• 제목/요약/키워드: Spectroscopic data

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Synthesis and Characterization of Copper(Ⅱ) Complex Containing 2,2'-dipyridylbenzamide

  • 이동환;김병순;오영희;라명수;장원길
    • Bulletin of the Korean Chemical Society
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    • 제17권9호
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    • pp.836-839
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    • 1996
  • A new copper complex containing 2,2'-dipyridylbenzamide(dpba), Cu(dpba)(NO3)2(CH3CN), has been synthesized and characterized. The crystal structure has been determined. Crystal data: space group P212121, Z=8, a=13.911(3) Å, b=16.813(3) Å, c=18.932(3) Å, V=4427.9(1) Å3 and R=0.0674 for 1716 reflections. The copper environment is square pyramidal containing acetonitrile in axial site. Spectroscopic properties has been characterized in solution state. The redox property of the Cu(dpba)(NO3)2 complex is different from that of corresponding copper-dpa complex.

Unsual Cytotoxic Phenethylamides form Xenerhabdus nemetophilus

  • 백선국;박영환;서승일;김현수;이인선;박명광;이천수;박선호
    • Bulletin of the Korean Chemical Society
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    • 제22권4호
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    • pp.372-374
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    • 2001
  • Three simple carboxamides incorporating the phenethylamine moiety have been isolated from strain XR-NC of a symbiotic bacterium Xenorhabdus nematophilus. Their structures were identified by spectroscopic data and synthesis. The compounds exhibited significant cytotoxicities against human cancer-cell line, viz. the gastric adenocarcinoma, colon adenocarcinoma and lung adenocarcinoma.

방선균 분리주 No. 2511-5로부터 포스포리파제 C 저해물질 스코파훈진의 분리 (Isolation of Scopafungin, a Potent Inhibitor of Phospholipase C from Actinomycetes isolate No. 2511-5)

  • 오원근;이현선;안순철;김보연;박문수;민태익;안종석
    • 약학회지
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    • 제39권5호
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    • pp.554-559
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    • 1995
  • MT 2511-5 was purified as a inhibitor of phospholipase C(PLC) from culture broth of a Streptmyces sp. NO. 2511-5. It was identified as scopafungin, 36-membered marcrolide by physico-chemical and spectroscopic data. Its $IC_{50}$ was 30.mu.M against phospholipase C and it also showed inhibitory activity against some fungi.

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A New 24-Nor-Lupane-Glycoside of Acanthopanax trifoliatus

  • Kiem, Phan-Van;Minh, Chau-Van;Cai, Xing-Fu;Lee, Jung-Joon;Kim, Young-Ho
    • Archives of Pharmacal Research
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    • 제26권9호
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    • pp.706-708
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    • 2003
  • A new 24-nor-lupaneglycoside was isolated from the leaves of Acanthopanax trifoliatus. Based on spectroscopic data its chemical structure was determined as 24-nor-11$\alpha$-hydroxy-3-oxo-lup-20(29)-en-28-oic acid 28-Ο-$\alpha$-L-rhamnopyranosyl-(1$\rightarrow4)-\beta-D-glucopyranosyl-(1\rightarrow6)-\beta$-D-glucopyranosyl ester.

VIS/NIR 스펙트럼 측정모드에 따른 신고 배의 당도 예측성능 비교 (Comparison of Performance of Measuring Method of VIS/NIR Spectroscopic Spectrum to Predict Soluble Solids Content of 'Shingo' Pear)

  • 서상룡;이경환;유승화;유수남;최영수
    • Journal of Biosystems Engineering
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    • 제36권2호
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    • pp.130-139
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    • 2011
  • Three modes of VIS/NIR spectroscopic measurement (interactance and two modes of transmission) were compared for their ability to estimate soluble solids content (SSC) of 'Shingo' pear non-destructively. The two transmission modes are named as full- and semi-transmission, where full-transmission stands for passing of light through abdomen of pear and semi-transmission is for transit of light mainly through flesh of pear. For comparison of the modes, prediction models developed from the collected spectroscopic data by the three modes were developed and tested for comparison of their performance. Partial least square regression (PSLR) was used to develop the models and various pre-processing methods were applied to develop models of high accuracy. The experiment was repeated three times with pears produced in different regions. The experiments resulted that selection of pre-processing is very important to attain accurate models, and multiplicative scatter correction (MSC) was selected as a pre-processor of high accuracy for the three modes of spectroscopic measurement in every experiment. Except for MSC, different group of pre-processing methods were selected for the three modes of measurement in every experiment without any tendency to the tested modes of measurement and pears of different produced region. Root-mean-square error of prediction (RMSEP) of prediction models of the three modes of measurement using prepreocessor of MSC were compared for their ability to estimate SSC. The models resulted in ranges of $0.37{\sim}0.57^{\circ}Brix$, $0.65{\sim}0.72^{\circ}Brix$, $0.39{\sim}0.51^{\circ}Brix$ for interactance, full- and semi-transmission, respectively. As shown, modes of semi-transmission and interactance resulted about the same level of prediction accuracy and were noted as modes of high performance to predict SSC.

