• Title/Summary/Keyword: Spectral range

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High Durable Anti-Reflective Polymer with Silica Nanoparticle Array Fabricated by RF Magnetron Sputter (RF sputter를 이용한 실리카 증착 고 내구성 반사 방지막 제조)

  • Jeon, Seong-Gwon;Jeong, Eun-Uk;Rha, Jong-Joo;Kwon, Jung-Dae
    • Journal of the Korean institute of surface engineering
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    • v.52 no.2
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    • pp.84-89
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    • 2019
  • We fabricated durable anti-reflective(AR) layer with silica globular coating on polymer by two steps. Firstly, nano-protrusions of polymer were formed by plasma etching known as R.I.E(reactive ion etching) process. Secondly, silica globular coating was deposited on polymer nano-protrusions for mechanically protective and optically enhancing AR layers by RF magnetron sputter. And then durable antireflective polymers were synthesized adjusting plasma power and time, working pressures of RIE and RF sputtering processes. Consequently, we acquired the average transmission (94.10%) in the visible spectral range 400-800 nm and the durability of AR layer was verified to sustain its transmission until 5,000 numbers by rubber test at a load of 500 gf.

The effect of the Modified Voiced Lip Trill (MVoLT) training on vocal changes of musical theater students (응용 입술 트릴 훈련이 뮤지컬 전공 학생의 음성 변화에 미치는 효과)

  • Lee, Seung Jin;Choi, Hong-Shik;Lim, Jae-Yol;Lee, Kwang Yong
    • Phonetics and Speech Sciences
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    • v.10 no.4
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    • pp.135-146
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    • 2018
  • The Modified Voiced Lip Trill (MVoLT) training is a variant of voiced lip-till training characterized by increased loudness, lowered laryngeal position, and lip contact facilitated with fingers. The purpose of the current study was to assess the effect of the MVoLT training program on vocal changes of musical singing theater students. A total of 32 musical theater students (17 males and 15 females, age ranging from 18 to 29) participated in the study. For about three months, each participant was tutored using a systematic program focussing on the MVoLT training, accompanied by certain facilitating strategies. Pre- & post-training multi-dimensional vocal characteristics were assesed and compared. Results showed that cepstral peak prominence during vowel phonation increased after training, while its standard deviation and Cepstral Spectral Index of Dysphonia decreased. When an aerodynamic assessment was performed, maximum phonation time, subglottal pressure, mean airflow rate increased, while electroglottographic measures did not change. In addition, decreased psychometric measures, higher maximum pitch, and increased vocal range were noted after training. In conclusion, the MVoLT was proven to have a potential as an effective and safe training method for musical theater singing.

Metal-Poor F-G-K type Local Subdwarfs From SDSS + GAIA GR2: Spectrophotometric & Kinematic Properties

  • Yang, Soung-Chul;Kim, Young Kwang;Lee, Young Sun;Lee, Hogyu
    • The Bulletin of The Korean Astronomical Society
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    • v.43 no.2
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    • pp.59.2-59.2
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    • 2018
  • We introduce a new project of constructing a large spectro-photometric samples of metal-poor (i.e. [Fe/H] < -1.0) subdwarfs in the Galactic halo. The sample is collected from a compilation of the stellar objects that are cross-identified both in the Sloan Digital Sky Survey (SDSS) and recently published data from GAIA mission. The color range of the selected stars covers 0.0 < (g-r) < 2.0; thus the spectral types of our sample span from early F- through late K-type stars on the metal-poor main sequence (i.e. the local subdwarf sequence). We scrutinized the physical, chemical, and kinematical properties of our samples using their SDSS medium-resolution (R ~ 2000) spectra, combined with accurately measured proper motions from GAIA satellite. Our study will provide useful information on the global trend in the various properties (e.g. abundance pattern as a function of the galactocentric distance; rotational velocity vs [Fe/H] ${\cdots}$ etc) of the metal-poor subdwarf populations in the Galactic halo, which is ultimately important to better understand metal-poor stellar evolutionary models and chemical evolution of the Milky Way halo in the early phase of its formation. Further our comprehensive catalog of the Galactic field halo subdwarfs collected in this study will serve a solid groundwork for future follow-up high resolution spectroscopic observations on many interesting individual targets.

