• Title/Summary/Keyword: Specific surface are

Search Result 1,399, Processing Time 0.034 seconds

Effect of operating temperature using Ni-Al-$ZrH_2$ anode in molten carbonate fuel cell (Ni-Al-$ZrH_2$ 연료극을 사용한 용융탄산염 연료전지의 온도의 영향)

  • Seo, Dongho;Jang, Seongcheol;Yoon, Sungpil;Nam, Suk Woo;Oh, In-Hwan;Lim, Tae-Hoon;Hong, Seong-Ahn;Han, Jonghee
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2010.06a
    • /
    • pp.134-134
    • /
    • 2010
  • Fuel cell is a device that directly converts chemical energy in the form of a fuel into electrical energy by way of an electrochemical reaction. In the anode for a high temperature fuel cell, nickel or nickel alloy has been used in consideration of the cost, oxidation catalystic ability of hydrogen which is used as fuel, electron conductivity, and high temperature stability in reducing atmosphere. Most MCFC stacks currently operate at an average temperature of $650^{\circ}C$. There is some gains with decreased temperature in MCFC to diminish the electrolyte loss from evaporation and the material corrosion, which could improve the MCFC life. However, operating temperature has a strong related on a number of electrode reaction rates and ohmic losses. Baker et al. reported the effect of temperature (575 to $650^{\circ}C$). The rates of cell voltage loss were 1.4mV/$^{\circ}C$ for a reduction in temperature from 650 to $600^{\circ}C$, and 2.16mV/$^{\circ}C$ for a decrease from 600 to $575^{\circ}C$. The two major contributors responsible for the change in cell voltage with reducing operation temperature are the ohmic polarization and electrode polarization. It appears that in the temperature range of 550 to $650^{\circ}C$, about 1/3 of the total change in cell voltage with decreasing temperature is due to an increase in ohmic polarization, and the electrode polarization at the anode and cathode. In addition, the oxidation reaction of hydrogen on an ordinary nickel alloy anode in MCFC is generally considered to take place in the three phase zone, but anyway the area contributing to this reaction is limited. Therefore, in order to maintain a high performance of the fuel cell, it is necessary to keep this reaction responsible area as wide as possible, that is, it is needed to keep the porosity and specific surface area of the anode at a high level. In this study effective anodes are prepared for low temperature MCFC capable of enhancing the cell performance by using zirconium hydride at least in part of anode material.

  • PDF

Size Determination Method of Bio-Retention Cells for Mimicking Natural Flow Duration Curves (자연상태 유황곡선 보전을 위한 생태저류지 용량결정방법)

  • Lee, Okjeong;Jang, Suhyung;Kim, Hongtae;Kim, Sangdan
    • Journal of Wetlands Research
    • /
    • v.18 no.4
    • /
    • pp.424-431
    • /
    • 2016
  • LID facilities like bio-retention cells is applied to manage stormwater. LID concept becomes an important part in stormwater management, and the clear understanding of hydrologic performance and hydrologic impact on the corresponding catchment has been needed. In this study, the application of flow duration curves as design strategy is investigated. Bio-retention cells like many LID facilities are installed to reproduce natural hydrologic processes. In this study, the attempt to determine the size of a bio-retention cell is carried out to satisfy the flow duration criteria. From the results, it is shown that "5 mm * the area of a target catchment" which is the current facility design capacity is valid for the drainage area with 20-30% impervious rate. In the 100% impervious catchment where LID facilities are typically installed, the design capacity to intercept stormwater of approximately 47 mm depth is required to reproduce natural flow duration curves. This means that about 11% of the target catchment area should be allocated as a bio-retention cell. However, the criteria of the design capacity and facility surface area should be set at the possible implementation conditions in reality, and site-specific hydrologic characteristics of a target catchment should be considered.

