• 공업화학
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• 제33권5호
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• pp.496-501
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• 2022

본 연구에서는 석유 정제 부산물인 석유계 잔사유를 이용하여 리튬이차전지용 음극재를 제조하였다. 석유계 잔사유 중 열분해 연료유(pyrolysis fuel oil, PFO), 유동접촉분해 데칸트 오일(fluidized catalyst cracking-decant oil, FCC-DO), 감압잔사유(vacuum residue, VR)를 탄소 전구체로 사용하였다. MALDI-TOF, 원소분석(EA)을 통하여 석유계 잔사유의 물리화학적 특징을 확인하였고, 잔사유로부터 제조된 음극재는 XRD, Raman 등의 분석을 통해 그 구조적 특징을 평가하였다. VR은 PFO 및 FCC-DO에 비하여 광범위한 분자량 분포와 많은 양의 불순물을 함유하는 것을 확인할 수 있었고, PFO와 FCC-DO는 거의 유사한 물리화학적 특징을 나타내었다. XRD 분석결과로부터 탄화된 PFO와 FCC-DO는 유사한 d₀₀₂값을 나타내었다. 그러나 Lc 및 La값에서는 FCC-DO가 PFO보다 더 발달된 층상구조를 갖는 것으로 확인되었다. 또한, 전기화학적 특성 평가에서는 FCC-DO가 가장 우수한 사이클 특성을 나타내었다. 이러한 석유계 잔사유의 물리화학적, 전기화학적 결과로 미루어 보아 FCC-DO가 PFO와 VR보다 더 우수한 리튬이차전지용 탄소 전구체인 것으로 사료된다.

• 한국과학예술포럼
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• 제31권
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• pp.171-180
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• 2017

본 연구는 최근 건강, 웰빙에 대한 관심이 증가함에 따라, 공공의 다수가 이용하는 공공보건시설이 국민건강 증진에 기여하는 색채환경 구축을 위한 색채이미지 특성을 분석하여 공공보건색채 계획 및 지표개발의 데이터로 활용하고자 하는 것을 목적으로 한다. 이를 위하여 기존 관련 선행연구 결과를 종합하였고, 공공보건시설을 유형별로 의료시설(종합병원), 보건시설(보건소), 준치유시설(요양시설)로 구분하였다. 총 18곳의 공공보건시설을 직접 방문하여 측색기로 환경색채를 측색하여 환경색채이미지를 분석하였고, 이에 대한 결과 및 선행연구 결과와 비교분석하여 색채이미지 특성 및 향후 보완할 점들을 도출하였다. 결과는 다음과 같다. 첫 번째, 공공보건시설의 환경색채이미지 어휘와 관련된 선행연구에서는 편안하고 밝은 긍정적인 이미지를 선호하는 것으로 나타났다. 두 번째, 공공보건시설의 환경색채를 직접 측색한 결과, 대부분 Y계열의 고명도, 저채도 색상을 사용하고 있는 것으로 나타났다. 세 번째, 공공보건시설의 환경색채이미지 어휘를 분석한 결과, '내츄럴한' 이미지가 가장 높은 빈도를 나타내었고, 그 외 '은은한', '점잖은' 등의 이미지가 나타나고 있는데, 공공보건시설의 색채이미지어휘간의 특성을 파악하기가 어려웠다. 본 연구는 색채과학과 환경디자인 분야의 융합연구로서, 디자인과 관련된 다학제적 연구 범위를 넓혔으며, 사용자 감성 중심의 환경계획에 도움이 될 것으로 사료된다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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• pp.360-360
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• 2012

Zn-Sn-O (Zinc-Tin-Oxide; ZTO) thin films have been gaining extensive academic and industrial attentions owing to a semiconducting channel materials applicable to large-sized flat-panel displays. Due to the constituent oxides i.e., ZnO and SnO2, the resultant Zn-Sn-O thin films possess artificially controllable bandgaps and transmittances especially effective in the visible regime. The current approach employed RF sputtering in depositing the Zn-Sn-O thin films onto glass substrates at ambient conditions. This work places its main emphases on the electrical/optical features which are closely related to the combinations of processing variables. The electrical characterizations are performed using dc-based current-voltage characteristics and ac-based impedance spectroscopy. The optical constants, i.e., refractive index and extinction coefficient, are calculated through spectroscopic ellipsometry along with the estimation of bandgaps. The charge transport of the deposited ZTO thin films is based on electrons characteristic of n-type conduction. In addition to the basic electrical/optical information, the delicate manipulation of n-type conduction is indispensible in diversifying the industrial applications of the ZTO thin films as active devices in information and energy products. Ultimately, the electrical properties are correlated to the processing variables along with the underlying mechanism which largely determines the electrical and optical properties.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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• pp.355-355
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• 2016

