• 한국수자원학회논문집
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• 제41권6호
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• pp.605-617
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• 2008

본 연구에서는 우리나라 홍수유출의 특성을 종합적으로 표현할 수 있는 홍수지수를 개발하였다. 홍수유출특성을 종합적으로 지수에 반영하기 위하여 유출곡선으로 표현되는 홍수유출의 특성을 홍수수문곡선의 상승률, 첨두유량, 홍수 응답시간, 첨두발생 전 홍수용적 등 4가지의 특성인자로 표현하였다. 이러한 유출특성인자를 객관적인 상대심도로 표현하기 위하여 본 연구에서는 특성인자의 분포함수를 표준정규분포함수로 변환하여 특성지수를 산정하였다. 본 연구에서 산정한 종합홍수지수(Comprehensive Flood Index, CFI)는 기존의 돌발홍수지수(Flash Flood Index, FFI)의 문제점을 보완한 것으로 홍수의 심도를 유역별로 상대평가할 수 있는 특징이 있다. 본 연구에서는 한강과 설마천 유역에 대하여 CFI를 산정하고, 상관분석과 회귀분석을 통해 FFI와 비교 평가하였다. CFI는 산정과정에서 특정 홍수유출 특성에 지배받지 않아 종합적으로 홍수유출특성을 표현할 수 있고, FFI에 비해 강우-유출관계를 효과적으로 설명할 수 있었다.

• 한국산업융합학회 논문집
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• 제6권1호
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• pp.81-86
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• 2003

For the simultaneous removal of $SO_2$/NOx from an iron-ore sintering plant, industrial plasma experiments have been conducted with a flue gas flow rate of $5,000Nm^3/hr$. The maximum 40kW power using the magnetic pulse compression (MPC) system generates a peak value of 100-150kV pulse voltage with its risetime of 200nsec and full width at half maximum (FWHM) of 500nsec, and with a frequency <300Hz. The plasma reactor module adopts a wire-plate structure with a gap of 200-400mm ID between plates. Initial concentrations of $SO_2$ and NOx were around 100-150ppm, respectively in the presence of 15% $O_2$ and <10% $H_2O$. Various reaction parameters such as specific energy ($Whr/Nm^3$), $NH_3$ injection with corona discharge, flow rate and injection of hydrocarbons were investigated for $SO_2$/NOx removal characteristics. About 90/65% of $SO_2$/NOx were simultaneously removed with a specific energy of $3.0Whr/Nm^3$ when both $NH_3$ and hydrocarbons were injected. Practical implications that the pilot-scale plasma results provide are further discussed.

• Current Applied Physics
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• 제18권11호
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• pp.1399-1402
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• 2018

Nanorod films of cobalt oxide ($Co_3O_4$) have been grown by a unique oblique angle deposition (OAD) technique in an e-beam evaporator for supercapacitor electrode applications. This technique offers a non-chemical route to achieve large aspect ratio nanorods. The fabricated electrodes at OAD $80^{\circ}$ exhibited a specific capacitance of 2875 F/g. The electrochemically active surface area was $1397cm^{-2}$, estimated from the non-Faradaic capacitive current region. Peak energy and power densities obtained for $Co_3O_4$ nanorods were 57.7 Wh/Kg and 9.5 kW/kg, respectively. The $Co_3O_4$ nanorod electrode showed a good endurance of 2000 charge-discharge cycles with 62% retention. The OAD approach for fabricating supercapacitor nanostructured electrodes can be exploited for the fabrication of a broad range of metal oxide materials.

• 전기화학회지
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• 제7권3호
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• pp.131-137
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• 2004

Sol-gel method which provides better electrochemical and physiochemical properties compared to the solid-state method was used to synthesize the material of $LiFe_yMn_{2-y}O_4$. Fe was substituted to increase the structural stability so that the effects of the substitution amount and sintering temperature were analyzed. XRD was used for the structural analysis of produced material, which in turn, showed the same cubic spinel structure as $LiMn_2O_4$ despite the substitution of $Fe^{3+}$. During the synthesis of $LiFe_yMn_{2-y}O_4$, as the sintering temperature and the doping amount of Fe(y=0.05, 0.1, 0.2)were increased, grain growth proceeded which in turn, showed a high crystalline and a large grain size, certain morphology with narrow specific surface area and large pore volume distribution was observed. In order to examine the ability for the practical use of the battery, charge-discharge tests were undertaken. When the substitution amount of $Fe^{3+}\;into\;LiMn_2O_4$ increased, the initial discharge capacity showed a tendency to decrease within the region of $3.0\~4.2V$ but when charge-discharge processes were repeated, other capacity maintenance properties turned out to be outstanding. In addition, when the sintering temperature was $800\~850^{\circ}C$, the initial capacity was small but showed very stable cycle performance. According to EVS(electrochemical voltage spectroscopy) test, $LiFe_yMn_{2-y}O_4(y=0,\;0.05,\;0.1,\;0.2)$ showed two plateau region and the typical peaks of manganese spinel structure when the substitution amount of $Fe^{3+}$ increased, the peak value at about 4.15V during the charge-discharge process showed a tendency to decrease. From the previous results, the local distortion due to the biphase within the region near 4.15V during the lithium extraction gave a phase transition to a more suitable single phase. When the transition was derived, the discharge capacity decreased. However the cycle performance showed an outstanding result.

