• Title/Summary/Keyword: Spectral studies

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Estimation of Brune's Stress Drops around the Korean Peninsula (한반도 인근 지진의 Brune 응력강하량(파라미터)추정에 대한 고찰)

  • Yun, Kwan-Hee;Park, Dong-Hee;Chang, Chun-Jung
    • Proceedings of the Earthquake Engineering Society of Korea Conference
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    • 2006.03a
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    • pp.70-77
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    • 2006
  • Stress drops of Brune's single-corner ${\omega}^2$ source model were estimated for the earthquakes (2.0$M3.5{\sim}4.0$ and increase up to $M4.5{\sim}5.0$ above which the level of the stress drop could be assumed to be flat or decrease according to whether the rupture process accompanies buried fault or surface rupturing. The converted data of corner frequency and seismic moment were nicely fitted to the relation of $M_0{\propto}f^3$ but show systematically higher corner frequencies for $M_0>10^15$ Nm. This relationship enables systematic evaluation of a scaling relation between magnitude and stress drop. The inverted level of the stress drop is comparable to the recent studies conducted domestic and abroad. A result of lower stress drop estimated by Jun(1991) is supposed to be due to the use of low frequency spectra and existence of two-comer source model around the Korean Peninsula.

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Reactions of Pyrimidinonethione Derivatives;Synthesis of 2-Hydrazinopyrimidin-4-one, Pyrimido[1,2-a]-1,2,4-triazine, Triazolo-[1,2-a]pyrimidine, 2-(1-pyrazolo)Pyrimidine and 2-Arylhydrazonopyrimidine Derivatives

  • Attaby, Fawzy-A.;Eldin, Sanaa-M.;Hanafi, Eman-A.Z.
    • Archives of Pharmacal Research
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    • v.20 no.6
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    • pp.620-628
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    • 1997
  • 6-Aryl-5-cyano-4-pyrimidinon-2-thione derivatives 1a-c reacted with ethyl iodide to give the corresponded 2-S-ethylpyrimidin-4-one-derivatives 2a-c. Compounds 2a-c was, in turn, reacted with hydrazine hydrate to give the sulfur free reaction products, 3a-c. These reaction products were taken as the starting materials for the synthesis of several newly synthesized heterocyclic derivatives. Reactions with several halogenated ketones, esters, chloroacetic acid and chloroacetamide give pyrimidotriazines 8,12 and 15 while their reactions with formic acid, acetic acid and carbon disulfide gave the corresponded triazolopyrimidines 17 and 21. The reaction with both acetyl acetone and ethylacetoacetate gave the corresponded 2-$(3^{I},5^{I}-dimethyl-1^{I}-pyrazoly$pyrimidine derivatives 20a-c and 24a-c respectively while the reaction with cinnamonitriles 25a-h afforded the corresponded aryl hydrazopyrimidines 27a-f. The structure of these reaction products were eatablished based on both elemental anlayses and spectral data studies.

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Development of Monitoring System for Forests Type Based on Web (Web 기반의 산림형태 모니터링시스템 개발)

  • Kim, Jin-Soo;Seo, Dong-Ju
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.12 no.2
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    • pp.321-327
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    • 2008
  • In recently, researches which appling satellite image are introduced target to the forest area. Especially, it is satellite image analysis's advantage that collecting information of terrain at the direct accesses are dangerous and impassible area. But, the studies approaching to a inflectional paradigm of forests and change detection system for the distinguished forests type are leaves much to be desired. In this study, therefore, change of forests type was analyzed using Landsat TM satellite image which have multi-spectral bands. Furthermore, change detection system for forests type was constructed on web for the periodical monitoring.

Object-oriented Classification and QuickBird Multi-spectral Imagery in Forest Density Mapping

  • Jayakumar, S.;Ramachandran, A.;Lee, Jung-Bin;Heo, Joon
    • Korean Journal of Remote Sensing
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    • v.23 no.3
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    • pp.153-160
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    • 2007
  • Forest cover density studies using high resolution satellite data and object oriented classification are limited in India. This article focuses on the potential use of QuickBird satellite data and object oriented classification in forest density mapping. In this study, the high-resolution satellite data was classified based on NDVI/pixel based and object oriented classification methods and results were compared. The QuickBird satellite data was found to be suitable in forest density mapping. Object oriented classification was superior than the NDVI/pixel based classification. The Object oriented classification method classified all the density classes of forest (dense, open, degraded and bare soil) with higher producer and user accuracies and with more kappa statistics value compared to pixel based method. The overall classification accuracy and Kappa statistics values of the object oriented classification were 83.33% and 0.77 respectively, which were higher than the pixel based classification (68%, 0.56 respectively). According to the Z statistics, the results of these two classifications were significantly different at 95% confidence level.

