• Korean Journal of Construction Engineering and Management
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• v.23 no.1
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• pp.73-82
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• 2022

Waste paint, one of the specified wastes in Korea, is currently treated entirely by incineration treatment method, and is hardly recycled compared to other wastes. Incineration treatment method also causes environmental problems such as air pollution. Thus, this study breaks away from the existing incineration treatment method of waste paint and switch to a method of pretreatment operation through evaporation, condensation, and thermal decomposition by temperature control. and then proposes a sustainable waste paint treatment process that can be recycled as an alternative energy heat source. If a new method of disposing of waste paint and technology for recycling are developed and disseminated, it is expected that the effect will be large from an economic and environmental point of view.

• Korean Journal of Soil Science and Fertilizer
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• v.47 no.1
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• pp.36-40
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• 2014

Korea's agricultural land is constantly being reduced. The reasons for this are due to the change of agricultural profitability and the policy conditions. The reduction of agricultural land in 2010 showed a decline trend by 14.4 % of paddy fields and 1.2% of uplands compared to areas from 2000. These reductions were mainly due to switch rice paddy fields into upland or greenhouse facility cultivation because of low profitability of rice products compared to farm products. In addition, the permit system of agricultural areas was relaxed in switching paddy fields and this accelerated the reduction of agricultural land. For this reason, more than 1% of agricultural land area has been reduced every year for last five years. Moreover, indiscreet fill and cover materials such as construction wastes were used in agricultural lands and caused land contamination which threatened foundation as sustainable agricultural lands. For these reasons, it is a desperate situation to conserve good agricultural lands. However, the standards of transported soils, filling soils and cutting soils in the Agricultural Land Act are qualitative and have a problem of causing complaints. Therefore, the following criteria (proposals) are proposed in the Agricultural Land Act; (1) Use the proper soils for crops (criterion), (2) Soil components and amounts should be proper as transported soils (range), and (3) Prohibiting usage of improper earth rocks or recycled aggregates in case of filling soils (kinds). The presented criteria (proposals) suggest following; (1) Use physio-chemically proper soils for crops (criterion), (2) In case of transported soils, i, exclude potential acid sulphate soils, ii, gravel content sould be less than 15%, and iii, Heavy metals and other contaminants should be less than the soil contamination warning limit from the Ministry of Environments, (3) In case of filling soils, 13 kinds of recycled wastes specified in the Wastes Control Act should not be used as filling soils, (4) Practice soil conservation technology in case of sloping areas, and (5) Follow proper fertilizer application standards for maturing paddy fields and uplands when cutting soils.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2001.04a
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• pp.206-209
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• 2001

This study presents the leaching characterization of heavy metals according to changes of pH by ANC test on slag produced in electric arc furnace, bottom ash produced in coal-fired plants and their recycling products. Availability test was performed to assess the fraction of the total concentration that under worst environmental conditions could become available for leaching. TCLP, KLT(Korea Leaching Test) and KLTS(Korea Leaching Test of Soil contamination) were carried out to compare the leaching capacity and to estimate the adequacy of regulatory leaching test. Results from regulatory leaching tests could be misleading because the variable ANC of wastes can lead to very different final leachate pHs. The final pH of the regulatory test is not the ambient pH in the disposal environment, the actual solubilities of contaminants in the field may be entirely different from those predicted by these regulatory tests. Leaching behaviour of by-products was changed by recycling processes, therefore acid neutralization capacity and availability of new products, not leaching concentration by one batch regulatory test, are necessary to determine the method of recycling.

• Clean Technology
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• v.10 no.3
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• pp.139-148
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• 2004

The recovery of stainless steel fiber by removing cutting oil from grinding swarf, which is classified as specified wastes, was investigated. Swarf loaded with grinding oil was regenerated by supercritical carbon dioxide. And, the effects of temperature(313.15K-323.15K), pressure(10MPa-30MPa) on regeneration efficiency were studied. Regeneration effiency was increased as the pressure was increased. Also, at the same pressure, the experiments at higher temperature were more efficient for regeneration. The experiment results was predicted by applying a one-parameter mathematical model assuming linear desorption kinetics. The predicted value showed good agreement with experimental data.

