• Title/Summary/Keyword: Specific surface are

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Synthesis of Core/Shell Graphene/Semiconductor Nanostructures for Lithium Ion Battery Anodes

  • Sin, Yong-Seung;Jang, Hyeon-Sik;Im, Jae-Yeong;Im, Se-Yun;Lee, Jong-Un;Lee, Jae-Hyeon;Wang, Junyi;Heo, Geun;Kim, Tae-Geun;Hwang, Seong-U;Hwang, Dong-Mok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.288-288
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    • 2013
  • Lithium-ion battery (LIB) is one of the most important rechargeable battery and portable energy storage for the electric digital devices. In particular, study about the higher energy capacity and longer cycle life is intensively studied because of applications in mobile electronics and electric vehicles. Generally, the LIB's capacity can be improved by replacing anode materials with high capacitance. The graphite, common anode materials, has a good cyclability but shows limitations of capacity (~374 mAh/g). On the contrary, silicon (Si) and germanium(Ge), which is same group elements, are promising candidate for high-performance LIB electrodes because it has a higher theoretical specific capacity. (Si:4200 mAh/g, Ge:1600 mAh/g) However, it is well known that Si volume change by 400% upon full lithiation (lithium insertion into Si), which result in a mechanical pulverization and poor capacity retention during cycling. Therefore, variety of nanostructure group IV elements, including nanoparticles, nanowires, and hollow nanospheres, can be promising solution about the critical issues associated with the large volume change. However, the fundamental research about correlation between the composition and structure for LIB anode is not studied yet. Herein, we successfully synthesized various structure of nanowire such as Si-Ge, Ge-Carbon and Si-graphene core-shell types and analyzed the properties of LIB. Nanowires (NWs) were grown on stainless steel substrates using Au catalyst via VLS (Vapor Liquid Solid) mechanism. And, core-shell NWs were grown by VS (Vapor-Solid) process on the surface of NWs. In order to characterize it, we used FE-SEM, HR-TEM, and Raman spectroscopy. We measured battery property of various nanostructures for checking the capacity and cyclability by cell-tester.

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THE EFFECT OF FOUR KINDS OF ACID AND CONCENTRATION ON THE FORMATION OF ARTIFICIAL CARIOUS LESION IN HUMAN TOOTH ENAMEL (수종의 유기산이 법랑질 인공우식의 형성에 미치는 영향)

  • Kum, Kee-Yeon;Lee, Chan-Young
    • Restorative Dentistry and Endodontics
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    • v.21 no.2
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    • pp.470-488
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    • 1996
  • The end products of the metabolism of the oral microorganism, organic acids, are an element that produces dental caries. Four organic acids in plaque fluid, lactic acid, acetic acid, succinic acid, propionic acid which take the important role in producing dental caries, were chosen to evaluate the effect of acid type and concentration. The subject, $100{\mu}m$ in thickness, were immersed in acid-buffer solution which has the different acid concentration of 10mM, 25mM, 50mM, 100mM and pH 4.3 and degree of saturation was $0.153{\pm}0.003$ kept in constant and were operated to produce artificial caries under different demineralization time (1, 2, 3 day) at x25. The results were obtained by observing under polarizing microscope at x25. 1. The subsurface lesion, specific finding of incipient enamel caries, showed positive birefringence. but surface zone and sound enamel showed negative birefringence. 2. The demineralization rate of enamel was increased as the acid concentration increased. 3. The subsurface lesion showed increasing depth in the order of lactic, acetic, propionic acid, succinic acid. 4. The concentration of organic acid in artificial caries system had an independent effect on demineralization rate in enamel under the constant pH and degree of saturation. The result of this study showed that not only pH and the acid strength but the concentration of organic acid had an independent effect on demineralization rate in early enamel caries. And through the further research on the factors influencing enamel demineralization, it will be necessary to develop an effective caries preventive therapy.

