/NIR Transmittance Spectrum (가시광선 및 근적외선 투과스펙트럼을 이용한 홍삼의 내부품질예측)

  • 손재룡;이강진;김기영;강석원;최규홍;장익주
    • Journal of Biosystems Engineering
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    • v.29 no.4
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    • pp.335-340
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    • 2004
  • This study was conducted to evaluate the internal quality of Korean red ginseng using VIS/NIR transmittance spectra. To classify the internal qualities, partial least squares(PLS) regression was conducted. The main results are as follows: To develop the PLS model, several wave bands were divided and incorporated into the model. Among the bands, the wavelength range of 550-1,020nm, excluded noise signal, showed the best evaluation results. Effect of step size on the performance of quality evaluation showed optimal at 15 steps. In order to enhance the accuracy of quality evaluation, the abnormal spectrum shape was considered first and then the PLS model was applied. Among the 150 samples, 12 samples were evaluated by the spectrum shape. In this study, to develop the optimal PLS regression model, among the 150 samples, 138 samples was used with exception of 12 samples which could evaluate the spectrum shape. The result of quality evaluation was promising as SEC and correlation coefficient were 1.09 and 0.967, respectively, and SEP and correlation coefficient were 1.04 and 0.958, respectively.