• Title/Summary/Keyword: Specific surface are

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Fractionation and Pollution Index of Heavy Metals in the Sangdong Tungsten Mine Tailings (광미에 존재하는 중금속의 분획화와 오염도 평가)

  • Yang, Jae-E.;Kim, Hee-Joung;Jun, Sang-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.34 no.1
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    • pp.33-41
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    • 2001
  • Enormous volumes of mining wastes from the abandoned and closed mines are disposed without a proper treatment in the upper Okdong River basin at Southeastern part of Kangwon Province. Erosion of these wastes contaminates soil, surface water, and sediments with heavy metals. Objectives of this research were to fractionate heavy metals in the mine tailing stored in the Sangdong Tungsten tailing dams and to assess the potential pollution index of each metal fraction. Tailing samples were collected from tailing dams at different depth and analyzed for physical and chemical properties. pH of tailings ranged from 7.3 to 7.9. Contents of total N and organic matter were in the ranges of 3.2~5.5%, and 1.3~9.1%, respectively. Heavy metals in the tailings were higher in the newly constructed tailing dam than those in the old dam. Total concentrations of metals in the tailings were in the orders of Zn > Cu > Pb > Ni > Cd, exceeded the corrective action level of the Soil Environment Conservation Law and higher than the natural abundance levels reported from uncontaminated soils. Relative distribution of heavy metal fractions was residual > organic > reducible > carbonate > adsorbed, reversing the degree of metal bioavailability. Mobile fractions of metals were relatively small compared to the total concentrations. Distribution of metals in the tailing dam profiles was metal specific. Concentrations of Cu at the surface of tailing dams were higher than those at the bottom. Pollution index (PI) values of each fraction of metals were ranged from 4.27 to 8.51 based on total concentrations. PI values of mobile fractions were lower than those of immobile fractions. Results on metal fractions and PI values of the tailing samples indicate that tailing samples were contaminated with heavy metals and had potential to cause a detrimental effects on soil and water environment in the lower part of the stream. A prompt countermeasure to prevent surface of tailings in the dams from water and wind erosions is urgently needed.

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A Study on groundwater and pollutant recharge in urban area: use of hydrochemical data

  • Lee, Ju-Hee;Kwon, Jang-Soon;Yun, Seong-Taek;Chae, Gi-Tak;Park, Seong-Sook
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.119-120
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    • 2004
  • Urban groundwater has a unique hydrologic system because of the complex surface and subsurface infrastructures such as deep foundation of many high buildings, subway systems, and sewers and public water supply systems. It generally has been considered that increased surface impermeability reduces the amount of groundwater recharge. On the other hand, leaks from sewers and public water supply systems may generate the large amounts of recharges. All of these urban facilities also may change the groundwater quality by the recharge of a myriad of contaminants. This study was performed to determine the factors controlling the recharge of deep groundwater in an urban area, based on the hydrogeochemical characteristics. The term ‘contamination’ in this study means any kind of inflow of shallow groundwater regardless of clean or contaminated. For this study, urban groundwater samples were collected from a total of 310 preexisting wells with the depth over 100 m. Random sampling method was used to select the wells for this study. Major cations together with Si, Al, Fe, Pb, Hg and Mn were analyzed by ICP-AES, and Cl, N $O_3$, N $H_4$, F, Br, S $O_4$and P $O_4$ were analyzed by IC. There are two groups of groundwater, based on hydrochemical characteristics. The first group is distributed broadly from Ca-HC $O_3$ type to Ca-C1+N $O_3$ type; the other group is the Na+K-HC $O_3$ type. The latter group is considered to represent the baseline quality of deep groundwater in the study area. Using the major ions data for the Na+K-HC $O_3$ type water, we evaluated the extent of groundwater contamination, assuming that if subtract the baseline composition from acquired data for a specific water, the remaining concentrations may indicate the degree of contamination. The remainder of each solute for each sample was simply averaged. The results showed that both Ca and HC $O_3$ represent the typical solutes which are quite enriched in urban groundwater. In particular, the P$CO_2$ values calculated using PHREEQC (version 2.8) showed a correlation with the concentrations of maior inorganic components (Na, Mg, Ca, N $O_3$, S $O_4$, etc.). The p$CO_2$ values for the first group waters widely ranged between about 10$^{-3.0}$ atm to 10$^{-1.0}$ atm and differed from those of the background water samples belonging to the Na+K-HC $O_3$ type (<10$^{-3.5}$ atm). Considering that the p$CO_2$ of soil water (near 10$^{-1.5}$ atm), this indicates that inflow of shallow water is very significant in deep groundwaters in the study area. Furthermore, the P$CO_2$ values can be used as an effective parameter to estimate the relative recharge of shallow water and thus the contamination susceptibility. The results of our present study suggest that down to considerable depth, urban groundwater in crystalline aquifer may be considerably affected by the recharge of shallow water (and pollutants) from an adjacent area. We also suggest that for such evaluation, careful examination of systematically collected hydrochemical data is requisite as an effective tool, in addition to hydrologic and hydrogeologic interpretation.ion.ion.