• Bulletin of the Korean Chemical Society
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• 제21권11호
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• pp.1125-1132
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• 2000

The pH effect of the precursor solution on the preparation of $LiCoO_2$ by a solution phase reaction containing malonic acid was carried out. Layered $LiCoO_2$ powders were obtained with the precursors prepared at the different pHs (4, 7, and 9) and heat-treated at $700^{\circ}C(LiCoO_2-700)$ or $850^{\circ}C(LiCoO_2-850)$ in air. pHs of the media for precursor synthesis affects the charge/discharge and electrochemical properties of the $LiCoO_2electrodes.$ Upon irrespective of pH of the precursor media, X-ray diffraction spectra recorded for $LiCoO_2-850$ powder showed higher peak intensity ratio of I(003)/I(104) than that of $LiCoO_2-700$, since the better crystallization of the former crystallized better. However, $LiCoO_2$ synthesized at pH 4 displayed an abnormal higher intensity ratio of I(003)/I(104) than those synthesized at pH 7 and 9. The surface morphology of the $LiCoO_2-850$ powders was rougher and more irregular than that of $LiCoO_2-700$ made from the precursor synthesized at pH 7 and 9. The $LiCoO_2electrodes$ prepared with the precursors synthesized at pH 7 and 9 showed a better electrochemical and charge/discharge characteristics. From the AC impedance spectroscopic experiments for the electrode made from the precursor prepared in pH 7, the chemical diffusivity of Li ions (DLi+) in $Li0.58CoO_2determined$ was 2.7 ${\times}$10-8 $cm^2s-1$. A cell composed of the $LiCoO_2-700$ cathode prepared in pH 7 with Lithium metal anode reveals an initial discharge specific capacity of 119.8 mAhg-1 at a current density of 10.0 mAg-1 between 3.5 V and 4.3 V. The full-cell composed with $LiCoO_2-700$ cathode prepared in pH 7 and the Mesocarbon Pitch-based Carbon Fiber (MPCF) anode separated by a Cellgard 2400 membrane showed a good cycleability. In addition, it was operated over 100 charge/discharge cycles and displayed an average reversible capacity of nearly 130 mAhg-1.

• 환경정책연구
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• 제9권1호
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• pp.83-107
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• 2010

본 연구의 목적은 빗물저류 및 흡수 등 우수관리를 위해 설치하는 최적관리기법(Best Management Practices: BMPs)의 효율적인 위치 및 분배 정도를 유역단위에서 살펴보는 것이다. 이를 위해 여러 개의 지류유역과 본류유역으로 이루어진 하나의 대유역을 구축한 후 Hydrological Simulation Program Fortran(HSPF)을 이용하여 도시유역 내다양한 규모와 위치의 BMPs 시나리오를 제작/모의하였다. 이때 대유역 내 전체 BMPs 면적은 일정하도록 하였으며, 유역하구의 첨두유량과 이와 관련된 회피비용을 효율성의 지표로 활용하였다. 모의 결과 BMPs가 상류지류 유역들에 분산 입지했을 때 가장 높은 효율을 보였으며, 본류유역을 포함하여 소유역 한 곳에 집중되었을 때 가장 낮은 효율을 보였다. 하지만 본 연구는 BMPs의 위치 및 분배 변수를 제외한 BMPs 설계 및 유지관리, 유역 내 다양한 토양특성등의 기타변수가 통제된 가상유역을 대상으로 진행되었다는 한계를 안고 있다. 따라서 본 연구는 유역관리에서 BMPs위치 및 분배가 유역관리에 중요한 정책변수일 수 있다는 가능성을 제시하는 데 그치고 있으며, 이러한 가능성은 향후 국내유역에 대한 실증적 모의연구를 통해 논의될 수 있을 것이다.

