• 제목/요약/키워드: Specific surface are

검색결과 1,394건 처리시간 0.028초

화학적 표면처리에 따른 카본블랙/고무 복합재료의 접착력 증가 (Chemical Surface Treatment of Carbon Black to Enhance Interfacial Adhesion Between Elastomer and Carbon Black)

  • 김정순;이재락;신채호;나창운;박수진
    • Elastomers and Composites
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    • 제34권3호
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    • pp.222-228
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    • 1999
  • 본 연구에서는, 화학적 표면처리에 따른 카본블랙의 표면, 흡착, 그리고 미세구조의 성질과 물리적 표면 자유에너지를 고찰하였다. 실험적 결과를 통하여, 염기성 용액으로 표면 처리한 경우 pH와 비표면적의 변화 없이 표면 자유에너지의 비극성 또는 극성요소의 증가를 가져왔다. 반면에 산성표면처리의 경우에는 표면특성, 흡착성질과 미세구조의 큰 변화를 확인하였다. 특히, 염기성 처리된 카본블랙은 비극성이나 비표면적의 중요한 인자로 표면 자유에너지의 London 비극성 요소의 증가를 볼 수 있었다. 이는 카본블랙/고무 복합재료에 있어서, 카본블랙이 강화재의 역할 뿐 아니라 분산력 발달에 중요한 역할을 담당하고 있기 때문으로 사료된다.

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컴프레서용 Al-Si 합금의 파괴 및 마모 특성 (Fracture and Wear Characteristics of Al-Si alloy used for Compressor)

  • 김재훈;김덕회
    • Tribology and Lubricants
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    • 제15권2호
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    • pp.141-149
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    • 1999
  • Fracture, fatigue and wear characteristics of Al-Si alloy used for compressor are experimentally studied. Plane strain fracture toughness test is carried out using three point bending specimen. Fatigue test is performed under constant loading condition and wear test is carried out as a function of sliding velocity and applied load. To obtain the crack propagation characteristics and wear mechanism of Al-Si alloy, fracture and worn surfaces are investigated using SEM. It is verified that fracture and fatigue strength of Al-Si alloy are improved by the fine microstructure of alloy. The wear behavior and specific wear amount of Al-Si alloy are not dependent on the microstructure but on a function of the silicon content. Anodizing on the surface of Al-Si alloy, surface hardness and wear characteristics are improved.

다공성(多孔性) 유리메디아를 이용한 고정상(固定床) 생물막법(生物膜法)에 관한 연구(硏究) (A Study on a Fixed Bed Biofilm Process Using Porous Glass Media)

  • 윤태일;김재훈
    • 상하수도학회지
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    • 제10권1호
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    • pp.112-120
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    • 1996
  • In this study, the porous glass media was utilized as biomass carrier, and the optimum characteristics of this new media in fixed bed biofilm process were investigated. The characteristics of media considered here are a void volume fraction, a specific surface area, and surface characteristics of media. The effect of surface roughness and material could be clearly demonstrated by the fact that the porous glass media showed a good potential for biofilm development. This might results from the fact that biofilm is initially formed in the surface cavities of the media is protect from the shear effect. Therefore, the microcolonies are not readily detached by the fluid shear. In the steady state, biofilm formation along the packing bed depth was different from media to media. The specific area was also an important factor for the attachment of microorganism on the media surface. The specific area was also an important factor for the attachment of microorganism on the media surface. In the case of porous glass media, about $100m^2/m^3$ was enough to obtain a good organic removal efficiency The organic removal efficiency could be improved by increasing the void volume fraction in the reactor, at least 80% was required to obtain a high removal efficiency and prevent clogging. From the analysis of kinetics study, the yield coefficient, Y, was 0.42 mgMLSS/mgSBOD, endogenous respiration coefficient, ke, was $0.12day^{-1}$ and substrate removel coefficient of Mckinney. km, was $16.8hr^{-1}$ for the porous glass media G-2

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Electro-Chemical Reduction에 의한 $Hg_{1-x}Cd_{x}$Te재료의 특성 고찰 (A Research of the Characteristics of $Hg_{1-x}Cd_{x}$Te material by using Electro - Chemical Reduction)

