• Title/Summary/Keyword: Spectroscopic studies

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THE SPECTROSCOPIC STUDIES OF THE LONG PERIOD ECLIPSING BINARY AZ CAS

  • Cheon, Mun-Seok;Sohn, Young-Jong
    • Journal of Astronomy and Space Sciences
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    • v.11 no.1
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    • pp.13-20
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    • 1994
  • Spectroscopic observations of the long period eclipsing binary AZ Cas were made using 122cm telescope/Image Tube. From the relatively sharp and strong spectral FeI lines we can calculate the mean radial velocity as -39.7km/sec. The estimated equivalent widths of some atomic lines are well fitted to the phase of the AZ Cas.

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Spectroscopic Studies on Pu(III) Hydrolysis Under Reducing and Elevated Temperatures Conditions

  • Cho, Hye-Ryun;Kim, Hee Kyung;Jung, Euo Chang;Cha, Wansik
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2017.10a
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    • pp.137-138
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    • 2017
  • The spectroscopic reference data for plutonium at different temperatures are necessary information for the chemical speciation and evaluation of thermodynamic data at elevated temperature. This work is the initial step to extend research activities for understanding the plutonium chemistry in aquatic solutions at high temperature. The hydrolysis of Pu(III) and the solubility of Pu(III) hydroxide at the elevated temperature will be discussed.

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Spectroscopic Studies on ZrO2 Modified with MoO3 and Activity for Acid Catalysis

  • Sohn, Jong-Rack;Chun, Eun-Woo;Pae, Young-Il
    • Bulletin of the Korean Chemical Society
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    • v.24 no.12
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    • pp.1785-1792
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    • 2003
  • Zirconia modified with $MoO_3$ was prepared by impregnation of powdered $Zr(OH)_4$ with ammonium heptamolybdate aqueous solution followed by calcining in air at high temperature. Spectroscopic studies on prepared catalysts were performed by using FTIR, Raman, XRD, and DSC and by measuring surface area. Upon the addition of molybdenum oxide to zirconia up to 15 wt%, the specific surface area increased in proportion to the molybdate oxide content, while acidity measured by irreversible chemisorption of ammonia exhibited a maximum value at 3 wt% of $MoO_3$. Since the $ZrO_2$ stabilizes the molybdenum oxide species, for the samples equal to or less than 30 wt%, molybdenum oxide was well dispersed on the surface of zirconia and no phase of crystalline $MoO_3$ was observed at any calcination temperature above $400^{\circ}C$. The catalytic activities for cumene dealkylation were roughly correlated with the acidity of catalysts measured by ammonia chemisorption method, while the catalytic activities for 2-propanol dehydration were not correlated with the acidity because weak acid sites are necessary for the reaction.

Low-ε Static Probe Development for 15N-1H Solid-state NMR Study of Membrane Proteins for an 800 MHz NB Magnet

  • Park, Tae-Joon;Choi, Sung-Sub;Jung, Ji-Ho;Park, Yu-Geun;Kim, Yongae
    • Bulletin of the Korean Chemical Society
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    • v.34 no.3
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    • pp.823-826
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    • 2013
  • A low-${\varepsilon}$ solid-state NMR(Nuclear Magnetic Resonance) probe was developed for the spectroscopic analysis of two-dimensional $^{15}N-^1H$ heteronuclear dipolar coupling in dilute membrane proteins oriented in hydrated and dielectrically lossy lipid environments. The system employed a 800 MHz narrow-bore magnet. A solenoid coil strip shield was used to reduce deleterious RF sample heating by minimizing the conservative electric fields generated by the double-tuned resonator at high magnetic fields. The probe's design, construction, and performance in solid-state NMR experiments at high magnetic fields are described here. Such high-resolution solid-state NMR spectroscopic analysis of static oriented samples in hydrated phospholipid bilayers or bicelles could aid the structural analysis of dilute biological membrane proteins.

Metal Complexes of Enrofloxacin Part I: Preparation, Spectroscopic, Thermal Analyses Studies and Antimicrobial Evaluation

  • El-Shwiniy, Walaa H.;El-Attar, Mohamed S.;Sadeek, Sadeek A.
    • Journal of the Korean Chemical Society
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    • v.57 no.1
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    • pp.52-62
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    • 2013
  • The interaction of titanium (IV), yttrium (III), zirconium (IV), palladium (II) and cerium (IV) with deprotonated enrofloxacin leads to the formation of the neutral or cationic mononuclear complexes. The isolated solid complexes have been characterized with physicochemical and spectroscopic techniques and thermogravimeteric analyses. The spectroscopic data indicate that the enrofloxacin ligand is on the deprotonated mode acting as bidentate ligand coordinated to the metal ions through the ketone oxygen and a carboxylato oxygen and the metal ions completed the coordination number with water molecules. The thermal decomposition mechanisms proposed for enrofloxacin and their metal complexes were discussed. The activation energies, $E^*$, enthalpies, ${\Delta}H^*$, entropies, ${\Delta}S^*$ and Gibbs free energies, ${\Delta}G^*$, of the thermal decomposition reactions have been derived from thermogravimetric (TG) and differential thermogravimetric (DTG) curves, using Coats-Redfern (CR) and Horowitz-Metzeger (HM) methods. The antimicrobial activity has been evaluated against six different microorganisms.

Observation of the Bright Spectroscopic Binary Systems with DOAO/eShels Spectrograph

  • Shim, Hyunjin;Lee, Dongseob;Jeong, Yoonji;Kang, Wonseok;Kim, Taewoo
    • The Bulletin of The Korean Astronomical Society
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    • v.43 no.2
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    • pp.51.1-51.1
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    • 2018
  • Based on the DOAO/eShels observations, we have derived radial velocity curves of the three Algol-type spectroscopic binary systems : Algol, ${\beta}$ Aur, and ${\varepsilon}$ Per. The radial velocity amplitudes of the primary and the secondary (K1 and K2) were consistent within a few % of the values from the previous studies. Mass ratios between the two stars that constitutes each system ranges ~1 to ~10. In addition to the orbital elements derived, we discuss about the spectroscopic ability of the DOAO/eShels instrument.

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