Development of Shampoo Formulated by EPA for the Damaged Hair (손상 모발을 위한 EPA 함유 샴푸 개발)

  • Lee, Bo-Reum;Lee, Ok-Sang;Kang, Tae-Jin;Lim, Sung-Cil
    • Korean Journal of Clinical Pharmacy
    • /
    • v.21 no.3
    • /
    • pp.256-269
    • /
    • 2011
  • Omega-3 fatty acids are a specific type of unsaturated fat that the body cannot manufacture on its own, so they must be obtained from food which is essential fatty acids (EFAs). Omega-3 fatty acids consist of three types which are a-Linolenic Acid (ALA), Eicosapentaenoic (ELA), and Docosahexaenoic Acid (DHA). Especially, EFAs help to prevent skin and hair drying, acne, eczema, prevention from allergies, brittle nails, rashes, and tiny lumps. The aim of this study is to investigate improvement and protection for hair damaged by chemical treatment with omega-3 formulated shampoo. We selected virgin hair sample and divided into two groups for bleaching once and three times and then damaged hair by changing the number of hair bleaching (twice with interval of 15 minutes). Each bleached hair was treated by five different kinds of shampoo (Control, Horse shampoo, DHA shampoo, EPA shampoo, Omega-3 shampoo mixture). Apart from this, EPA/DHA 2, 5, 8, 10 and 12% shampoo were prepared and treated to hair for comparing rate of progress in damaged hair. To quantify improved condition of damaged hair, we performed Scanning Electron Microscope (SEM) for ultrastructure of damaged hair fraction, measurement of thickness change and BCA Protein Assay for recovery rate of damaged hair. The moisture in hair was measured by Thermal analysis machine. In results, we observed the particle of hair surface damaged by bleaching treatment were well improved with treatment with EPA and DHA shampoo. Also, quantity of protein was lowered with higher concentration of EPA & DHA i.e., 8 and 12 % then compared with horse oil shampoo in three times treatment group. It shows that bleached hair have been recovered by treating rapidly and get protective coat. In conclusion, EPA and DHA shampoo improved damaged hair, especially with EPA / DHA 12% shampoo. Also, EPA shampoo could protect the damaged hair depending on increasing concentration of EPA. Therefore, we conclude omega-3 shampoo could make damaged hair protect and get healthy hair environment.

Development of a Pipe Network Fluid-Flow Modelling Technique for Porous Media based on Statistical Percolation Theory (통계적 확산이론에 기초한 다공질체의 유동관망 유동해석 기법 개발)

  • Shin, Hyu-Soung
    • The Journal of Engineering Geology
    • /
    • v.23 no.4
    • /
    • pp.447-455
    • /
    • 2013
  • A micro-mechanical pipe network model with the shape of a cube was developed to simulate the behavior of fluid flow through a porous medium. The fluid-flow mechanism through the cubic pipe network channels was defined mainly by introducing a well-known percolation theory (Stauffer and Aharony, 1994). A non-uniform flow generally appeared because all of the pipe diameters were allocated individually in a stochastic manner based on a given pore-size distribution curve and porosity. Fluid was supplied to one surface of the pipe network under a certain driving pressure head and allowed to percolate through the pipe networks. A percolation condition defined by capillary pressure with respect to each pipe diameter was applied first to all of the network pipes. That is, depending on pipe diameter, the fluid may or may not penetrate a specific pipe. Once pore pressures had reached equilibrium and steady-state flow had been attained throughout the network system, Darcy's law was used to compute the resultant permeability. This study investigated the sensitivity of network size to permeability calculations in order to find out the optimum network size which would be used for all the network modelling in this study. Mean pore size and pore size distribution curve obtained from field are used to define each of pipe sizes as being representative of actual oil sites. The calculated and measured permeabilities are in good agreement.

Development of Biomass Evaluation Model of Winter Crop Using RGB Imagery Based on Unmanned Aerial Vehicle (무인기 기반 RGB 영상을 이용한 동계작물 바이오매스 평가 모델 개발)

