• Title/Summary/Keyword: Spectroscopic characteristics

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Analysis of CaCO3 structure of marine bivalves using X-ray diffraction (해산 이매패류 패각의 CaCO3 결정 구조에 대한 X-ray 회절 분석)

  • Nam, Ki-Woong;Lee, Seng-Woo;Song, Jae-Hee;Jeung, Hee-Do;Park, Kyung-Il
    • The Korean Journal of Malacology
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    • v.31 no.4
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    • pp.279-283
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    • 2015
  • This study investigated spectroscopic characteristics of shell crystals of eight marine bivalve species using X-ray diffraction (XRD) analysis; moreover, the Family level relatedness of shellfish was investigated. In XRD analysis, the shells of Ruditapes philippinarum, Meretrix lusoria, Anadara granosa, and Fulvia mutica were found to have orthorhombic aragonite $CaCO_3$ crystals, while shells of Patinopecten yessoensis and Crassostrea gigas had trigonal-rhombohedral calcite crystals. The shells of Mytilus coruscus and Atrina pectinata were determined to have a mixture of aragonite and calcite crystals. XRD information revealed the Family level-specific characteristics of shellfish; the results agreed with the current taxonomic system. In conclusion, spectroscopic characteristics of shell crystals indicated Family-level characteristics of shellfish and suggested a more intense species-level investigation; this technology may be useful in identifying shellfish species using small quantities of shells.

A Study of Optical Characteristics Correlated with Low Dielectric Constant of SiOCH Thin Films Through Ellipsometry (Ellipsometry를 이용한 저 유전상수를 갖는 SiOCH박막의 광학특성 연구)

  • Park, Yong-Heon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.3
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    • pp.228-233
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    • 2010
  • We studied the optical characteristics correlated with low dielectric constants of low-k SiOCH thin films through ellipsometry. The low-k SiOCH thin films were prepared by CCP-PECVD method using BTMSM(Bis-trimethylsilylmethane) precursors deposited on p-Si wafer. The Si-O-CHx, Si-O-Si, Si-CHx, CHx and Si-H bonding groups were specified by FTIR spectroscopic spectra, and the groups coupled with the nano-porous structural organic/inorganic hybrid-type of SiOCH thin films which has extremely low dielectric constant close to 2.0. The structural groups includes highly dense pore as well as ions in SiOCH thin films affecting to complex refraction characteristics of single layer on the p-Si wafer. The structural complexity originate the complex refractive constants of the films, and resulted the elliptical polarization of the incident linearly polarized light source of Xe-light source in the range from 190 nm to 2100 nm. Phase difference and amplitude ratio between s wave and p wave propagating through SiOCH thin film was studied. After annealing, the amplitude of p wave was reduced more than s wave, and phase difference between p and s wave was also reduced.

Analysis of the spectroscopic characteristics of Ground color images using a digital camera (디지털 카메라를 활용한 컬러 지상영상의 분광학적 특성 분석)

  • Ko, In-Chul;Seo, Su-Young
    • Proceedings of the Korean Association of Geographic Inforamtion Studies Conference
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    • 2010.06a
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    • pp.137-144
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    • 2010
  • Ground digital image data obtained by using DSLR camera can be used to the ground photogrammetry and spatial modeling. Intensity of each pixel in digital video images is the most important parameter to generate digital image. Therefore, it is needed to estimate the parameters and spectral characteristics of digital cameras in order to take more definite intensity data. In this study, using the Sony DSC-F828 DSLR camera, seven digital images are obtained by the continuous shooting. (frame rate, 0.38 seconds). And then extract the value of the intensity from RGB band of each digital color photographs to confirm difference of intensity between frames. The purpose of this study is to confirm spectral characteristics and changes and to estimate correlation through the analysis of statistical in each pixel of R, G, B band.

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Opticsal Characteristics of Bismuth-doped Aluminosilicate Glass Codoped with Li and Ge (Bi 첨가 알루미노실리케이트 유리에서 Li 및 Ge 공첨가가 광 특성에 미치는 영향)

  • Seo, Young-Seok
    • Korean Journal of Optics and Photonics
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    • v.18 no.3
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    • pp.221-225
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    • 2007
  • The possibility of improving amplification characteristics and lowering the melting point of bismuth-doped aluminosilicate glass as a new amplification material, which has broadband near-infrared emission at 1300 nm regions, was investigated. Spectroscopic analysis of bismuth-doped aluminosilicate glass shows that the addition of an alkali metal oxide, $Li_{2}O$ increases FWHM of fluorescence spectrum but decreases fluorescence intensity, while $GeO_{2}$ composition increases both FWHM of fluorescence spectrum and fluorescence intensity. Also, excellent optical amplification gain characteristics in a $GeO_{2}$-added sample were observed.

