• 제목/요약/키워드: Spectroscopic method

검색결과 527건 처리시간 0.037초

분광기법을 이용한 저압 차단기용 소호재료 특성연구 (Investigation of Arc Quenching Material for Low Voltage Circuit Breaker using Spectroscopic Method)

  • 이상엽;정영우;박홍태;오일성
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2003년도 하계학술대회 논문집 C
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    • pp.1665-1667
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    • 2003
  • Recently, a breaking capacity increases with breaking method using gas pressure from ablation materials in low voltage circuit breakers. In this paper, we investigated arc quenching materials with spectroscopic method. Especially, Hydrogen spectrum was investigated because its dielectric characteristics are better than other gases. We selected two arc quenching materials, UP and PA6, that use in circuit breakers. They had hydrogen spectrums, but PA6 was better than UP in the qualitative aspect.

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Determination of Nitrogen Abundance Ratio from Low-Resolution Stellar Spectra

  • Kim, Changmin;Lee, Young Sun
    • 천문학회보
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    • 제45권1호
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    • pp.58.2-58.2
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    • 2020
  • We present a method for determining the abundance ratio of nitrogen to iron ([N/Fe]) from low-resolution (R~2000) stellar spectra from large spectroscopic surveys such as Sloan Digital Sky Survey (SDSS) and Large Sky Area Multi-Object Fiber Spectroscopic Telescope (LAMOST). The basic idea of the method is to match a grid of synthetic spectra with an observed spectrum in the CN band region around 3883 Å. To calibrate our estimate of [N/Fe], we make use of the giants observed in Apache Point Observatory Galaxy Evolution Experiment (APOGEE), which are also observed in the SDSS. This method will be applied to the Galactic halo stars to determine [N/Fe], and the measured nitrogen abundance ratios will be used to investigate the C-N anti-correlation, which is observed in globular clusters, to trace their origin with their kinematic properties.

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레이저 유도 분해 분광법과 라만 분광법을 이용한 우주 광물의 정성 및 정량 분석 기법 (Qualitative and Quantitative Analysis of Space Minerals using Laser-Induced Breakdown Spectroscopy and Raman Spectroscopy)

  • 김동영;여재익
    • 한국항공우주학회지
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    • 제46권6호
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    • pp.519-526
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    • 2018
  • 우주 자원을 분석하기 위해서는 지구로 가져와야 한다는 단점이 있었다. 하지만, 레이저 유도 분해 분광법(Laser-induced breakdown spectroscopy, LIBS)고 라만 분광법(Raman spectroscopy)을 활용한다면 우주 광물의 실시간 정성 정량적으로 분석이 가능하다. 레이저 유도 분해 분광법은 높은 에너지의 레이저를 물질 표면에 집중시켜 플라즈마를 생성한후, 방출되는 빛을 분광기를 통해 획득하여 원자 구성을 분석하는 분광법이다. 라만 분광법은 레이저를 물질 표면에 조사시켜 산란되는 빛을 측정하여 분자구조를 분석하는 분광법이다. 이 두 가지 분광법은 각각 미지의 광물의 원자 분자를 분석하는 상호보완적인 분광법으로 우주탑재체로서 효율적인 장점을 가지고 있다. 본 연구에서는 주성분 분석법(Principal Component Analysis, PCA)을 활용하여 광물을 정성적으로 분석했다. 또한, 두 가지 광물을 혼합한 시료를 제작하여 구성 성분 비율에 따른 신호 세기로부터 물질의 구성 비율을 예측하는 정량분석을 시행하였다.

다양한 환경요인과 난분해성 유기물에 따른 고온산화 및 UV산화방식 총 유기탄소 산화율 변화 (Influences of Environmental Conditions and Refractory Organic Matters on Organic Carbon Oxidation Rates Measured by a High Temperature Combustion and a UV-sulfate Methods)

  • 정헌재;이보미;이근헌;신현상;허진
    • 한국물환경학회지
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    • 제32권1호
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    • pp.98-107
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    • 2016
  • This study examined the effects of environmental conditions and the presence of refractory organic matter on oxidation rates of total organic carbon (TOC) measurements based on high temperature combustion and ultraviolet-sulfate methods. Spectroscopic indices for prediction of oxidation rates were also explored using the UV spectra and fluorescence excitation-emission matrix (EEM) of humic acids. Furthermore, optimum TOC instrument conditions were suggested by comparing oxidation rates of a standard TOC material under various conditions. Environmental conditions included salts, reduced ions, and suspended solids. Salts had the greatest influence on oxidation rates in the UV-sulfate method. However, no effect was detected in the high temperature combustion method. The UV-sulfate method showed lower humic substance oxidation rates, refractory natural organic matter, compared to the other methods. TOC oxidation rates for the UV-sulfate method were negatively correlated with higher specific-UV absorbance, humification index, and humic-like EEM peak intensities, suggesting that these spectroscopic indices could be used to predict TOC oxidation rates. TOC signals from instruments using the UV-sulfate method increased with increasing chamber temperature and increasing UV exposure durations. Signals were more sensitive to the former condition, suggesting that chamber temperature is important for improving the TOC oxidation rates of refractory organic matter.