Electronic Absorption and Raman Spectroscopic Studies of ${\alpha},{\omega}$-Diphenylpolyenyl Anions with Odd Number of Polyene Carbons

  • Kim, Jin Yeol;Kim, Eung Ryeol;Ju, Jae Beom
    • Bulletin of the Korean Chemical Society
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    • v.22 no.8
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    • pp.837-841
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    • 2001
  • The electronic absorption and Raman spectra of $\alpha\omega-diphenylpolyenyl$, anions Ph(CH)nPh- (DPn- , n = 3, 5, 7, 9, and 13), with odd number of carbons at the polyene part, have been studied in the tetrahydrofuran (THF) solutions and in their solid film states, respectively. In the case of Raman spectra for DPn- , the frequencies and relative intensities of some Raman peaks regularly change with the increase of polyene chain length. The spectral patterns of anions (DPn- ) are very similar with those of radical anion (DPn${\cdot}$- ). However, the C=C stretching peaks of DPn- anions are observed in the 25-35 cm-1 higher frequency region than those of DPn${\cdot}$- radical anions. In the case of long chain models such as DP9- and DP13- , the C=C stretching peaks are observed in even higher frequency region than those of the corresponding neutral polyenes such as DP8, DP10, and DP12. The Raman patterns of DPn- anions in the THF solutions are similar with those in their solid film states. On the other hand, their electronic absorption spectra show a considerable difference each other. The n- ${\pi}*$ electronic absorption bands of DPn- anions in the THF solutions have been observed in the 0.27-0.39 eV lower energy region than those in their solid film states due to the solvent effects on polyene anions.

Assignment of ¹H and $^{13}C$ Nuclear Magnetic Resonances of Ganglioside $G_{A1}$

  • 이경익;전길자;류경임;방은정;최병석;김양미
    • Bulletin of the Korean Chemical Society
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    • v.16 no.9
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    • pp.864-869
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    • 1995
  • Investigation of the structures of the gangliosides has proven to be very important in the understanding of their biological roles such as regulation of differentiation and growth of cells. We used nuclear magnetic resonance spectros-copy in order to investigate the structure of GA1. In order to do this, the assignment of spectra is a prerequisite. Since GA1 does not have polar sialic acid, the spectral overlap is severe. In order to solve this problem, we use 2D NMR spectroscopy and heteronuclear 1H/13C correlated spectroscopy in this study. Here, we report the complete assignment of the proton and the carbon spectra of the GA1 in DMSO-d6-D20 (98:2, v/v). These assignments will be useful for interpreting 1H and 13C NMR data from uncharacterized oligosaccharides and for determining the linkage position, the number of sugar rings, and the sequence of new ganglioside. Amide proton in ring Ⅲ shows many interring nOes and has intramolecular hydrogen bonding. This appears to be an important factor in tertiary folding of GA1. Based on this assignment, determination of three dimensional structure of GA1 will be carried out. Studies on the conformational properties of GA1 may lead to a better understanding of the molecular basis of its functions.

Saponins from the Roots of Pulsatilla koreana

  • Kang, Sam-Sik
    • Archives of Pharmacal Research
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    • v.12 no.1
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    • pp.42-47
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    • 1989
  • From the roots of Puisatiila koreana, three monodesmosides(pulsatilla saponins A, B and D) and two bisdesmosides(pulsatilla saponins F and H) were isolated. The structure of these saponins have been determined as hederagenin 3-O-${\beta}$-L-rhamnopyranosyl($1{\to}2$)- ${\alpha}$-L-arabinopyranoside(A), hederagenin 3-O-${\beta}$-D-glucopyrano syl($1{\to}4$) - ${\alpha}$-L-arabinopyranoside(B), hederagenin 3-O- ${\alpha}$-L-rhamnopyranosyl ($1{\to}2$)-[${\beta}$-D-glucopyranosyl($1{\to}4$]-${\alpha}$-L-arabinopyranoside(D), 3-O-${\alpha}$-L-rhamnopyranosyl($1{\to}2$)-{${\alpha}$-L-arabinopyranosyl hederagenin 28-O-${\alpha}$-L-rhamnopyrano syl($1{\to}4$)-${\beta}$-D-glucopyrano syl($1{\to}6$)-${\beta}$-D-glucopyranosyI ester (F) and 3-O-${\alpha}$-L-rhamnopyranosyl($1{\to}2$)-[${\beta}$-D-glucopyranosyl($1{\to}4$)]- ${\alpha}$-L-arabinopyranosyl hederagenin 28-O-${\alpha}$-L-lharnnopyranosyl($1{\to}4$)-${\beta}$-D-glucopyranosyl($1{\to}6$)-${\beta}$-D-glucop yranosyl ester(H) on the basis of chemical and spectral studies. Pulsatilla saponin B is the first report of its presence in plants but saponins A, D, F, and H have recently been isolated from the same genus p. cernua.