Re-evaluation of physicochemical and NMR data of triol ginsenosides Re, Rf, Rg2, and 20-gluco-Rf from Panax ginseng roots

  • Cho, Jin-Gyeong;In, Seo-Ji;Jung, Ye-Jin;Cha, Byeong-Ju;Lee, Dae-Young;Kim, Yong-Bum;Yeom, Myeonghun;Baek, Nam-In
    • Journal of Ginseng Research
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    • v.38 no.2
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    • pp.116-122
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    • 2014
  • Ginseng roots were extracted with aqueous methanol, and extracts were suspended in water and extracted successively with ethyl acetate and n-butanol. Column chromatography using the n-butanol fraction yielded four purified triol ginseng saponins: the ginsenosides Re, Rf, Rg2, and 20-gluco-Rf. The physicochemical, spectroscopic, and chromatographic characteristics of the ginsenosides were measured and compared with reports from the literature. For spectroscopic analysis, two-dimensional nuclear magnetic resonance (NMR) methods such as $^1H$-$^1H$ correlation spectroscopy, nuclear Overhauser effect spectroscopy, heteronuclear single quantum correlation, and heteronuclear multiple bond connectivity were employed to identify exact peak assignments. Some peak assignments for previously published $^1H$-and $^{13}C$-NMR spectra were found to be inaccurate. This study reports the complete NMR assignment of 20-gluco-Rf for the first time.

[ $T_2$ ]-relaxation Time Measurement of ex vivo $^1H$ MR Metabolite Peaks for Evaluation of Human Stomach Cancer

  • Mun Chi-Woong;Choi Ki-Sueng;Shin Oon-Jae;Yang Young-Ill;Chang Hee-Kyung;Hu Xiaoping;Eun Chung-Ki
    • Journal of Biomedical Engineering Research
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    • v.27 no.2
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    • pp.53-58
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    • 2006
  • In this study, transverse relaxation time (T2) measurement and the evaluation of the characteristics of the spectral peak related to stomach tissue metabolites were performed using ex vivo proton magnetic resonance spectroscopic imaging (MRSI) at 1.5-T MRI/S instruments. Thirty-two gastric tissues resected from 12 patients during gastric cancer surgery, of which 19 were normal tissue and 13 were cancerous tissue, were used to measure the $T_2$ of the magnetic resonance spectroscopy (MRS) peaks. The volume of interest data results from the MRSI measurements were extracted from the proper muscle (MUS) layer and the composite mucosa/submucosa (MC/SMC) layer and were statistically analyzed. MR spectra were acquired using the chemical shift imaging (CSI) point resolved spectroscopy (CSI-PRESS) technique with the parameters of pulse repetition time (TR) and echo times (TE) TR/(TE1,TE2)=1500 msec/(35 msec, 144 msec), matrix $size=24{\times}24$, NA=1, and voxel $size=2.2{\times}2.2{\times}4mm^3$. In conclusion, the measured $T_2$ of the metabolite peaks, such as choline (3.21ppm) and lipid (1.33ppm), were significantly decreased (p<0.01 and p<0.05, respectively) in the cancerous stomach tissue.

DESIGN & STRUCTURAL ANALYSIS OF MULTI-OPTICAL MOUNT SYSTEME FOR TRACKING/OBSERVING ARTIFICIAL SPACE OBJECTS (인공우주물체 추적/관측을 위한 다중 광학계 탑재용 가대 설계 및 구조해석)

  • Seol, K.H.;Kim, S.J.;Jang, M.;Min, S.W.;Mun, B.S.
    • Journal of Astronomy and Space Sciences
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    • v.23 no.4
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    • pp.435-444
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    • 2006
  • Since artificial space objects are observable only in a short period of time and the characteristics of their motion is not exactly predictable, it is difficult to obtain both photometric and spectroscopic data by a set of observations. We have, therefore, designed a mount to load multi-optical instruments on the Kyung Hee University (KHU) satellite tracking and observation system for both photometric and spectroscopic observations of artificial space objects. In this paper, we have calculated the deformation of the remodeled mount using structural analyses for the loading of the multi-optical instruments. We have also deduced pointing errors of the mount occurring at tracking and observing artificial space objects. we have derived tracking reliably artificial space objects in our field of view and confirmed structural safety test of mount utilizing equivalent (von-mises) stress distribution.

