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http://dx.doi.org/10.14478/ace.2022.1085

Fabrication and the Electrochemical Characteristics of Petroleum Residue-Based Anode Materials  

Kim, Daesup (Department of Applied Chemistry and Chemical Engineering, Chungnam National University)
Lim, Chaehun (Department of Applied Chemistry and Chemical Engineering, Chungnam National University)
Kim, Seokjin (Department of Applied Chemistry and Chemical Engineering, Chungnam National University)
Lee, Young-Seak (Department of Applied Chemistry and Chemical Engineering, Chungnam National University)
Publication Information
Applied Chemistry for Engineering / v.33, no.5, 2022 , pp. 496-501 More about this Journal
Abstract
In this study, an anode material for lithium secondary batteries was manufactured using petroleum-based residual oil, which is a petroleum refining by-product. Among petroleum-based residual oils, pyrolysis fuel oil (PFO), fluidized catalyst cracking-decant oil (FCC-DO), and vacuum residue (VR) were used as carbon precursors. The physicochemical characteristics of petroleum-based residual oil were confirmed through Matrix-assisted laser desorption/ionization Time-of-Flight (MALDI-TOF) and elemental analysis (EA), and the structural characteristics of anode materials manufactured from residual oil were evaluated using X-ray crystallography (XRD) and Raman spectroscopic techniques. VR was found to contain a wide range of molecular weight distributions and large amounts of impurities compared to PFO and FCC-DO, and PFO and FCC-DO exhibited almost similar physicochemical characteristics. From the XRD analysis results, carbonized PFO and FCC-DO showed similar d002 values. However, it was confirmed that FCC-DO had a more developed layered structure than PFO in Lc (Length of a and c axes in the crystal system) and La values. In addition, FCC-DO showed the best cycle characteristics in electrochemical characteristics evaluation. According to the physicochemical and electrochemical results of the petroleum-based residual oil, FCC-DO is a better carbon precursor for a lithium secondary battery than PFO and VR.
Keywords
Pyrolysis fuel oil (PFO); Fluid catalytic cracking-decant oil (FCC-DO); Vacuum residue; Structural analysis; Lithium-ion batteries;
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