• 제목/요약/키워드: Spectroscopic data

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국내 토양 휴믹물질의 특성 규명 및 DB 구축에 대한 연구 (Characterization of Humic and Fulvic Acids Extracted at the Soils of Korea and Its DB Establishment)

  • 이창훈;유지호;신현상;정근호;이창우
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2003년도 총회 및 춘계학술발표회
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    • pp.397-400
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    • 2003
  • In this study, humic and fulvic acids in soils at the vicinity of domestic atomic power plants(NPPs), located in Yungkwang(YK), Uljin(UJ), Kori(KR), Koseong(KS), Wolseong(WS) area, and in volcanic ash soils of the Cheju island(Mt. Hanla(HL), Manjanggul(MJ)) were isolated, and characterized using chemical(elemental analysis, proton exchange capacity, molecular size distribution) and spectroscopic(UV/Vis., IR, FL, $^{13}$ C NMR spectra) methods. The results were compared with one another and compiled for their DB establishments. The humic substances distribution (humic acid, fulvic acid, Humin) in the soils were also determined by IHSS standard method. Main purpose of this study was to provide a basic data needed to evaluate the effect of humic substances on the migrational behaviour of radioactive elements in contaminated surface soil.

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Surface-Enhanced Raman Spectroscopic Studies of Oriented Monolayers on Electrode Surfaces

  • Yoon, Wan-Shik;Im, Jung-Hyuk;Kim, Jae-Ho
    • 분석과학
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    • 제8권4호
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    • pp.699-705
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    • 1995
  • Monolayers of hypericin, a photodynamic polycyclic quinoidal compound, were prepared at the air-water interface, and were transferred to metal substrates to form Langmuir-Blodgett (LB) monolayers. The structural characteristics of hypericin LB monolayers and self-assembled (SA) monolayers were investigated using surface-enhanced resonance Raman scattering (SERRS) spectroscopy. Both the spectroscopic data and the surface pressure - area (${\pi}-A$) isotherms suggest that hypericin forms ${\pi}-{\pi}$ aggregates that orient vertically to the subphase surface. Whereas the ordering and orientation of control was less effective in SA monolayers, a higher structural regularity was attained in LB systems. The effect of subphase on the structural integrity of the monolayer was also investigated.

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Potentially Bioactive Two New Natural Sesquiterpenoids from the Rhizomes of Zingiber zerumbet

  • Jang Dae Sik;Seol Eun Kyoung
    • Archives of Pharmacal Research
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    • 제28권3호
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    • pp.294-296
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    • 2005
  • Repeated chromatography of the n-hexane-soluble fraction of the MeOH extract of the rhizomes of Zingiber zerumbet led to the isolation of two isomers of 6-methoxy-2E,9E-humula-dien-8-one (1 and 2) and stigmast-4-en-3-one. The structures of 1 and 2 were determined by spectroscopic methods including 10 and 2D-NMR elucidated by analysis of spectroscopic data as well as by comparison with published values. This is the first report on the isolation of compounds 1 and 2 from the nature. Stigmast-4-en-3-one was first isolated from this plant.

Spectroscopic study of Planetary hosting star HD 20794

  • Rittipruk, Pakakaew;Yushchenko, Alexander V.;Kang, Young-Woon
    • 천문학회보
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    • 제41권1호
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    • pp.43.4-44
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    • 2016
  • We observed the high resolution spectra of a solar-neighborhood planetary hosting star HD 20794. The analysis of spectroscopic data was performed using URAN and SYNTHE programs. These spectra allow us to determine the effective temperatures, surface gravities, microturbulent velocities and, chemical abundances. Bond et al. (2008) found chemical abundance for 11 elements, but using the Spectrum synthesis method we have so far determine about 30 elements. We have derived iron metallicity $[FeI/H]=-0.42{\pm}0.03$, $[FeII/H]=-0.43{\pm}0.012$, and surface gravity, log g = 4.48, in good agreement with values from previous investigation.

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Cosmic Web traced by ELGs and LRGs from the Multidark Simulation

  • 김도일
    • 천문학회보
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    • 제41권1호
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    • pp.72.1-72.1
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    • 2016
  • Current and planned large-volume surveys such as the Sloan Digital Sky Survey extended Baryon Oscillation Spectroscopic Survey (SDSS IV-eBOSS) or the Dark Energy Spectroscopic Instrument (DESI) will use Luminous Red Galaxies (LRGs) and Emission Line Galaxies (ELGs) to map the cosmic web up to z~1.7, and will allow one to accurately constrain cosmological models and obtain crucial information on the nature of dark energy and the expansion history of the Universe in novel epochs - particularly by measuring the Baryon Acoustic Oscillation (BAO) feature with improved accuracy. To this end, we present here a study of the spatial distribution and clustering of a sample of LRGs and ELGs obtained from a sub-volume of the MultiDark simulation complemented by different semi-analytic prescriptions, and investigate how these two different populations trace the cosmic web at different redshift intervals - along with their synergy. This is the first step towards the interpretation of upcoming ELG and LRG data.