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Full mouth rehabilitation of a patient with severe tooth erosion with a digital crown lengthening guide (심한 부식 환자의 디지털 치관연장술 가이드를 이용한 전악 수복 증례)

  • Park, Yunjae;Hong, Seoung-Jin;Paek, Janghyun;Pae, Ahran;Kim, Hyeong-Seob
    • The Journal of Korean Academy of Prosthodontics
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    • v.57 no.3
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    • pp.280-287
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    • 2019
  • In the oral cavity, the teeth undergo wear and corrosion throughout their lives. Progressive and constant tooth wear is a natural phenomenon of aging, but wear and corrosion due to specific factors are pathological factors. It can cause pathological damage of the occlusal surface, aesthetic problems, dimensional loss and jaw joint disorders. This case is a 26-year-old female patient with general tooth abrasion and erosion on the entire dentition. Diagnostic wax-up was fabricated based on the information including digital facial analysis, physiological stabilization, and evaluation of anterior crown length. Through the digital analysis, the necessary guides for crown lengthening were prepared and the mastication function and esthetics were evaluated by using temporary crowns. Definitive prosthesis was fabricated with the zirconia restorations. The results were satisfactory when they were observed 3 months of follow-up.

The Effects of Direction Changes on the Muscular Activity of the Lower Extremities During Seated Reaching Exercises

  • Kim, Jwa-Jun;Kim, Dae-Kyung;Kim, Jae-Yong;Shin, Jae-Wook;Park, Se-Yeon
    • PNF and Movement
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    • v.17 no.2
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    • pp.207-214
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    • 2019
  • Purpose: Although multi-directional reaching exercises are commonly used clinically, the effects of specific movement directions on the muscle systems of the lower extremities have not been explored. We therefore investigated lower extremity muscle activity during reaching exercises with different sagittal and horizontal plane movements. Methods: The surface electromyography responses of the bilateral rectus femoris, tibialis anterior, peroneus longus, and gastrocnemius muscles were measured during reaching exercises in three directions in the horizontal plane (neutral, $45^{\circ}$ horizontal shoulder adduction, and $45^{\circ}$ abduction) and three directions in the sagittal plane (neutral, $120^{\circ}$ flexion, and $60^{\circ}$ flexion). A total of 20 healthy, physically active participants completed six sets of reaching exercises. Two-way repeated ANOVA was performed: body side (ipsilateral and contralateral) was set as the intra-subject factor and direction of reach as the inter-subject factor. Results: Reaching at $45^{\circ}$ horizontal shoulder adduction significantly increased the activity of the contralateral rectus femoris and gastrocnemius muscles, while $45^{\circ}$ horizontal shoulder abduction activated the ipsilateral rectus femoris and gastrocnemius muscles. The rectus femoris activity was significantly higher with reaching at a $120^{\circ}$ shoulder flexion compared to the other conditions. The gastrocnemius activity decreased significantly as the shoulder elevation angle increased from $60^{\circ}$ to $120^{\circ}$. Conclusion: Our results suggest that multi-directional reaching stimulates the lower extremity muscles depending on the movement direction. The muscles acting on two different joints responded to the changes in reaching direction, whereas the muscles acting on one joint were not activated with changes in reaching direction.

Application of Membranes for Biological Waste Gas Treatment Processes (생물학적 폐가스 처리공정 내 멤브레인 활용)

  • Lee, Sang-hun
    • Membrane Journal
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    • v.31 no.5
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    • pp.327-332
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    • 2021
  • The use of membranes for MBRWG (Membrane Bioreactor for Waste Gas) treatment can provide highly selective separation of a waste gas stream followed by effective biological removal. MBRWG have several potential advantages, among which the most distinctive one is separation of gas and liquid phases at each side of membrane potentially allowing the optimal biomass control toward effective biodegradation of target gases as well as biofilm activation. This advantage becomes especially favorable for removal of hydrophobic toxic gases, such as xylene, by MBRWG systems, because the mass transfer, the toxicity, and thereby the biodegradation of hydrophobic gas treatment requires sensitive handling of liquid stream and water control near biofilm. Among various membranes for MBRWG treatment, PDMS-hollow fiber membranes provide the high gas mass transfer. Despite lower specific surface areas, capillary type membranes are also applied current MBRWG studies. In addition to the main application of membranes as biofilm supporter in MBRWG systems, there can be another application of membranes in a posterior process for removal of residual gases or dusts emitted from conventional biological waste gas treatment processes.