  • Na, Sang-il;Park, Chan-won;So, Kyu-ho;Ahn, Ho-yong;Lee, Kyung-do
    • Korean Journal of Remote Sensing
    • /
    • v.34 no.5
    • /
    • pp.709-720
    • /
    • 2018
  • In order to optimize the evaluation of biomass in crop monitoring, accurate and timely data of the crop-field are required. Evaluating above-ground biomass helps to monitor crop vitality and to predict yield. Unmanned Aerial Vehicle (UAV) imagery are being assessed for analyzing within field spatial variability for agricultural precision management, because UAV imagery may be acquired quickly during critical periods of rapid crop growth. This study reports on the development of remote sensing techniques for evaluating the biomass of winter crop. Specific objective was to develop statistical models for estimating the dry weight of barley and wheat using a Excess Green index ($E{\times}G$) based Vegetation Fraction (VF) and a Crop Surface Model (CSM) based Plant Height (PH) value. As a result, the multiple linear regression equations consisting of three independent variables (VF, PH, and $VF{\times}PH$) and above-ground dry weight provided good fits with coefficients of determination ($R^2$) ranging from 0.86 to 0.99 with 5 cultivars. In the case of the barley, the coefficient of determination was 0.91 and the root mean squared error of measurement was $102.09g/m^2$. And for the wheat, the coefficient of determination was 0.90 and the root mean squared error of measurement was $110.87g/m^2$. Therefore, it will be possible to evaluate the biomass of winter crop through the UAV image for the crop growth monitoring.

COMPARATIVE STUDY ON THE DETECTION OF PORPHYROMONAS ENDODONTALIS BY ANAEROBIC CULTURE, IIF AND DNA PROBE METHOD IN INFECTED ROOT CANALS (감염 근관에서 혐기성 배양법과 간접 면역 형광법 및 DNA 프로브법에 의한 Porphyromonas endodontalis의 검출에 관한 비교 연구)

  • Kim, Min-Kyum;Yoon, Soo-Han;Chung, Chong-Pyoung
    • Restorative Dentistry and Endodontics
    • /
    • v.21 no.1
    • /
    • pp.1-18
    • /
    • 1996
  • There are many advantages when using IIF and DNA probe methods over anaerobic culture method in that they are time-and effort-saving, more precise and more sensitive. Furthermore, in IIF and DNA probe methods, the detection is possible only with small amount of bacteria, the quantitative analysis is possible, and the cell viability is not necessary. The purpose of this study is to observe the incidence of P.endodontalis by carrying out anaerobic culture, IIF and colony lift using DNA probe method respectively, and to compare these 3 methods in terms of effectiveness and sensitivity in order to identify the most effective detection method. 30 teeth with at least one clinical symptoms, with single canal, and with pulp necrosis were sampled. For sampling bacteria, access cavity was prepared after disinfecting tooth and its surroundings. Then the paper point was inserted up to the periapical area, leave there for a while, and finally it was placed into PRAS Ringer's sol. and PBS sol. In anaerobic culture method, P.endodontalis was identified by biochemical tests after subculturing black and brown colonies which were produced after 7 days of incubation on BAP and Brucella BAP in anaerobic chamber. To identify P.endodontalis in IIF method, species-specific polyclonal rabbit-antisera of P.endodontalis(ATCC 35406) was reacted with sampled PBS sol. dispensed onto glass slide, and then P.endodontalis was examined by phase contrast microscopy after incubating with Goat anti-rabbit lgG conjugated to Fluorescein isothiocyanate. For colony lift using DNA probe method, membranes were laid over colonies on the surface of BAP and were hybridized with cloned DNA probe of P.endodontalis. The existence of P.endodontalis was then identified by the methods of chemiluminescent detection and color metric detection. Black colony was found in 11 teeth out of 30 teeth and P.endodontalis was detected in 6 teeth (20 %) by anaerobic culture method, 16 teeth (53 %) by IIF method, and 7 teeth (23 %) by DNA probe method. IIF method is significantly better in detecting P.endodontalis than DNA probe method and anaerobic culture method. There was no significant differences between DNA probe method and anaerobic culture method. There was significant correlation between the formation of black colony and the existence of P.endodontalis. The probability of detecting P.endodontalis when black colony being present is 2.89 times higher than when not being present. There was significant relationship between the foul odor of clinical symptoms and P.endodontalis. The sensitivity of existing P.endodontalis when foul odor being present was 93.75 %, while the specificity of not existing P.endodontalis when foul odor not being present was 28.57 %. These results suggested that the probes of P.endodontalis will be used to decide the method and prognosis in endodontic treatments.