Rapid Soil Quality Assessment for Sustainable Agricultural Systems at Songco, Lantapan, Bukidnon, Philippines

  • Daquiado, Nonilona P.
    • 한국환경농학회:학술대회논문집
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    • 한국환경농학회 2011년도 30주년 정기총회 및 국제심포지엄
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    • pp.177-187
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    • 2011
  • This study was conducted to determine some physical and chemical properties of the soil and their relationship to spectroscopic-based (visible range) analytical methods while evaluating soil organic matter fractions and soil quality in degraded and non-degraded soils in a wide range of environments. Soil samples were collected from the different landscape positions of cultivated and noncultivated soils, and the latter from the same landscape positions but with different vegetation, at Songco, Lantapan, Bukidnon. The physical and chemical properties of the soils were determined at the SPAL, CMU, Musuan, Bukidnon while the metagenomic properties were determined at the Laboratory of the University of Missourri, Missourri, USA. Bulk density and air dry soil strength values of the soils from the cultivated areas were generally higher than those of the uncultivated areas. Also, soils at the summit generally had lower bulk density and soil strength values than the other landscape positions. Moreover, soils planted to camote (Ipomoea batatas) had higher bulk density and soil strength values compared to soils grown to pepper under the trees. Exchangeable calcium (Ca), magnesium (Mg), and potassium (K) and cation exchange capacity (CEC) of the soils were generally higher in uncultivated areas than those of the cultivated areas. A similar trend was observed for the potassium permanganate ($KMnO_4$)-oxidizable organic C contents determined by spectroscopic method and the total C contents determined by the Walkley-Black method. The $KMnO_4$-oxidizable organic C contents determined by spectroscopic method and the total C contents determined by the Walkley-Black method were closely related ($r=0.631^{**}$). Hence, the former method shows promise in assessing soil quality as it is a rapid test, relatively low cost and can be distributed as a field kit either with a portable spectrometer or with a color chart.

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규칙화 역과정 방법을 이용한 Ar-Ar의 분자간 위치에너지 결정 (The Intermolecular Potential of Ar-Ar by Regularized Inverse Method)

  • 김화중;김영식
    • 대한화학회지
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    • 제40권1호
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    • pp.20-27
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    • 1996
  • 분광학적 실험 자료들로부터 안정하고 정확한 위치에너지를 역으로 얻어내는 방법에 대하여 연구하였다. 이러한 역과정 방법은 비선형 역과정 문제에서 야기되는 불안정성을 위치에너지가 유연하게 연속적이라는 제한 조건을 사용하여 최적의 해를 얻어내는 Tikhonov의 규칙화에 기초를 두고 있다. 이 방법의 장점은 특정한 형태의 위치에너지 변수를 맞추는 보통의 방법과는 달리 위치에너지를 분자간 거리의 연속함수로 다루었다. 이 방법을 실험적으로 얻은 Ar-Ar계의 분광학적 자료에 적용하여 전 구간에서 정확한 위치에너지를 찾아가는 것을 보여주었고, Morse나 RKR 방법으로 얻은 위치에너지의 부정확한 먼거리 인력 부분을 보정할 수 있음을 보여주었다.

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분광 분석법에 의한 고압 수은등의 온도분포 측정 (Temperature Distribution Measurement of High-pressure Mercury Lamp using Spectroscopic Method)

  • 김상용;김창섭;지철근
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 1989년도 추계학술발표회논문집
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    • pp.13-18
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    • 1989
  • Temperature distribution of 250W high-pressure mercury lamp has been measured by the spectroscopic method using relative intensities of spectral lines. To obtain radial temperature distribution, the measured intensity which was integrated along the line of sight was transformed into radial line intensity by Abel's inversion. Temperature was determined from relative intensities of spectral lines of the same atomic species. The measured temperature of 250W high-pressure mercury lamp is 6000K at the axis. In this experiment temperature profile of high-pressure arc is papabolic as known.

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The Application of Time-Resolved Laser Induced Fluorescence Spectroscopy in the Complexation Studies of Eu(III) and Cm(III) with Humic Substances

  • Joong Gill Choi;Oum Ka Won;Chang Yeoul Choi;Hichung Moon;Hyun Sang Shin;Park, Seung Min;Paul Joe Chong
    • Bulletin of the Korean Chemical Society
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    • 제14권1호
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    • pp.72-78
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    • 1993
  • The application of time-resolved laser induced fluorescence spectroscopy (TRLIF) to the complexation studies of Eu(III) and Cm(III) with humic substances is described. Using this method, three different spectroscopic characteristics(excitation spectra, emission spectra, and lifetimes) of these aquo ions and their complexes can be directly measured. By observing shifts in the wavelength and changes in the lifetime and intensities of the fluorescence emission, the information on the complexation behavior of humic substances with these trivalent metal cations in an aqueous solution, as well as energy transfer mechanisms, can be obtained. In addition, this method allows precise spectroscopic quantification of the complexation processes at very low concentrations of both components.

Complex Detection Between Transcription Regulator and Promoter DNA by UV Spectroscopic Method

  • Lee, Kyungmin;Gang, Jongback
    • 통합자연과학논문집
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    • 제5권3호
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    • pp.163-167
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    • 2012
  • UV spectrophotometer was used to detect protein-DNA complex from DNA melting profile under constant temperature increase. Melting temperature (Tm) was $43^{\circ}C$ in copA duplex DNA alone. In the presence of Proteus mirabilis transcription regulator protein (PMTR) protein at 0.2 and 0.4 ${\mu}M$, Tm's were $45{\pm}0.5$ and $47.6{\pm}0.6^{\circ}C$, respectively. According to fluorescence polarization and gel shift assay. PMTR:copA complex was detected by the retarded migration on gel and the dissociation constant ($K_d$) was $(9.2{\pm}2.8){\times}10^{-9}M$.