  • 이상돈;김봉흡;강형부
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1994년도 춘계학술대회 논문집
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    • pp.38-41
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    • 1994
  • The method of passivation for protecting the $Hg_{1-x}Cd_{x}$Te surface is important device fabrication process. Because the surface components are highly reactive leading to its chemical and electrical instability. Especially. the material of detecting for infrared radiation, of which composition is x=0.2 or 0.3, is narrow bandgap semi- conductor. The narrow bandgap semi conductors are largely governed by the properties of the semiconductor surface. The narrow bandgap semi-conductors are largely governed by the properties of the semiconductor surface. The electro-chemical processing of $Hg_{1-x}Cd_{x}$Te allows rigorous control of the surface chemistry and provides an in-suit monitor of surface reaction. So electro-chemical reduction at specific potential can be selectively eliminated the undesirable species on the surface and mainpulated to reproducibly attain the desired stoichiometry. This method shows to assess the quality of chemically treated good $Hg_{1-x}Cd_{x}$Te surface.

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CNTs 합성을 통해 향상된 비표면적을 갖는 Ti 다공체의 제조 (Fabrication of Ti Porous body with Improved Specific Surface Area by Synthesis of CNTs)

  • 최혜림;변종민;석명진;오승탁;김영도
    • 한국분말재료학회지
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    • 제23권3호
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    • pp.235-239
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    • 2016
  • This study is performed to fabricate a Ti porous body by freeze drying process using titanium hydride ($TiH_2$) powder and camphene. Then, the Ti porous body is employed to synthesize carbon nanotubes (CNTs) using thermal catalytic chemical vapor deposition (CCVD) with Fe catalyst and methane ($CH_4$) gas to increase the specific surface area. The synthesized Ti porous body has $100{\mu}M$-sized macropores and $10-30{\mu}m$-sized micropores. The synthesized CNTs have random directions and are entangled with adjacent CNTs. The CNTs have a bamboo-like structure, and their average diameter is about 50 nm. The Fe nano-particles observed at the tip of the CNTs indicate that the tip growth model is applicable. The specific surface area of the CNT-coated Ti porous body is about 20 times larger than that of the raw Ti porous body. These CNT-coated Ti porous bodies are expected to be used as filters or catalyst supports.

Characteristics of Pt-Ru Catalyst Supported on Activated Carbon for Direct Methanol Fuel Cell

  • Jung, Doo-Hwan;Jung, Jae-Hoon;Hong, Seong-Hwa;Peck, Dong-Hyun;Shin, Dong-Ryul;Kim, Eui-sik
    • Carbon letters
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    • 제4권3호
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    • pp.121-125
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    • 2003
  • The Pt-Ru/Carbon as an anode catalyst supported on the commercial activated carbon (AC) having high surface area and micropore was characterized for application of Direct Methanol Fuel Cell (DMFC). The Pt-Ru/AC anode catalyst used in this experiment showed the performance of $600\;mA/cm^2$ current density at 0.3 V. The borohydride reduction process using $NaBH_4$, denoted as a process A, showed much higher current and power densities than process B prepared by changing the reduction and washing process of process A. The particle sizes are strongly affected by the reduction process than the specific surface area of raw active carbon and the sizes are almost constant when the specific surface area of carbon are over than the $1200\;m^2/g$. Smaller particle size of catalyst and more narrow intercrystalite distance increased the performance of DMFC.

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위성과 부이자료를 이용한 현.잠열 추정에 관한 연구 (Estimation of Sensible and Latent Heat Fluxes Using the Satellite and Buoy Data)

  • 홍기만;김영섭;윤홍주;박경원
    • 대한원격탐사학회:학술대회논문집
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    • 대한원격탐사학회 2001년도 춘계 학술대회 논문집 통권 4호 Proceedings of the 2001 KSRS Spring Meeting
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    • pp.104-110
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    • 2001
  • Ocean heat fluxes over a wide region are generally estimated by an aerodynamic bulk fromula. Though a remote sensing technique can be expected to estimated global heat flux, it is difficult to obtain air temperature and specific humidity at sea surface by a remote sensor. In this study present a new method with which to determine near-sea surface air temperature from in situ data. Also, These methods compared with other methods. A new method used a linear regression equation between sea surface temperature and air temperature of the buoys data. In this study new method is validated using observed monthly mean data at the Japan Meteorological Agency(JMA), National Data Buoy Center(NDBC) and Tropical Ocean-Global Atmosphere(TOGA)-Tropical Atmosphere Ocean(TAO) buoys. The result that bias and rmse are 0.28, 1.5$0^{\circ}C$ respectively. The correlation coefficient is 0.98. Also, to retrieve near-sea surface specific humidity(Q) from good nonlinear regression relationship between vapor pressure(Ea) of buoy data and air temperature, after obtained the third-order polynomial function, compared with that of estimated from SSM/I empirical equation by Schussel et al(1995). The result that bias and rmse are -1.42 and 1.75(g/kg).