There has been an explosive development of nanocrystal (NC) synthesis and application due to their composition-dependent specific properties. Despite the composition, shape, and size of NCs foremost determine their physicochemical properties, the surface state and molecule conjugation also drastically change their characteristics. To make practical use of NCs, it is a prerequisite to understand the NC surface state and the degree to which they have been modified because the reaction occurs on the interface between the NCs and the surrounding medium. We report in here an analysis method to identify conjugated ligands and their binding states on semiconductor nanocrystals based on their molecular information. Surface science techniques, such as time-of-flight secondary-ion mass spectrometry (ToF-SIMS) and FT-IR spectroscopy, are adopted based on the micro-aggregated sampling method. Typical trioctylphosphine oxide-based synthesis methods of CdSe/ZnS quantum dots (QDs) have been criticized because of the peculiar effects of impurities on the synthesis processes. Since the ToF-SIMS technique provides molecular composition evidence on the existence of certain ligands, we were able to clearly identify the n-octylphosphonic acid (OPA) as a surface ligand on CdSe/ZnS QDs. Furthermore, the complementary use of the ToF-SIMS technique with the FT-IR technique could reveals the OPA ligands' binding state as bidentate complexes.

• 천문학회지
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• 제38권2호
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• pp.303-306
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• 2005

Transient luminous events (TLEs; sprites, elves, jets and etc.) are lightning-related optical flashes occurring above thunderstorms. Since the first discovery of sprites in 1989, scientists have learned a great deal about the morphological, spectroscopic and electromagnetic characteristics of TLEs through ground and spacecraft campaigns. However, most of the TLE studies were based on events recorded over US High Plains. To elucidate the possible biasing effects, space-borne observations are needed and have their merits. Imager of sprites and Upper Atmospheric Lightning (ISUAL) on the FORMOSAT-2 satellite is the first instrument to carry out a true global measurement of TLEs from a low- earth orbit. In this short paper, we apply a common astronomical data analysis technique, two-color diagram, on the ISUAL spectrophotometer (SP) data. By choosing appropriated bandpasses and converting the measured flux of TLEs into the unit of magnitude, two-color diagrams of TLEs can be constructed. We demonstrate that two-color diagrams, which were constructed from the narrow-band spectrophotometer data, can be used to classify different types of TLEs and trace their temporal evolution. The amount of reddening due to Earth's atmosphere can also be estimated from two-color diagrams assembled from the broad-band spectrophotometer data.

• Bulletin of the Korean Chemical Society
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• 제23권2호
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• pp.281-285
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• 2002

The photophysical properties and the singlet oxygen generation efficiencies of meso-tetraphenyl-trithiasapphyrin $(S_3TPS)$ and meso-tetmkis(p-methoxy phenyl)-trithiasapphy rin ((p-MeO)-$S_3TPS$) have been investigated, utilizing steady-state and time-resolved spectroscopic methods to elucidate the possibility of their use as photosensitizers for photodynamic therapy (PDT). The observed photophysical properties were compared with those of other porphyrin-like photosensitizers in geometrical and electronic structural aspects, such as extended ${\pi}$ conjugation, structural distortion, and internal heavy atoms. The steady-state electronic absorption and fluorescence spectra were both red-shifted due to the extended ${\pi}$-conjugation. The fluorescence quantum yields were measured as very small. Even though intersystem crossing rates were expected to increase due to the increment of spin orbital coupling, the triplet quantum yields were measured as less than 0.15. Such characteristics can be ascribed to the more enhanced internal conversion rates compared with the intersystem crossing rates. Furthermore, the triplet state lifetimes were shortened to -1.0 ${\mu}s$ as expected. Therefore, the singlet oxygen quantum yields were estimated to be near zero due to the fast triplet state decay rates and the inefficient energy transfer to the oxygen molecule as well as the low triplet quantum yields. The low efficiencies of energy transfer to the oxygen molecule can be attributed to the lower oxidation potential and/or the energetically low lying triplet state. Such photophysical factors should be carefully evaluated as potential photosensitizers that have extended ${\pi}$-conjugation and heavy core atoms synthesized for red-shifted absorption and high triplet state quantum yields.

• 대한원격탐사학회지
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• 제33권5_1호
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• pp.537-546
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• 2017

본 연구는 무인항공기 및 다중분광센서를 이용한 부유쓰레기 탐지 알고리즘을 개발하고자 하였다. 또한 알고리즘을 적용하여 하천의 부유쓰레기 발생 범위를 산정하였다. 부유쓰레기 탐지 구간을 대상으로 무인항공기를 이용한 항공촬영을 통해 면적 계산이 가능한 정사영상을 생성하였으며, 분광조사를 수행하여 하천수, 스티로폼, 초목류 등의 분광학적 특성을 이용한 부유쓰레기 탐지 지수식을 산출하였다. 그리고 산출된 지수식을 이용한 센서의 밴드 조합을 통해 스티로폼을 비롯한 부유쓰레기를 탐지하였다. 탐지 지수식 적용 결과 정사영상 내 총 3지점에서 대량의 부유쓰레기 집적 구간이 확인되었으며, 탐지 대상 면적 중 집적구간을 포함한 3.6%에 해당하는 0.82 ha($8,200m^2$)에서 스티로폼과 초목류를 포함한 대량의 부유쓰레기가 발생한 것으로 추정되었다.