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Identification of Anti-Oxidant and Anti-Tyrosinase Activity of Phenolic Components Isolated from Betula schmidtii (박달나무로부터 분리된 페놀성 화합물의 항산화 및 Tyrosinase 저해 활성 연구)

  • Wang, Da-Hye;Chung, Ha Sook
    • The Korean Journal of Food And Nutrition
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    • v.34 no.5
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    • pp.553-559
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    • 2021
  • The aim of study to investigate the phytochemicals and biological activities the bark of Betula schmidtii. The studies consisted of the solvent extraction, followed by the isolation of phenolic components 1~3 from ethyl acetate-soluble fraction of Betula schmidtii Bark. Their chemical structures were identified as arbutin (1), ρ-coumaric acid (2) and ferulic acid (3) using Ultraviolet-Visible (UV-Vis) Spectrophotometer, Electrospray Ionization Mass Spectrometry (ESI-MS) (negative ion mode), 1H-Nuclear Magnetic Resonance (NMR), 13C-NMR, 1H-1H Correlation Spectroscopy (COSY) and 1H-13C Hetero Nuclear Multiple Quantum Correlation (HMQC) spectral data. Compounds 1~3 shows the anti-oxidant effect with IC50 values of 29.74±1.52, 21.32±1.07 and 34.41±1.24 in 1,1-diphenyl-2-picrylhydrazyl (DPPH) free radical scavenging activity, respectively. Also, compounds 1~3 exhibited mushroom tyrosinase inhibitory activity with IC50 values of 31.14±1.07, 42.54±1.46 and 69.22±1.43 µM, respectively.

A Design Method of The Active Noise Controllers for The Perceived Noise Reduction (청감적 소음 감소를 위한 능동소음제어기 설계)

  • Kim, Jong-Ho;Oh, Wong-Eun
    • The Journal of the Korea institute of electronic communication sciences
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    • v.14 no.1
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    • pp.179-184
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    • 2019
  • In this paper, we propose a design method of Active Noise Control (ANC) that reduces perceived level of the residual noise. A FELMS (Filtered-E Least Mean Squares) algorithm is used for the ANC system and the NC (noise criteria) is applied as an evaluation criterion of the residual noise. With this structure, we present the allowable spectral shape of the noise shaping filter that minimizes the NC index within the effective operating frequency band of the ANC, and showed that the filter satisfying in the criterion has a lower NC value than the psychoacoustic-based filter used in the previous studies.

Spectral Characteristics of Hydrothermal Alteration in Zuru, NW Nigeria

  • Aisabokhae, Joseph;Tampul, Hamman
    • Korean Journal of Remote Sensing
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    • v.35 no.4
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    • pp.535-544
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    • 2019
  • This study demonstrated the ability of a Landsat-8 OLI multispectral data to identify and delineate hydrothermal alteration zones around auriferous prospects within the crystalline basement, North-western Nigeria. Remote sensing techniques have been widely used in lithological, structural discrimination and alteration rock delineation, and in general geological studies. Several artisanal mining activities for gold deposit occur in the surrounding areas within the basement complex and the search for new possible mineralized zones have heightened in recent times. Systematic Landsat-8 OLI data processing methods such as colour composite, band ratio and minimum noise fraction were used in this study. Colour composite of band 4, 3 and 2 was displayed in Red-Green-Blue colour image to distinguish lithologies. Band ratio ${\frac{4}{2}}$ image displayed in red was used to highlight ferric-ion bearing minerals(hematite, goethite, jarosite) associated with hydrothermal alteration, band ratio ${\frac{5}{6}}$ image displayed in green was used to highlight ferrous-ion bearing minerals such as olivine, amphibole and pyroxenes, while ratio ${\frac{6}{7}}$ image displayed in blue was used to highlight clay minerals, micas, talc-carbonates, etc. Band rationing helped to reduce the topographic illumination effect within images. The result of this study showed the distribution of the lithological units and the hydrothermal alteration zone which can be further prospected for mineral reserves.