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Laser Powder Bed Fusion 공정으로 제조된 Ti-6Al-4V 격자 구조물의 최적 설계 기법 연구 (A Study on the Optimal Design of Ti-6Al-4V Lattice Structure Manufactured by Laser Powder Bed Fusion Process)

  • 김지윤;우정민;손용호;김정호;이기안
    • 한국분말재료학회지
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    • 제30권2호
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    • pp.146-155
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    • 2023
  • The Ti-6Al-4V lattice structure is widely used in the aerospace industry owing to its high specific strength, specific stiffness, and energy absorption. The quality, performance, and surface roughness of the additively manufactured parts are significantly dependent on various process parameters. Therefore, it is important to study process parameter optimization for relative density and surface roughness control. Here, the part density and surface roughness are examined according to the hatching space, laser power, and scan rotation during laser-powder bed fusion (LPBF), and the optimal process parameters for LPBF are investigated. It has high density and low surface roughness in the specific process parameter ranges of hatching space (0.06-0.12 mm), laser power (225-325 W), and scan rotation (15°). In addition, to investigate the compressive behavior of the lattice structure, a finite element analysis is performed based on the homogenization method. Finite element analysis using the homogenization method indicates that the number of elements decreases from 437,710 to 27 and the analysis time decreases from 3,360 to 9 s. In addition, to verify the reliability of this method, stress-strain data from the compression test and analysis are compared.

죽탄 및 죽초액 제조를 위한 인도네시아산 및 국내산 대나무의 탄화특성 비교 연구 (A Study on Carbonization Characteristics of Indonesian and Korean Bamboo for Production of Bamboo Charcoal and Vinegar)

  • 양원;김희열;채태영
    • 한국연소학회지
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    • 제15권1호
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    • pp.30-37
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    • 2010
  • Carbonization characteristics of Indonesian bamboos were investigated using lab-scale tube furnace, in order to find optimum design temperature of a carbonizer for producing bamboo charcoal and vinegar. The bamboo samples used in this study are local bamboos from Damyang in Korea, Andong and Petung in Indonesia. Correlation of electric resistance, specific surface area and pH of bamboo vinegar with pyrolysis temperature has been investigated. Electric resistance of the charcoal increased for higher pyrolysis temperature the specific surface area was also increased as carbonization temperature got higher. Charcoal which has specific surface area of over $300\;m^2/g$ could be produced at $700^{\circ}C$. pH of bamboo vinegar was decreased for highter carbonization temperature and vinegar under pH 3 could be produced for all bamboo samples. In this experimental condition, it was found that lower carbonization temperature is better for producing bamboo vinegar of high quality, while higher temperature is better for obtaining bamboo charcoal with larger surface.

Distribution of Silver Particles in Silver-containing Activated Carbon Fibers

  • Ryu, S.K.;Eom, S.Y.;Cho, T.H.;Edie, D.D.
    • Carbon letters
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    • 제4권4호
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    • pp.168-174
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    • 2003
  • Silver nitrate ($AgNO_3$) powder was mixed into a reformed pitch precursor. Then, the silver-containing pitch was melt spun to form round and "C" shape fibers. A wire mesh was inserted prior to the nozzle to improve the spinnability of the silvercontaining precursor pitch. Silver particles in the carbon fibers (CFs) were detected by XRD and TEM. These tests showed that silver particles were uniformly distributed and the total amount of silver remained constant during stabilization and carbonization. Next, the silver-containing CFs were activated by steam diluted in nitrogen gas. Silver particles accelerated the activation rate, but the specific surface areas of the silver-containing ACFs were similar to those of non-silver containing ACFs at the same burn-off levels. The specific surface area of the C-shaped activated carbon fibers was larger than that of the round activated carbon fibers. The likely reason is that the surface area of a C-shaped CF is about two times larger than that of a round CF when equivalent cross-sectional areas are compared. A small amount of silver particles in the periphery of the CFs was removed during the activation, but the remainder of silver was stayed within the ACFs.

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