NMR Spectroscopic Study of Quinolone Carboxylic Acid Derivatives

  • Dongsoo Koh;Lee, Inwon;Park, Jongmin;Lee, Hyeseung;Yoongho Lim
    • 한국자기공명학회논문지
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    • 제3권1호
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    • pp.52-59
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    • 1999
  • Authors synthesized common intermediates which are applicable for potential antibiotics. Their complete 13C and 1H NMR chemical shift data as well as carbon-and proton-fluorine coupling constants are reported. The knowledge of proton and carbon-fluorine coupling constants may help one assign the NMR data of the fluorinated quinolone derivatives. These results agree with the data published previously.

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NIR Spectroscopic Observation of Ultra-Long GRB 111209A and The Early Afterglow

  • Lee, Sang-Yun;Im, Myungshin
    • 천문학회보
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    • 제41권2호
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    • pp.63.1-63.1
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    • 2016
  • We observed Ultra-Long GRB 111209A using NASA's 3m InfraRed Telescope Facility (IRTF). The observation was started around 40 min later than T0 = 07:12:08 UT of Swift's BAT, lasted for 24 min. The spectrum was extracted using Spextool package. The NIR SEDs show power law distribution indicating afterglow emission from the GRB according to the fireball model with beta ~ 1.2. Also they do not show thermal emission component compared to the SED of "Christmas burst" GRB 101225A. Because there is no other NIR data with this observation epoch, this data can be compared only with TAROT-R band. It seems NIR data has the same flare which exists in R band as an optical flare.

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Herschel/SPIRE Galaxies in the NEP-Wide Field - Preliminary Results

  • Kim, Seong Jin;Jeong, Woong-Seob;Lee, Hyung Mok
    • 천문학회보
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    • 제41권1호
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    • pp.66.3-66.3
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    • 2016
  • We report preliminary results from our analyses on the star-forming galaxies in the Herschel/SPIRE survey data over the AKARI/NEP-Wide Field. In this work, we utilize a combination of the SPIRE point source catalogue containing ~ 4,800 sources distributed over the wide (5.6 sq. deg) field and the spectroscopic redshift (zSPEC) data for 1790 selected targets obtained by MMT/Hectospec and WIYN/Hydra. Our analyses take advantages of multi-wavelengths photometric data (28 bands at most) covering from u* to $500{\mu}m$ band as well as continuous MIR wavelengths sampling by AKARI and WISE (4 to $25{\mu}m$). Various physical properties such as total infrared luminosity (LTIR), star formation rate (SFR), and luminosity functions (LFs) will be presented.

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3D Nano Object Recognition based on Phase Measurement Technique

  • Kim, Dae-Suk;Baek, Byung-Joon;Kim, Young-Dong;Javidi, Bahram
    • Journal of the Optical Society of Korea
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    • 제11권3호
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    • pp.108-112
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    • 2007
  • Spectroscopic ellipsometry (SE) has become an important tool in scatterometry based nano-structure 3D profiling. In this paper, we propose a novel 3D nano object recognition method by use of phase sensitive scatterometry. We claims that only phase sensitive scatterometry can provide a reasonable 3D nano-object recognition capability since phase data gives much higher sensitive 3D information than amplitude data. To show the validity of this approach, first we generate various $0^{th}$ order SE spectrum data ($\psi$ and ${\Delta}$) which can be calculated through rigorous coupled-wave analysis (RCWA) algorithm and then we calculate correlation values between a reference spectrum and an object spectrum which is varied for several different object 3D shape.

A BVR Photometric Survey of the Small Magellanic Cloud with a Mosaic CCD

  • Lee, Ki-Won
    • 한국지구과학회지
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    • 제34권5호
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    • pp.415-427
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    • 2013
  • We performed a BVR photometric survey for the entire Small Magellanic Cloud (~26 deg 2 ) with a mosaic system, Wide Field Imager (WFI), covering three seasons: September and October 2001 and November 2002. Through the usual data reduction procedures, we present ~0.73 million catalogue stars brighter than 19 magnitude in B amongst a total of ~1.3 million and compare them with published astrometry and photometry results. We found that the average differences between our and the published data are ~0.7 arcsec in astrometry and 0.065, 0.054, and 0.163 in B, V, and R, respectively, in photometry. In addition, using the 2dF spectroscopic data from Evans et al. (2004), we determined the color excesses in (B-V) and (V-R) to be $0.086{\pm}0.156$, and $0.065{\pm}0.112$, respectively, while for the distance modulus, we obtained $18.55{\pm}1.05$.