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Effect of Fouling Reducing Additives on Membrane Filtration Resistance of Activated Sludge (막오염 감소제가 활성슬러지의 여과저항에 미치는 영향)

  • Chung, Tai Hak;Lee, Jong Hoon;Kim, Hyoung Gun;Bae, Young Kyoung
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.6
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    • pp.406-413
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    • 2012
  • Effect of three additives, chitosan, ferric chloride, and MPE50 on membrane fouling reduction was studied. They were introduced with various dosing rate into activated sludge, and changes in filtration resistance measured by the batch cell filtration test were evaluated. Both the filtration resistance and the specific cake resistance were minimized at 20 mg/g-MLSS with chitosan, 70 mg/g-MLSS with ferric chloride, and 20 mg/g-MLSS with MPE50 addition, respectively. Introduction of the additives into the activated sludge resulted in reduction of not only cake resistance, but also fouling resistance. However, the chitosan addition to three different activated sludge resulted in three different optimal dose of 10, 20, 30 mg/g-MLSS, respectively. This implies that the optimal dose is dependent on sludge characteristics rather than a constant value. Overdose above the optimal dosage always aggravated filterability in all cases. Zeta potential of sludge flocs, relative hydrophobicity, floc size distribution, soluble EPS concentration and supernatant turbidity were measured in order to analyze fouling reduction mechanism. Nearly neutral surface charge along with the largest particle size was observed at the optimal dose. This could be explained by particle destabilization and restabilization mechanism as positively charged additives were injected into sludge flocs of negative surface charge. Both soluble EPS concentration and supernatant turbidity also showed the lowest value at the optimal dose. These foulants are believed to be coagulated and entrapped in sludge flocs during flocculation. Chitosan and MPE50 which are cationic polymeric substances showed higher reduction in both soluble EPS and fine particles comparing with ferric chloride.

A Study on the Guidelines on the Insertion of Metal Stiffeners in the Restoration of Stone Cultural Heritages (석조문화재 복원을 위한 금속보강재 매입방법 표준화 연구)

  • Lee, Dong-sik;Kim, Hyun-yong;Kim, Sa-dug;Hong, Seong-geol
    • Korean Journal of Heritage: History & Science
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    • v.46 no.3
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    • pp.212-228
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    • 2013
  • Stone cultural heritages are repaired by the use of metal stiffeners. The problem is that this type of repair has been based on the experience of workers without specific guidelines and has caused various problems. This is to suggest the structural reinforcement and behavioral characteristics of metal rods to minimize the secondary damage of materials and have the specimens tested and verified to establish the guidelines on how to insert metal stiffeners. When only epoxy resin is applied to the cut surface, only 70% of the properties of the parent material are regenerated and it is required to structurally reinforce the metal stiffener for the remaining 30%. The metal rod is under the structural behavior after the brittle failure of stone material and the structural behavior does not occur when the metal stiffener is below 0.251%. When it accounts for over 0.5%, it achieves structural reinforcement, but causes secondary damage of parent materials. The appropriate ratio of metal stiffener for the stone material with the strength of $1,500kgf/cm^2$, therefore, should be between 0.283% and 0.377% of the cross section of attached surface to achieve reversible fracture and ductility behavior. In addition, it is more effective to position the stiffeners at close intervals to achieve the peak stress of metal rod against bending load and inserting the stiffener into the upper secions is not structurally supportive, but would rather cause damage of the parent material. Thus, most stiffeners should be inserted into the lower part and some into the central part to work as a stable tensile material under the load stress. The dispersion effect of metal rods was influenced by the area of reinforcing rods and unrelated to their diameter. However, it ensures stability under the load stress to increase the number of stiffeners considering the cross section adhered when working on large-scale structures. The development length is engineered based upon the diameter of stiffener using the following formula: $l_d=\frac{a_tf_y}{u{\Sigma}_0}$. Also, helically-threaded reinforcing rods should be used to perform the behaviors as a structural material.