Compression of DSM Files Based on Quad BTC for Terrain Reference Flight (지형 참조 비행을 위한 Quad BTC 기반의 DSM 파일 압축)

  • Min, Gyung-Chul;Ko, Yun-Ho
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.50 no.7
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    • pp.515-521
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    • 2022
  • In this paper, we propose Quad BTC that compresses DSM files to allow random access for TRF (Terrain Referenced Flight). The terrain data used for TRF has a large data capacity to be stored in the UAV (Unmanned Aerial Vehicle), so its size must be reduced through compression. Conventional BTC (Block Truncation Coding) based compression methods are suitable for TRF because it can decode randomly accessing specific coordinates. However, These conventional methods have a problem that the error increases because the deviation of the data increases as the size of the block increases. In this paper, we propose Quad BTC method that adaptively divides a block in to 4 sub blocks and compresses to solve this problem. The proposed method may reduce errors because the size of the sub block can be adjusted within the block. Through simulation using actual terrain data, it is verified that Quad BTC has less error at the same compression ratio than conventional BTC and AM BTC.

A computed tomography-based analysis of the structure of the mandible according to age and sex

  • Jung, Soyeon;Yun, Hyunjong;Chung, Chul Hoon;Kim, Kuylhee;Chang, Yongjoon
    • Archives of Craniofacial Surgery
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    • v.23 no.3
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    • pp.103-110
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    • 2022
  • Background: The primary objectives of mandibular surgery are to achieve optimal occlusion, low sensory disturbance, and adequate fixation with early movement. In-depth knowledge of the mandibular structure is required to achieve these goals. This study used computed tomography (CT) to evaluate the mandibular cortical thickness and cancellous space according to age and sex. Methods: We enrolled 230 consecutive patients, aged 20 to 50 years, who underwent CT scanning. The cortex and cancellous space centered around the inferior alveolar nerve (IAN) canal were measured at two specific locations: the lingula and second molar region. Statistical analysis of differences according to increasing age and sex was performed. Results: The t-test revealed that the cancellous space and cortical thickness differed significantly with respect to the threshold of 35 years of age. Both cortical thickness and cancellous space in the molar region were negatively correlated with age. Meanwhile, both cortical thickness and cancellous space in the lingula region showed a positive correlation with age. With respect to sex, significant differences in the cancellous space at the molar region and the cortical thickness at the lingula were observed. However, no further statistically significant differences were observed in other variables with respect to sex. The sum of each measurement on the mandibular body reflected the safe distance from the surface of the outer cortex to the IAN canal. The safe distances also showed statistically significant differences between those above and below 35 years of age. Conclusion: Knowledge of the anatomical structure of the mandible and of changes in bone structure is crucial to ensure optimal surgical outcomes and avoid damage to the IAN. CT examination is useful to identify changes in the bone structure, and these should be taken into account in the planning of surgery for older patients.

Synthesis of ginsenoside Rb1-imprinted magnetic polymer nanoparticles for the extraction and cellular delivery of therapeutic ginsenosides

  • Liu, Kai-Hsi;Lin, Hung-Yin;Thomas, James L.;Shih, Yuan-Pin;Yang, Zhuan-Yi;Chen, Jen-Tsung;Lee, Mei-Hwa
    • Journal of Ginseng Research
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    • v.46 no.5
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    • pp.621-627
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    • 2022
  • Background: Panax ginseng (ginseng) is a traditional medicine that is reported to have cardioprotective effects; ginsenosides are the major bioactive compounds in the ginseng root. Methods: Magnetic molecularly imprinted polymer (MMIP) nanoparticles might be useful for both the extraction of the targeted (imprinted) molecules, and for the delivery of those molecules to cells. In this work, plant growth regulators were used to enhance the adventitious rooting of ginseng root callus; imprinted polymeric particles were synthesized for the extraction of ginsenoside Rb1 from root extracts, and then employed for subsequent particle-mediated delivery to cardiomyocytes to mitigate hypoxia/reoxygenation injury. Results: These synthesized composite nanoparticles were first characterized by their specific surface area, adsorption capacity, and magnetization, and then used for the extraction of ginsenoside Rb1 from a crude extract of ginseng roots. The ginsenoside-loaded MMIPs were then shown to have protective effects on mitochondrial membrane potential and cellular viability for H9c2 cells treated with CoCl2 to mimic hypoxia injury. The protective effect of the ginsenosides was assessed by staining with JC-1 dye to monitor the mitochondrial membrane potential. Conclusion: MMIPs can play a dual role in both the extraction and cellular delivery of therapeutic ginsenosides.