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Application of Cu-loaded One-dimensional TiO2 Nanorods for Elevated Photocatalytic Environmental Friendly Hydrogen Production

  • Kim, Dong Jin;Tonda, Surendar;Jo, Wan-Kuen
    • Journal of Environmental Science International
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    • v.30 no.1
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    • pp.57-67
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    • 2021
  • Photocatalytic green energy H2 production utilizing inexhaustible solar energy has been considered as a potential solution to problems of energy scarcity and environmental contamination. However, the design of a cost-effective photocatalyst using simple synthesis methodology is still a grand challenge. Herein, a low-cost transition metal, Cu-loaded one-dimensional TiO2 nanorods (Cu/TNR) were fabricated using an easy-to-use synthesis methodology for significant H2 production under simulated solar light. X-ray photoelectron spectral studies and electron microscopy measurements provide evidence to support the successful formation of the Cu/TNR catalyst under our experimental conditions. UV-vis DRS studies further demonstrate that introducing Cu on the surface of TNR substantially increases light absorption in the visible range. Notably, the Cu/TNR catalyst with optimum Cu content, achieved a remarkable H2 production with a yield of 39,239 µmol/g after 3 h of solar light illumination, representing 7.4- and 27.7-fold enhancements against TNR and commercial P25, respectively. The notably improved H2 evolution activity of the target Cu/TNR catalyst was primarily attributed to its excellent separation and efficiently hampered recombination of photoexcited electron-hole pairs. The Cu/TNR catalyst is, therefore, a potential candidate for photocatalytic green energy applications.

Chromophorylation of a Novel Cyanobacteriochrome GAF Domain from Spirulina and Its Response to Copper Ions

  • Jiang, Su-Dan;sheng, Yi;Wu, Xian-Jun;Zhu, Yong-Li;Li, Ping-Ping
    • Journal of Microbiology and Biotechnology
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    • v.31 no.2
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    • pp.233-239
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    • 2021
  • Cyanobacteriochromes (CBCRs) are phytochrome-related photoreceptor proteins in cyanobacteria and cover a wide spectral range from ultraviolet to far-red. A single GAF domain that they contain can bind bilin(s) autocatalytically via heterologous recombination and then fluoresce, with potential applications as biomarkers and biosensors. Here, we report that a novel red/green CBCR GAF domain, SPI1085g2 from Spirulina subsalsa, covalently binds both phycocyanobilin (PCB) and phycoerythrobilin (PEB). The PCB-binding GAF domain exhibited canonical red/green photoconversion with weak fluorescence emission. However, the PEB-binding GAF domain, SPI1085g2-PEB, exhibited an intense orange fluorescence (λabs.max = 520 nm, λfluor.max = 555 nm), with a fluorescence quantum yield close to 1.0. The fluorescence of SPI1085g2-PEB was selectively and instantaneously quenched by copper ions in a concentration-dependent manner and exhibited reversibility upon treatment with the metal chelator EDTA. This study identified a novel PEB-binding cyanobacteriochrome-based fluorescent protein with the highest quantum yield reported to date and suggests its potential as a biosensor for the rapid detection of copper ions.

High sensitivity determination of iridium contents in ultra-basic rocks by INAA with coincidence gamma-ray detection

  • Ebihara, Mitsuru;Shirai, Naoki;Kuwayama, Jin;Toh, Yosuke
    • Nuclear Engineering and Technology
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    • v.54 no.2
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    • pp.423-428
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    • 2022
  • Very low contents (in the range of 10-9 g/g) of Ir in mantle-derived rock samples (komatiites) were non-destructively determined by INAA coupled with coincidence gamma-ray spectrometry using 16 Ge detectors. Aliquots of the same samples were analyzed by NiS fire-assay ICP-MS for Ir and other platinum group elements. Because the INAA procedure used in this study is non-destructive and is almost free from spectral interference in gamma-ray spectrometry, the INAA values of Ir contents obtained in this study can be highly reliable. Iridium values obtained by ICP-MS were consistent with the INAA values, implying that the ICP-MS values of Ir obtained in this study are equally reliable. Under the present experimental conditions, detection limits were estimated to be 1 pg/g, which corresponds to 0.1 pg for a sample mass of 0.1 g. These levels can be even lowered by an order of magnitude, if necessary, which cannot be achieved by ICP-MS carried out in this study.

Design of Dynamically Focus-switchable Fresnel Zone Plates Based on Plasmonic Phase-change VO2 Metafilm Absorbers

  • Kyuho Kim;Changhyun Kim;Sun-Je Kim;Byoungho Lee
    • Current Optics and Photonics
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    • v.7 no.3
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    • pp.254-262
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    • 2023
  • Novel thermo-optically focus-switchable Fresnel zone plates based on phase-change metafilms are designed and analyzed at a visible wavelength (660 nm). By virtue of the large thermo-optic response of vanadium dioxide (VO2) thin film, a phase-change material, four different plasmonic phase-change absorbers are numerically designed as actively tunable Gires-Tournois Al-VO2 metafilms in two and three dimensions. The designed phase-change metafilm unit cells are used as the building blocks of actively focus-switchable Fresnel zone plates with strong focus switching contrast (40%, 83%) and high numerical apertures (1.52, 1.70). The Fresnel zone plates designed in two and three dimensions work as cylindrical and spherical lenses in reflection type, respectively. The coupling between the thermo-optic effect of VO2 and localized plasmonic resonances in the Al nanostructures offer a large degree of freedom in design and high-contrast focus-switching performance based on largely tunable absorption resonances. The proposed method may have great potential in photothermal and electrothermal active optical devices for nonlinear optics, microscopy, 3D scanning, optical trapping, and holographic displays over a wide spectral range including the visible and infrared regimes.