Comparative study on the performance of Pod type waterjet by experiment and computation

  • Kim, Moon-Chan;Park, Warn-Gyu;Chun, Ho-Hwan;Jung, Un-Hwa
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.2 no.1
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    • pp.1-13
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    • 2010
  • A comparative study between a computation and an experiment has been conducted to predict the performance of a Pod type waterjet for cm amphibious wheeled vehicle. The Pod type waterjet has been chosen on the basis of the required specific speed of more than 2500. As the Pod type waterjet is an extreme type of axial flow type waterjet, theoretical as well as experimental works about Pod type waterjets are very rare. The main purpose of the present study is to validate and compare to the experimental results of the Pod type waterjet with the developed CFD in-house code based on the RANS equations. The developed code has been validated by comparing with the experimental results of the well-known turbine problem. The validation also extended to the flush type waterjet where the pressures along the duct surface and also velocities at nozzle area have been compared with experimental results. The Pod type waterjet has been designed and the performance of the designed waterjet system including duct, impeller and stator was analyzed by the previously mentioned m-house CFD Code. The pressure distributions and limiting streamlines on the blade surfaces were computed to confirm the performance of the designed waterjets. In addition, the torque and momentum were computed to find the entire efficiency and these were compared with the model test results. Measurements were taken of the flow rate at the nozzle exit, static pressure at the various sections along the duct and also the nozzle, revolution of the impeller, torque, thrust and towing forces at various advance speed's for the prediction of performance as well as for comparison with the computations. Based on these measurements, the performance was analyzed according to the ITTC96 standard analysis method. The full-scale effective and the delivered power of the wheeled vehicle were estimated for the prediction of the service speed. This paper emphasizes the confirmation of the ITTC96 analysis method and the developed analysis code for the design and analysis of the Pod type waterjet system.

A study on slope protection works in cemetery establishment area ( I ) - The case of a public cemetery in Kangnung city - (묘지 조성사업지의 비탈면 보호공법에 관한 연구( I ) - 강릉시 시범 공설묘지 조성사업을 중심으로 -)

  • Chun, Kun-Woo;Yoo, Nam-Jae;Cha, Du-Song;Yi, Myong-Jong;Park, Wan-Geun;Han, Sang-Kyun
    • Journal of Forest and Environmental Science
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    • v.16 no.1
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    • pp.17-33
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    • 2000
  • The construction of a public cemetery in Kangnung city includes terraced graveyard with cutting or banking in mountain which has severe altitude differences with a slope of $30^{\circ}$. Therefore, there are scattered cutting and banking sections with vertical height more than 15m. Especially, if the slope failure or the loss of a graveyard happens after graveyard establishment due to surface flow and inflow around. it is difficult to repair, causing serious public censure. Accordingly, revegetation works were examined that need protection of slope. The specific content of the study was the selection of slopes requiring special care through blueprint and field investigation. the measurement of the physical property of slope and the situation of vegetative growth, the investigation of vegetation in slopes and the selection of vegetation. and the analysis of soil condition of slopes and the physical condition of slope sediment. On the basis of investigations some alternatives were proposed.

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Mechanical Properties and Resistance to Freezing and Thawing of the Recycled Aggregate Concrete with Metakaolin (메타카올린을 혼합한 재생골재 콘크리트의 역학적 특성 및 동결융해 저항성)

  • Moon, Han-Young;Kim, Yang-Bae;Moon, Dae-Joong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.9 no.4
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    • pp.270-278
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    • 2005
  • Recycled aggregate concrete has lower strength and durability compared to concrete with natural aggregate. Therefore, metakaolin is used to improve the properties of recycled aggregate concrete. Main components of metakaolin are $SiO_2$ and $Al_2O_3$. and specific surface area is 9 times larger than that of ordinary portland cement. Quality of demolished-recycled aggregate(DRA) satisfies the type 1 of KS F 2573, but quality of source-recycled aggregate(SRA) does not satisfy with the type 2 of KS F 2573. When metakaolin was replaced with 20% of cement, compressive strength of concrete with SRA and DRA develops about 40~64% of control concrete. Water absorption ratio was reduced about 2% by replacing 20% metakaolin and it represents low compared to the natural aggregate concrete without metakaolin. In addition, the resistance to freezing and thawing, of concrete with DRA is indicated to remarkably enhanced due to the contribution of metakaolin. However, when metakaolin is replaced with 20% of cement, relative dynamic modulus of elasticity of concrete with SRA was below 60% at 210 freezing and thawing cycles.

A study on preparation of activated carbon from waste tire (폐타이어로부터 활성탄 제조에 관한 연구)

  • Kim, Jin-Uk;Lim, Ki-Hyuk;Shon, Byung-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.2
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    • pp.947-953
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    • 2012
  • In this study we investigated the manufacturing method for the activated carbon using the char from the pyrolysis of waste tire. The physical activation method using the steam in the fixed-bed quartz reactor was used for preparation of activated carbon. The primary experiment parameters are the activation temperature, activation time, heating rate, and the injection quantity of active agent. From the results of pore distribution of activated carbon, the micropore which was made in $850^{\circ}C$ of activation temperature, $5^{\circ}C$/min of heating rate, and 3 hours of activation time was developed in biggest quantity, and mesopore and macropore were developed in the biggest quantity too. The optimum conditions for producing the activated carbon using the pyrolysis residue were $850^{\circ}C$ of activation temperature, 3 hours of activation time, $5^{\circ}C$/min of heating rate, and 3 g $H_2O/char-g{\cdot}hr$ of active agent through this study. The produced activated carbon in these conditions showed that the potentiality of utilization as activated carbon because the BET specific surface area was $517.6m^2/g$ and total pore volume was $0.648cm^3/g$.