  • PDF

Review of the CO2 Geological Storage Using Nanoparticle-stabilized CO2 Foam (나노입자기반 CO2 폼을 이용한 CO2 지중저장에 대한 기술적 고찰)

  • Son, Han Am
    • Economic and Environmental Geology
    • /
    • v.53 no.2
    • /
    • pp.213-220
    • /
    • 2020
  • When CO2 foam is injected into the saline aquifer, the relative permeability of CO2 decreases and its viscosity increases, thereby reducing mobility in porous media and ultimately improving CO2 storge with enhanced sweep efficiency. In general, surfactants were used to fabricate CO2 foam. Recently, nanoparticles have been used to form stable foam than surfactant. This paper introduces CO2 storage technology using nanoparticle stabilized CO2 foam. If the surface of the hydrophilic nanoparticles is partially modified into a CO2-philic portion, the particles have an affinity for CO2 and water, thus forming a stable CO2 foam even in deep saline aquifers under high temperature and high salinity conditions, thereby it can be stored in the pores of the rock. In terms of economics, injection method using nanopaticle-stabilized CO2 foam is more expensive than the conventional CO2 injection, but it is estimated that it will have price competitiveness because the injection efficiency is improved. From an environmental point of view, it is possible to inject chemical substances such as surfactants and nanomaterials into aquifers or reservoirs for specific purposes such as pollutant removal and oil production. However, some studies have shown that nanoparticles and surfactants are toxic to aquatic animals, so environmentally proven substances should be used. Therefore, further research and development will be needed to study the production and injection of nanoparticle-stabilized CO2 foam that are environmentally safe and economically reasonable.

Aluminum Powder Metallurgy Current Status, Recent Research and Future Directions

  • Schaffer, Graham
    • Proceedings of the Korean Powder Metallurgy Institute Conference
    • /
    • 2001.11a
    • /
    • pp.7-7
    • /
    • 2001
  • The increasing interest in light weight materials coupled to the need for cost -effective processing have combined to create a significant opportunity for aluminum P/M. particularly in the automotive industry in order to reduce fuel emissions and improve fuel economy at affordable prices. Additional potential markets for Al PIM parts include hand tools. Where moving parts against gravity represents a challenge; and office machinery, where reciprocating forces are important. Aluminum PIM adds light weight, high compressibility. low sintering temperatures. easy machinability and good corrosion resistance to all advantages of conventional iron bm;ed P/rv1. Current commercial alloys are pre-mixed of either the AI-Si-Mg or AL-Cu-Mg-Si type and contain 1.5% ethylene bis-stearamide as an internal lubricant. The powder is compacted in closed dies at pressure of 200-500Mpa and sintered in nitrogen at temperatures between $580~630^{\circ}C$ in continuous muffle furnace. For some applications no further processing is required. although most applications require one or more secondary operations such as sizing and finishing. These sccondary operations improve the dimension. properties or appearance of the finished part. Aluminum is often considered difficult to sinter because of the presence of a stable surface oxide film. Removal of the oxide in iron and copper based is usually achieved through the use of reducing atmospheres. such as hydrogen or dissociated ammonia. In aluminum. this occurs in the solid st,lte through the partial reduction of the aluminum by magncsium to form spinel. This exposcs the underlying metal and facilitates sintering. It has recently been shown that < 0.2% Mg is all that is required. It is noteworthy that most aluminum pre-mixes contain at least 0.5% Mg. The sintering of aluminum alloys can be further enhanced by selective microalloying. Just 100ppm pf tin chnnges the liquid phase sintering kinetics of the 2xxx alloys to produce a tensile strength of 375Mpa. an increilse of nearly 20% over the unmodified alloy. The ductility is unnffected. A similar but different effect occurs by the addition of 100 ppm of Pb to 7xxx alloys. The lend changes the wetting characteristics of the sintering liquid which serves to increase the tensile strength to 440 Mpa. a 40% increase over unmodified aIloys. Current research is predominantly aimed at the development of metal matrix composites. which have a high specific modulus. good wear resistance and a tailorable coefficient of thermal expnnsion. By controlling particle clustering and by engineering the ceramic/matrix interface in order to enhance sintering. very attractive properties can be achicved in the ns-sintered state. I\t an ils-sintered density ilpproaching 99%. these new experimental alloys hnve a modulus of 130 Gpa and an ultimate tensile strength of 212 Mpa in the T4 temper. In contest. unreinforcecl aluminum has a modulus of just 70 Gpa.