Perception of Tamil Mono-Syllabic and Bi-Syllabic Words in Multi-Talker Speech Babble by Young Adults with Normal Hearing

  • Gnanasekar, Sasirekha;Vaidyanath, Ramya
    • Journal of Audiology & Otology
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    • v.23 no.4
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    • pp.181-186
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    • 2019
  • Background and Objectives: This study compared the perception of mono-syllabic and bisyllabic words in Tamil by young normal hearing adults in the presence of multi-talker speech babble at two signal-to-noise ratios (SNRs). Further for this comparison, a speech perception in noise test was constructed using existing mono-syllabic and bi-syllabic word lists in Tamil. Subjects and Methods: A total of 30 participants with normal hearing in the age range of 18 to 25 years participated in the study. Speech-in-noise test in Tamil (SPIN-T) constructed using mono-syllabic and bi-syllabic words in Tamil was used as stimuli. The stimuli were presented in the background of multi-talker speech babble at two SNRs (0 dB and +10 dB SNR). Results: The effect of noise on SPIN-T varied with SNR. All the participants performed better at +10 dB SNR, the higher of the two SNRs considered. Additionally, at +10 dB SNR performance did not vary significantly for neither mono-syllabic or bi-syllabic words. However, a significant difference existed at 0 dB SNR. Conclusions: The current study indicated that higher SNR leads to better performance. In addition, bi-syllabic words were identified with minimal errors compared to mono-syllabic words. Spectral cues were the most affected in the presence of noise leading to more of place of articulation errors for both mono-syllabic and bi-syllabic words.

Development of AI oxygen temperature measurement technology using hyperspectral optical visualization technology (초분광 광학가시화 기술을 활용한 인공지능 산소온도 측정기술 개발)

  • Jeong Hun Lee;Bo Ra Kim;Seung Hun Lee;Joon Sik Kim;Min Yoon;Gyeong Rae Cho
    • Journal of the Korean Society of Visualization
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    • v.21 no.1
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    • pp.103-109
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    • 2023
  • This research developed a measurement technique that can measure the oxygen temperature inside a high temperature furnace. Instead of measuring only changes in frequency components within a small range used in the existing variable laser absorption spectroscopy, laser spectroscopy technology was used to spread out wavelength of the light source passing through the gas Based on a total of 20,000 image data, research was conducted to predict the temperature of a high-temperature furnace using CNN with black and white images in the form of spectral bands by temperature of 25 to 800 degrees. The optimal model was found through Hyper parameter optimization, R2 score is 0.89, and the accuracy of the test data is 88.73%. Based on this research, it is expected that concentration measurement and air-fuel ratio control technology can be applied.

Application of Fluorescence Excitation Emission Matrices for Diagnosis and Source Identification of Watershed Pollution : A Review (유기물 형광분석법을 활용한 유역 오염 진단 및 오염원 추적: 문헌 연구)

  • Kandaddara Badalge Nipuni Dineesha;Jin Hur;Byung Joon Lee
    • Journal of Korean Society on Water Environment
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    • v.39 no.1
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    • pp.87-101
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    • 2023
  • The constituents of a watershed control a wide range of ecosystem processes, such as, carbon sequestration, nutrient retention, and biodiversity preservation. Maintenance of a healthy watershed is advantageous to humans in many direct and indirect ways. Dissolved organic matter fluorescence analysis is one of the most commonly utilized parameters for water quality measurement, pollution source tracking, and determination of the ecological state of a watershed. Throughout the recent decades, the advancement in data processing, instrumentation, and methods has resulted in many improvements in the area of watershed study with fluorescence analysis. The current trend of coupling advanced instrumentations and new comparative parameters, such as, microplastics of different types, antibiotics, and specific bacterial contaminants have been reported in watershed studies. However, conventional methodologies for obtaining fluorescence excitation emission matrices and for calculating the fluorescence and spectral indices are preferred to advanced methods, due to their easiness and simple data collection. This review aims to gain a general understanding of the use of dissolved organic matter fluorescence analysis for diagnosis and source identification of watershed pollutions, by focusing on how the studies have utilized fluorescence analysis to improve existing knowledge and techniques in recent years.