Analysis of virulence gene profiles of Salmonella spp. and Enterococcus faecalis isolated from the freshly slaughtered poultry meats produced in Gyeong-Nam province (경남지역 가금류 도축장 신선육에서 분리한 Salmonella spp.와 Enterococcus faecalis의 독성인자 보유 패턴 분석)

  • Hah, Do-Yun;Cha, Hwi-Geun;Han, Kwon-Seek;Jang, Eun-Hee;Park, Ha-Yeong;Bae, Min-jin;Cho, Ah Reum-Song I;Lee, Hoo-Geun;Ko, Byeong-Hyo;Kim, Do-Kyoung;Hwang, Bo-Won;Kim, Sang-Hyun
    • Korean Journal of Veterinary Service
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    • v.41 no.3
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    • pp.157-163
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    • 2018
  • In order for monitoring of pathogenic bacterial contamination in the freshly slaughtered poultry meats produced in Gyeong-Nam province, we first isolated 4 strains of Salmonella spp. and 32 strains of Enterococcus faecalis from the total 164 samples, then we analyzed potential virulence gene profiles of the bacterial isolates by PCR using species-specific primer. The potential virulence genes we selected in this study were stn, invA, fimA, spvR, and spvC for the isolates of Salmonella spp. and those of esp, cylM, cylA, cylB, gelE, fsrA, fsrB, and fsrC were for the isolates of E. faecalis. The PCR results showed that all 5 virulence genes were detected simultaneously in the all isolates of Salmonella spp. However, there was a diverse occurrence pattern of the virulence genes in the case of E. faecalis. The gene for enterococcal surface protein (esp) was not detected among the isolates (0/32), and the haemolysin gene prevalence rate of cylA, cylB, and cylM were 3.1% (1/32), 9.3% (3/32), and 9.3% (3/32), respectively. Moreover, the genes of gelE, fsrA, fsrB, and fsrC that associated with gelatinase activity were detected in the rate of 53.1% (17/32), 53.1% (17/32), 53.1% (17/32), and 53.1% (17/32), respectively. In conclusion, in the isolates of Salmonella spp., all possessed 5 virulence genes tested, suggesting that they are all related with each other clonally. However, in the case of E. faecalis isolates, the occurrence of the haemolysin genes (cylM, cylA, cylB) and the gelatinase genes (gelE, fsrABC) was highly variable among the isolates.

Development of Tumor Screening ELISA kit by Using Novel Tumor Antigen, CM1 (새로운 종양항원인 CM1을 이용한 종양 진단 ELISA kit의 개발)

  • Kang, Jae-Seung;Kim, Dae-Jin;Kim, Young-In;Chang, Ka-Young;Lee, Wang-Jae
    • IMMUNE NETWORK
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    • v.5 no.2
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    • pp.124-129
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    • 2005
  • Background: CM1 (centrocyte/-blast marker 1) is originally defined as a germinal center B cell marker. It is known that CM1 plays a critical role on B cell development in germinal center. In addition, we have found that CM1 is expressed on lymphoma cell lines, such as Raji, Ramos and IM-9. This means that CM1 might be served as a tumor marker as well. In the present study, we examined the expression of CM1 on the surface of the other tumors and the possibility of the development of tumor screening ELISA kit by using CM1. Methods: First, we have examined the expression of CM1 on stomach cancer and hepatoma, which are predominantly (discovered) occurred in Korean, by flow cytometry analysis. After purifying of CM1 antigen from Raji and Ramos, the optimal ELISA condition was determined. And then we compared the level of CM1 between normal individuals and cancer patients by ELISA. To decrease the non-specific binding of anti-CM1 mAb with serum components except CM1 and to enhance the diagnostic accuracy, albumin depletion spin column was used. Results: CM1 was highly expressed on stomach cancer and hepatoma cell lines. In addition, we have also confirmed the increased CM1 expression on cancer patients. The difference of CM1 expression between normal individuals and cancer patients were more clearly observed, after deletion of serum albumin by using albumin depletion spin column. Conclusion: Based on the results from this study, CM1 might be a useful molecule for the early diagnosis of cancer. In addition, further studies for the increase of ELISA sensitivity and appropriate albumin depletion methods should be needed.