• 한국근적외분광분석학회:학술대회논문집
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• 한국근적외분광분석학회 2001년도 NIR-2001
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• pp.1125-1125
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• 2001

Micro-scale test methods are producing small-sample size where the conventional physical and chemical tests can not be used (high standard deviation, uncertain sampling conditions, low repeatability). Different small-scale test methods were developed recently for determination of physico-chemical, functional, rheological properties of wheat or wheat dough using miniaturized instruments with sophisticated sample preparation/handling and mechanics (RVA, 2 g mixograph, micro-Z-arm mixer, small-scale noodle maker, micro-baking method etc.). The small-scale methodologies can be used as basic research tools or as technology supported measurements and can be also essential in the early selection for quality traits in breeding programs. The milling as a sample preparation step is essential procedure providing good quality flour or semolina samples from small amount of grain (5-10 g) in a reproducible and reliable way. The aim of present study was to use NIR as quality control tool, and to evaluate the recently developed and manufactured micro-scale lab mill (FQC-2000) produced by Inter-Labor Co. Ltd., Hungary. The milling characteristics of the new instrument were compared to other laboratory mills and the effects of milling action on the chemical composition of fractions were analysed. The fractions were tested with both chemical and near infrared spectroscopic methods. The micro-scale milling resulted significantly different yields, particle size distributions and different fractions from compositional point of view. The near infrared spectra were sensitive enough to distinguish the fractions obtained by different milling procedures. Quantitative NIR calibration equations were developed and tested in order to measure the chemical composition of characteristic milling fractions. Special qualification procedure the PQS (Polar Qualification System) method was used for detecting the differences between fractions obtained by macro and micro-milling procedures. The results and the limitations of PQS method in this application will be discussed.

• Spatial Information Research
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• 제18권3호
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• pp.73-83
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• 2010

본 연구는 정지장면의 연속영상간 각 픽셀위치에서 일어나는 통계적 특성을 활용하여 영상을 분할하는 기법을 제안한다. 공간정보의 획득과 분석에서 디지털 영상 처리 기법의 활용은 아주 중요한 의미를 가진다. 특히 디지털 영상의 영역 구분을 위해 다양한 영상 분할(image segmentation) 기법들이 활용되고 있다. 본 연구에서는 선행 연구한 연속프레임 영상의 분광학적 특성 분석의 결과를 바탕으로 연속 프레임 간 Randomness를 활용한 이미지 분할 방법을 제안하였다. 우선 연속 프레임 간 각 화소에 통계학적인 분석 방법을 적용하여 각 화소의 평균과 표준편차 값을 구하고, 이를 통하여 대상 영상에서 가장 신뢰할 만한 화소들을 찾아 씨앗 점(seed point)을 결정하였다. 그리고 이 씨앗 점들을 시작으로 이웃 화소 간 T-test를 실시하였으며, 이를 기반으로 영역 성장(region growing)의 개념을 적용하여 영상을 분할 할 수 있는 기법을 연구하였다. 제안방식의 성능을 검증하기 위하여 실험을 통하여 기존의 방식과 비교분석을 수행하였다. 이러한 실험의 결과 영상분할에서 영상의 단일 프레임을 활용한 것보다 연속 프레임을 활용한 경우가 유리함을 확인 할 수 있었다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 춘계학술대회 및 기술 세미나 논문집 디스플레이 광소자
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• pp.43-43
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• 2008

Recently, it is widely studied to liquid crystal (LC) alignment using ion-beam exposure. Because conventional rubbing method has some problems such as defects from dust and electrostatic charges and rubbing scratch during rubbing process. Moreover rubbing method needs cleaning process to remove these defects. Therefore rubbing-free techniques like ion-beam method are strongly required. We studied LC alignment by controlling ion-beam irradiation angles and electro-optical (EO) characteristics of twisted nematic LC on the polyimide surface. In this experiment, a good uniform alignment of the nematic liquid crystal (NLC) with the ion-beam exposure on the polyimide (PI) surface was observed. We also achieved low pretilt angle as function of ion-beam irradiation angles. X-ray photoelectron spectroscopic (XPS) analysis provided chemical evidence for LC alignment by controlling ion-beam irradiation angles. In addition, it can be achieved the good EO properties of the ion-beam-aligned twisted nematic liquid crystal display (TN-LCD) on PI surface. Some other experiments results and discussion will be included in the presentation.