A combined application of molecular docking technology and indirect ELISA for the serodiagnosis of bovine tuberculosis

  • Song, Shengnan;Zhang, Qian;Yang, Hang;Guo, Jia;Xu, Mingguo;Yang, Ningning;Yi, Jihai;Wang, Zhen;Chen, Chuangfu
    • Journal of Veterinary Science
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    • v.23 no.3
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    • pp.50.1-50.12
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    • 2022
  • Background: There is an urgent need to find reliable and rapid bovine tuberculosis (bTB) diagnostics in response to the rising prevalence of bTB worldwide. Toll-like receptor 2 (TLR2) recognizes components of bTB and initiates antigen-presenting cells to mediate humoral immunity. Evaluating the affinity of antigens with TLR2 can form the basis of a new method for the diagnosis of bTB based on humoral immunity. Objectives: To develop a reliable and rapid strategy to improve diagnostic tools for bTB. Methods: In this study, we expressed and purified the sixteen bTB-specific recombinant proteins in Escherichia coli. The two antigenic proteins, MPT70 and MPT83, which were most valuable for serological diagnosis of bTB were screened. Molecular docking technology was used to analyze the affinity of MPT70, MPT83, dominant epitope peptide of MPT70 (M1), and dominant epitope peptide MPT83 (M2) with TLR2, combined with the detection results of enzyme-linked immunosorbent assay to evaluate the molecular docking effect. Results: The results showed that interaction surface Cα-atom root mean square deviation of proteins (M1, M2, MPT70, MPT83)-TLR2 protein are less than 2.5 A, showing a high affinity. It is verified by clinical serum samples that MPT70, MPT83, MPT70-MPT83 showed good diagnostic potential for the detection of anti-bTB IgG and M1, M2 can replace the whole protein as the detection antigen. Conclusions: Molecular docking to evaluate the affinity of bTB protein and TLR2 combined with ELISA provides new insights for the diagnosis of bTB.

Investigation of 0.5 MJ superconducting energy storage system by acoustic emission method.

  • Miklyaev, S.M.;Shevchenko, S.A.;Surin, M.I.
    • Proceedings of the KIPE Conference
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    • 1998.10a
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    • pp.961-965
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    • 1998
  • The rapid development of small-scale (1-10 MJ) Superconducting Magnetic Energy Storage Systems (SMES) can be explained by real perspective of practical implementation of these devices in electro power nets. However the serious problem of all high mechanically stressed superconducting coils-problem of training and degradation (decreasing) of operating current still exists. Moreover for SMES systems this problems is more dangerous because of pulsed origin of mechanical stresses-one of the major sources of local heat disturbances in superconducting coils. We investigated acoustic emission (AE) phenomenon on model and 0.5 MJ SMES coils taking into account close correlation of AE and local heat disturbances. Two-coils 0.5 MJ SMES system was developed, manufactured and tested at Russian Research Center in the frames of cooperation with Korean Electrical Engineering Company (KEPCO) [1]. The two-coil SMES operates with the stored energy transmitted between coils in the course of a single cycle with 2 seconds energy transfer time. Maximum operating current 1.55 kA corresponds to 0.5 MF in each coil. The Nb-Ti-based conductor was designed and used for SMES manufacturing. It represents transposed cable made of Nb-Ti strands in copper matrix, several cooper strands and several stainless steel strands. The coils are wound onto fiberglass cylindrical bobbins. To make AE event information more useful a real time instrumentation system was used. Two main measured and computer processed AE parameters were considered: the energy of AE events (E) and the accumulated energy of AE events (E ). Influence of current value in 0.5 MJ coils on E and E was studied. The sensors were installed onto the bobbin and the external surface of magnets. Three levels of initial current were examined: 600A, 1000A, 2450 A. An extraordinary strong dependence of the current level on E and E was observed. The specific features of AE from model coils, operated in sinusoidal vibration current changing mode were investigated. Three current frequency modes were examined: 0.012 Hz, 0.03 Hz and 0.12 Hz. In all modes maximum amplitude 1200 A was realized.

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