• Applied Chemistry for Engineering
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• v.27 no.1
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• pp.21-25
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• 2016

When copper alloy is used in etching process for the production of lead frame, the high concentration of heavy metals, such as iron, nickel and zinc may be included in the etching waste. Those etching waste is classified as a specified one. Therefore a customized design was designed for the purification process of the lead frame etching waste liquid containing high concentrations of heavy metals for the production of an electroplating copper(II) oxide. Since the lead frame etching waste solution contains highly concentrated heavy metal species, an ion exchange method is difficult to remove all heavy metals. In this study, a copper(I) chloride was manufactured by using water solubility difference related to the reduction-oxidation method followed by the reunion of copper(II) chloride using sodium sulfate as an oxidant. The hydrazine was chosen as a reducing agent. The optimum added amount was 1.4 mol per 1.0 mol of copper. In the case of removal of heavy metals by using the combination of reduction-oxidation and ion exchange resin methods, 4.3 ppm of $Fe^{3+}$, 2.4 ppm of $Ni^{2+}$ and 0.78 ppm of $Zn^{2+}$ can be reused as raw materials for electroplating copper(II) oxide when repeated three times.

• Analytical Science and Technology
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• v.24 no.5
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• pp.395-400
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• 2011

This study has been carried out in order to effectively manage three groups of unregulated hazardous organic substances (PCDD/DFs, PAHs, PCBs) in South Korea. The investigated substances have been analyzed according to the test methods for hazardous substances in specified wastes provided by the National Institute of Environmental Research, Korea. Total contents of the organic compounds have been determined for hazardous wastes from three major industrial categories (paint, iron removal, steelmaking), such as waste organic solvent, waste paint or dust. By investigating the waste samples for 7 PAHs using GC/MSD, Naphthalene has been detected (N.D~1631.33 mg/kg). The highest Naphthalene concentration, which exceeded the korean marine dumping waste standard, was found in waste organic solvents and waste paints. Although a content analysis of 7 PCB isomers has been conducted, none of these compounds was detected. The analysis of PCDD/DFs has revealed that all samples meet the criterion for low POP content defined in the technical guidelines developed under the Basel Convention. The PCDD/DFs content in dust samples deriving from 10 manufacturing processes (billet, bloom) was determined to be in the range of N.D~5.66 ng I-TEQ/g waste.

• Journal of Korean Society of Environmental Engineers
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• v.38 no.2
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• pp.96-99
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• 2016

This study characterized fly ash produced from a sewage sludge incineration facility in Korea to determine if the byproducts can be utilized. All the incinerated sewage sludge was from a city in Korea. To characterize fly ash and to determine if it can be utilized, pH, water contents, elemental components, particle size, surface morphology, heavy metal compositions, and others were analyzed. In average, pH was 6.2, and water contents was about 5%. T-N and $T-P_2O_5$ were 3% and 24.5%, respectively. Particle size averaged 836 nm; surface morphology did not exhibit any significant results. X-ray diffraction (XRD) analysis results revealed that major components of the fly ash were $P_2O_5$, CaO, MgO, $K_2O$. Composition of heavy metals by the Korea Standard Methods for Waste Quality did not exceed the criteria for specified wastes in Korea.