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Effective Characterization Methods of Polycrystalline Silicon Films Fabricated by Ni Induced Crystallization

  • Koo, Hyun-Woo;Maidanchuk, Ivan;Jung, Jae-Wan;Lee, Ki-Yong;Berkeley, Brian H.;Kim, Sang-Soo
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.250-253
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    • 2009
  • Effective methods for monitoring the quality of polycrystalline silicon (poly-Si) films are discussed. Raman spectroscopy is typically used to determine crystallinity of poly-Si, but this method has limitations for data gathering on large substrates for mass production of poly-Si TFT backplanes. Spectroscopic ellipsometry is proposed as an alternative for fast and simple estimation of poly-Si quality on large substrates. By using both ellipsometry and Raman spectroscopy, it is possible to determine whether the quality and uniformity of the poly-Si films meet the criteria required for mass production of TFT backplanes for AMOLED panels.

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The Weatherproof Detection System of Sea Fog by Remote Sensing and its Applications

  • Bao, Xianwen;Wang, Xin;Sun, Litan;Zhou, Faxiu
    • 대한원격탐사학회:학술대회논문집
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    • 대한원격탐사학회 2003년도 Proceedings of ACRS 2003 ISRS
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    • pp.1380-1382
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    • 2003
  • Detection of sea fog by remote sensing with spectroscopic analysis method and structural analysis method is introduced in this paper. On this base, designing principles and frame of weatherproof detection system of sea fog by remote sensing are systemically explained. Using GMS5 and NOAA visible and infrared channel data, progresses of sea fog on yellow sea on April 17,18, 2001 is monitored which accord with the observing.

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Antioxidant and antimicrobial constituents of Crucianella maritima L.

  • Badr, Jihan M.
    • Natural Product Sciences
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    • 제14권4호
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    • pp.227-232
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    • 2008
  • Phytochemical further investigation of the chloroform extract of the aerial parts of Crucianella maritima L. (Rubiaceae) growing in Egypt resulted in the isolation of a new anthraquinone; 3-formyl-1-hydroxy-2-methoxy anthraquinone (3) along with the four known compounds isolated for the first time from the genus Crucianella; alizarin-1-methyl ether (2), 1,4-dihydroxy-2-methoxy anthraquinone (5), 1, 3, 6-trihydroxy-2-methoxy anthraquinone (7) and the flavonol kaempferol (8), beside four known compounds previously isolated from the same plant. The structures of the isolated compounds were established based on different spectroscopic data including UV, IR, EIMS, 1D and 2D-NMR. Moreover, the antioxidant and antimicrobial activities of the isolated compounds were evaluated.

Magnetic and Spectroscopic Studies of some Oxovanadium(IV) Complexes having O = V(O)$_4$ Chromophore

  • Choi, Sung-Nak;Kim, Young-Inn;Shim, Yoon-Bo;Choo, Hi-Shik;Kim, Young-Jin
    • Bulletin of the Korean Chemical Society
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    • 제10권2호
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    • pp.138-142
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    • 1989
  • Three oxovanadium(IV) complexes with bidentate ligands having only oxygen donor atoms, benzohydroxamic acid (Hben), 8-hydroxyquinoline-N-oxide(Hhqno) and picolinic acid-N-oxide (Hpicn) are prepared and magnetic and spectroscopic properties are investigated for the complexes $VO(ben)_2,\;VO(hqno)_2\;and \;VO(picn)_2.$ Magnetic data together with IR results strongly indicate that dimeric intermolecular interaction is significant in $VO(ben)_2$ while the presence of polymeric V-O${\cdot}{\cdot}$V-O interaction is suggestive in $VO(picn)_2$. For all three complexes, three electronic d-d transitions were observed; extremely strong optical absorption of these bands of $VO(ben)_2$ in DMSO are supposed to be arised from a great metal-ligand covalency. Some fundamental vibration modes of oxovanadium(IV) complexes were empirically assigned from the differences in the spectrum of metal complexes with free ligand.

Spectroscopic Studies on the Interaction of N-alkyl Phenothiazines with Bovine Serum Albumin

  • Seetharamappa, J.;Shaikh, S.M.T;Kamat, B.P.
    • Journal of Photoscience
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    • 제12권1호
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    • pp.25-32
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    • 2005
  • Binding of N-Alkyl phenothiazines (NAP) to bovine serum albumin (BSA) was studied by spectroscopic methods.It was found that the phenothiazine ring common to all drugs makes major contribution to interaction. However, the nature of alkylamino group at position 10 influences the protein binding significantly. Stern-Volmer plots indicated the presence of static component in the quenching mechanism. The high magnitude of rate constant of quenching indicated that the process of energy transfer occurs by intermolecular interaction and thus the drug-binding site is in close proximity to tryptophan residues of BSA. Binding studies in presence of hydrophobic probe, 8-anilino-1-naphthalein-sulphonic acid showed that there is hydrophobic interaction between drug and the probe and they do not share common sites in BSA. Thermodynamic parameters obtained from data at different temperatures showed that the binding of NAP to BSA predominantly involve hydrophobic forces. The effects of some cations and anions common ions were investigated on NAP-BSA interactions. The CD spectrum of BSA in presence of drug showedthat binding of drug leads to change in the helicity of the protein.

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