• 전기화학회지
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• 제5권2호
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• pp.74-78
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• 2002

아연공기전지는 공기중의 산소를 사용하므로 cathode의 재활용이 가능하다는 장점이 있으며 아연의 이론용량이 820(mAh/g)으로 상당히 높다. 그러나, 아연공기전지는 cathodf치 기공이 너무 작으면 외부로부터 유입되는 산소량이 부족하여 전지의 방전전압이 낮아지는 결과를 초래하게 되며 cathode에 포함되어 있는 도전재의 함량에 따라 저항 및 기공율에 많은 변화를 보이고 있다. 이에 본 연구에서는 전지의 용량, 출력특성, 방전전압, DC저항, ASTM에 의한 기공율 측정을 통해 도전재의 종류 및 함량이 아연공기전지에 미치는 영향을 연구하였으며, Super P의 도전재를 $5wt\%$ 첨가하였을 때 가장 우수한 전지특성을 얻을 수 있었다.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2004년도 제22회 춘계학술대회논문집
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• pp.577-587
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• 2004

A coaxial pulsed plasma thruster (PPT) with a Teflon cavity was designed, and its performance characteristics were examined varying stored energy, cavity length and capacitance. The PPT was tested as the entire system including the discharge circuit, and the results were explained with both the transfer efficiency and the acceleration efficiency. The transfer efficiency is defined as the fraction of energy in capacitors supplied into plasma, and the acceleration efficiency as the fraction of energy supplied into plasma converted to thrust energy. To estimate these efficiencies, the equivalent plasma resistance was defined and calculated using energy conservation during discharge. The equivalent plasma resistance proportionally increased with cavity length, and therefore the current peak increased with decreasing cavity length. The energy density calculated by the transfer efficiency was increased with decreasing cavity length. As a result, higher acceleration efficiency and lower transfer efficiency were obtained with shorter cavity length. Accordingly, there was an optimal cavity length for the thrust efficiency. The specific impulse and the impulse bit per unit stored energy ranged from 390 s and 50 $\mu$ Ns/J for a cavity length of 34 mm to 825 s and 11 $\mu$ Ns/J for a cavity length of 4 mm when the stored energy was fixed to 21.4J. Thus, it was showed that the performance of this PPT approached that of electromagnetic-acceleration-type PPT with decreasing cavity length. The PPT achieved thrust efficiencies of 10-12% at 21.4 J and 6-7% at 5.35 J at cavity lengths between 14 mm and 29 mm.

• 한국방재학회 논문집
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• 제11권1호
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• pp.77-84
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• 2011

각종 수공구조물 설계를 위한 첨두홍수량을 추정시 합리식(rational formula) 및 가지야마(Kajiyama)공식 등을 사용하고 있으나, 이러한 방법들을 이용하여 가능최대홍수량(PMF)을 산정하기 위해서는 가능최대강수량(PMP)의 추정이 선행되어야 하므로 미계측지역에서는 적용에 상당한 제약이 따른다. Creager 등이 1945년에 제시한 Creager방법은 비홍수량산정기법의 일종으로 유역면적과 PMF사이의 비선형성을 직접 수식화하여 제공하므로 PMP값이 주어지지 않은 상황에서 PMF산정이 가능하며, 주로 중규모이상 다목적댐의 PMF 산정시 사용되어 왔는데, 국내에는 아직 적용된 사례가 많지 않다. 본 연구에서는 PMP도를 이용한 강우-유출 모델로 산정된 상수전용댐과 다목적댐의 PMF를 이용하여 유역규모와 강우지속시간에 따라 보편적으로 적용할 수 있는 Creager 공식의 매개변수와 Creager 계수값의 결정범위 및 기준 등을 산정하여 국내 유역에 적용가능한 방법을 제시하였다.

• International Journal of Fluid Machinery and Systems
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• 제3권4호
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• pp.352-359
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• 2010

In recent years, the market has shown increasing interest in pump-turbines. The prompt availability of pumped storage plants and the benefits to the power system achieved by peak lopping, providing reserve capacity, and rapid response in frequency control are providing a growing advantage. In this context, there is a need to develop pumpturbines that can reliably withstand dynamic operation modes, fast changes of discharge rate by adjusting the variable diffuser vanes, as well as fast changes from pumping to turbine operation. In the first part of the present study, various flow patterns linked to operation of a pump-turbine system are discussed. In this context, pump and turbine modes are presented separately and different load cases are shown in each operating mode. In order to create modern, competitive pump-turbine designs, this study further explains what design challenges should be considered in defining the geometry of a pump-turbine impeller. The second part of the paper describes an innovative, staggered approach to impeller development, applied to a low head pump-turbine project. The first level of the process consists of optimization strategies based on evolutionary algorithms together with 3D in-viscid flow analysis. In the next stage, the hydraulic behavior of both pump mode and turbine mode is evaluated by solving the full 3D Navier-Stokes equations in combination with a robust turbulence model. Finally, the progress in hydraulic design is demonstrated by model test results that show a significant improvement in hydraulic performance compared to an existing reference design.