  • PDF

Effects of water physico-chemical parameters on tilapia (Oreochromis niloticus) growth in earthen ponds in Teso North Sub-County, Busia County

  • Makori, Agano J.;Abuom, Paul O.;Kapiyo, Raphael;Anyona, Douglas N.;Dida, Gabriel O.
    • Fisheries and Aquatic Sciences
    • /
    • v.20 no.11
    • /
    • pp.30.1-30.10
    • /
    • 2017
  • Small-scale fish farmers in developing countries are faced with challenges owing to their limited information on aquaculture management. Nile tilapia farmers in Teso North Sub-County recorded lower yields than expected in 2009 despite having been provided with required inputs. Water quality was suspected to be the key factor responsible for the low yields. This study sought to assess the effects of earthen pond water physico-chemical parameters on the growth of Nile tilapia in six earthen fish ponds under semi-intensive culture system in Teso North Sub-County. The study was longitudinal in nature with pond water and fish being the units of analysis. Systematic sampling was used to select five ponds while a control pond was purposively selected based on its previously high harvest. Four ponds were fed by surface flow and two by underground water. Each pond was fertilized and stocked with 900 fry of averagely 1.4 g and 4.4 cm. Physico-chemical parameters were measured in-situ using a multi-parameter probe. Sixty fish samples were randomly obtained from each pond fortnightly for four months using a 10 mm mesh size and measured, weighed and returned into the pond. Mean range of physico-chemical parameters were: dissolved oxygen (DO) 4.86-10.53 mg/l, temperature $24-26^{\circ}C$, pH 6.1-8.3, conductivity $35-87{\mu}S/cm$ and ammonia 0.01-0.3 mg/l. Temperature (p = 0.012) and conductivity (p = 0.0001) levels varied significantly between ponds. Overall Specific Growth Rate ranged between 1.8% (0.1692 g/day) and 3.8% (1.9 g/day). Ammonia, DO and pH in the ponds were within the optimal levels for growth of tilapia, while temperature and conductivity were below optimal levels. As temperature and DO increased, growth rate of tilapia increased. However, increase in conductivity, pH and ammonia decreased fish growth rate. Temperature and DO ranging between 27 and $30^{\circ}C$ and 5-23 mg/l, respectively, and SGR of 3.8%/day and above are recommended for higher productivity.

A Study on the Velocity, the Grain Size and the Bed Depth of the Rapid Filter (급속여과지(急速濾過池)의 여과속도(濾過速度)와 여재구성(濾材構成)의 연구(硏究) -여과저항(濾過抵抗)을 중심(中心)으로-)

  • Kang, Yong Tai
    • KSCE Journal of Civil and Environmental Engineering Research
    • /
    • v.3 no.3
    • /
    • pp.1-7
    • /
    • 1983
  • In spite of extensive knowledge of the surface chemistry and the transport mechanism in filtration systems, there is still insufficient understanding of the physical characteristics of suspensions and the system components. Because of this, no filtration mechanisms are mathematically generalized to the full extent. The purpose of this paper is to propose experimental equations for the filtration process. using the tracer study in filter layer. Some of results are as follows. (1) The Volume of the specific deposit (${\sigma}$) in filtration was directly measurable using the tracer study without interrupting the filtration. (2) It was also confirmed that the head loss in filtration was greatly in fluenced by the micro-air babbles. (3) The correction coefficient(f) was introduced into the Kozeny-Carman equation in order to apply it for the clogging filter media. The coefficient(f) was experimentally obtained. The total head loss of the filter media is given by next equation. $${\frac{h}{h_0}}={\frac{1}{L}}{\int}^{z=L}_{z=0}f({\sigma})g({\varepsilon}_0,{\sigma})dz$$ $$f=aexp(-b{\sigma})$$ The above equation was applicable without regard to the variation of the suspension concentration, the filter medium diameter, the filter depth, the filtration velocity, and the amount of aluminum in all continuous filtration experiments. (4) The total head loss was graphically generalized assuming mathematical filtration models I II (see fig. 7,8) (5) The total head loss was obtained from the filtration model in the field filtration conditions. (see fig. 9,10)

  • PDF