• Journal of the Korean Wood Science and Technology
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• v.39 no.5
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• pp.451-458
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• 2011

Adhesives derived from renewable resources allow wood panel producers to make lower cost alternatives to formaldehyde-based adhesive resins. Among them, adhesive components extracted from industrial by-products or wastes are the most important research fields in the efficient utilization of waste and cost reduction. In our study, the rapeseed flour, which is a by product from the production of biodiesel extracted from rapeseed, was introduced to develop alternative adhesives for the production of wood flooring. The rapeseed flour was hydrolyzed with 1% sodium hydroxide solution and PF prepolymers were prepared with 3-molar ratios, 1.8, 2.1 and 2.4. The linear fracture mechanics was introduced to evaluate the glue bond quality in wood flooring composed of fancy-veneered and plywood, and the formaldehyde emission and adhesive penetration were also investigated. The formaldehyde emissions of wood flooring met the requirement of the standard of $SE_0$ specified in the KS standard. The rapeseed flour adhesive penetrated sufficiently into the vessel elements and lumens in fancy veneer and plywood and gave strong bond quality to the wood flooring. The fracture mechanics was introduced to evaluate the adhesive joint between fancy veneer and plywood. The critical stress intensity factor ($K_{IC}$) of boliva overlayed wood flooring was increased with increasing molar ratio and this was the same tendency in oak overlayed wood flooring. From the results, the formulated adhesives were efficiently used to bond fancy veneer onto the plywood to make wood flooring and showed a potential to be used as a component of environmentally friendly adhesive resin systems for production of flooring.

• Nuclear Engineering and Technology
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• v.43 no.6
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• pp.583-592
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• 2011

The radiological characteristics for waste classification were assessed for neutron-activated decommissioning wastes from a CANDU reactor. The MCNP/ORIGEN2 code system was used for the source term analysis. The neutron flux and activation cross-section library for each structural component generated by MCNP simulation were used in the radionuclide buildup calculation in ORIGEN2. The specific activities of the relevant radionuclides in the activated metal waste were compared with the specified limits of the specific activities listed in the Korean standard and 10 CFR 61. The time-average full-core model of Wolsong Unit 1 was used as the neutron source for activation of in-core and ex-core structural components. The approximated levels of the neutron flux and cross-section, irradiated fuel composition, and a geometry simplification revealing good reliability in a previous study were used in the source term calculation as well. The results revealed the radioactivity, decay heat, hazard index, mass, and solid volume for the activated decommissioning waste to be $1.04{\times}10^{16}$ Bq, $2.09{\times}10^3$ W, $5.31{\times}10^{14}\;m^3$-water, $4.69{\times}10^5$ kg, and $7.38{\times}10^1\;m^3$, respectively. According to both Korean and US standards, the activated waste of the pressure tubes, calandria tubes, reactivity devices, and reactivity device supporters was greater than Class C, which should be disposed of in a deep geological disposal repository, whereas the side structural components were classified as low- and intermediate-level waste, which can be disposed of in a land disposal repository. Finally, this study confirmed that, regardless of the cooling time of the waste, 15% of the decommissioning waste cannot be disposed of in a land disposal repository. It is expected that the source terms and waste classification evaluated through this study can be widely used to establish a decommissioning/disposal strategy and fuel cycle analysis for CANDU reactors.

• Journal of Radiation Industry
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• v.18 no.1
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• pp.95-100
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• 2024

To establish a radioactive waste life cycle history management system, a series of processes including waste generation, classification, packaging, storage, transportation, and disposal were reflected in the information management system. A preliminary review process was introduced to reduce the amount of radioactive waste generated and manage it efficiently. Through this, the amount of radioactive waste generated must be checked from the beginning of the research, and the generated radioactive waste must be thoroughly managed from the stage of generation to final disposal. In particular, in the case of radioactive waste data generated during nuclear facility operation and each experiment, a radioactive waste information management system must be operated to receive information from the waste generator and integrate it with processing information at the management stage. The application process for small-package containers was reflected so that information such as the generation facility of radioactive waste, generation facility, project information, types of radioactive waste, major radionuclides, etc. In the radioactive waste management process, the preceding steps are to receive waste history from the waste generators. This includes an application for a specified container with a QR label, pre-inspection, and management request. Next, the succeeding steps consist of repackaging, treatment, characterization, and evaluating the suitability of disposal, for a process to transparently manage radioactive wastes.