Environmental Risk Assessment of Polyhexamethyleneguanidine Phosphate by Soil Adsorption/Desorption Coefficient

  • Chang, Hee-Ra;Yang, Kyung-Wook;Kim, Yong-Hwa
    • Korean Journal of Environmental Agriculture
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    • v.25 no.4
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    • pp.365-370
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    • 2006
  • This study was performed to determine the adsorption-desorption characteristics of polyhexame-thyleneguanidine phosphate in three different soil types of textural classification. Adsorption and desorption studies is impotent for prediction their fate and generating essential information on the mobility of chemicals and their distribution in the soil, water and air of our biosphere. The detection limit of the test substance quantified by a spectroscopic method using Eosin indicator was $0.25{\mu}g/mL$. The reproducibility of analytical method was confirmed by the preliminary test. The concentrations of polyhexamethylenequanidine phosphate in aqueous solution were $1.36{\pm}0.09,\;2.45{\pm}0.01,\;and\;$4.25{\pm}0.05{\mu}g/mL$ by a spectroscopic method using Eosin indicator. The adsorption percents of polyhexamethylenequanidine phosphate in soil were greater than 95.2% for all three test soils. The desorption percents from the adsorbed soil were less than 4.5, 4.7 and 4.7%. Therefore, the adsorption coefficient (K) were greater than 110, 111 and 116. The adsorption coefficient calculated as a function of the organic carbon content (Koc) of the test soils were greater than 9,181, 11,100, and 8,942, respectively. Therefore, the test substance, polyhexamethylenequanidine phosphate could be concluded as medium or high adsorption (>25%) and poorly desorption (<75%) in soil media. Therefore, this chemical is likely to be retained in soil media and may not pose a risk in the aquatic environment.

OASIS Spectral Images of the Seyfert galaxy NGC 5728 (시이펏 은하 NGC 5728의 OASIS 분광 영상)

  • Hyung, Siek;Son, Dong-Hoon;Ferruit, Pierre;Lee, Woo-Baik
    • Journal of the Korean earth science society
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    • v.27 no.5
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    • pp.569-578
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    • 2006
  • The distribution and kinematic information of the continuum, $H{\alpha},\;H{\beta}$, [O III], & [N II] images based on spectroscopic data secured with the OASIS at the Hawaii CFHT 3.6m telescope have been analyzed to study the physical characteristics of NGC 5728. The three bright regions-northwestern knot, southeastern knot, and the nucleus-exist within a $15"{\times}12"$ sky area which seem to indicate gas flows along the northwestern or western direction from the nucleus. We find that the center of a 10" diameter ring is at the northwestern knot, not at the galactic center. To further analyze the formation mechanism of such a ring, the kinematics of the nucleus and knot have been studied and the central structure of the Active Galactic Nuclei has been investigated by comparing various emission images.

Study on the Spectroscopic Characteristics of Irradiated Diamonds (전자빔 처리된 다이아몬드의 분광학적 특성 연구)

  • Shon, Shoo-Hack;Kim, Bea-Seoub;Jang, Yun-Deuk;Kim, Jong-Rang;Kim, Jong-Gun;Kim, Jeong-Jin
    • Journal of the Mineralogical Society of Korea
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    • v.22 no.4
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    • pp.407-415
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    • 2009
  • The change of the nitrogen-related centers and the color change of electron beam irradiated type Ia natural diamonds were studied. The irradiation of diamond with high-energy electron beam creates lattice defects which are neutral single vacancy $V^0$. It increased with increasing electron dose density. The B aggregation seems to produce vacancies more easily than the A aggregation, because diamonds with more B aggregation have more platelets, which are sufficient breakable size by electron beam. Greenish blue color of irradiated diamond is changed to darker with increasing electron dose density. GR1 centers with a zero-phonon line at 741 nm and phonon sidebands make transmit visible light at 530 nm and it moves to 500 nm with higher intensity of GR1 centers.