• Title/Summary/Keyword: Specific heat capacity

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The Cooling Characteristics of Clathrate Compound according to Concentration of TMA

  • Lee, Jong-In;Kim, Chang-Oh;Chung, Nak-Kyu
    • International Journal of Air-Conditioning and Refrigeration
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    • v.17 no.1
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    • pp.32-36
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    • 2009
  • The ice storage system uses water for low temperature latent heat storage. However, a refrigerator capacity is increased and COP is decreased due to supercooling of water in the course of phase change from solid to liquid. This study investigates the cooling characteristics of the TMA-water clathrate compound including TMA (Tri-methyl-amine, $(CH_3)_3N$) of $20{\sim}25wt%$ as a low temperature latent heat storage material. The results showed that the phase change temperature and the specific heat is increased and the supercooling degree is decreased as the weight concentration of TMA increased. Especially, the clathrate compound containing TMA 25 wt% has the average phase change tempera ture of $5.8^{\circ}C$, the supercooling degree of $8.0^{\circ}C$ and the specific heat of 3.499 kJ/kgK in the cooling process. This can lead to reduction of operation time of refrigerator in low temperature latent heat storage system and efficiency improvement of refrigerator COP and overall system. Therefore, energy saving and improvement of utilization efficiency are expected.

Maximum Power Output Cycle of Heat Engines (열기관의 최대출력 사이클)

  • 김수연;정평석;노승탁;김효경
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.3
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    • pp.694-701
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    • 1990
  • The cycle of heat engine which produces the maximum power output is constructed when heat sources are finitely constant, and the maximum power as a thermodynamic limit of the engine, is obtained. The characteristics of the maximum power cycle are as follows, which represent the operation conditions and design conditions of the heat engine to produce the maximum power output. In heat exchangers, the temperature profiles of the heat source and the working fluid have the same functional formula and the ratio of the working fluid temperature to the heat source temperature is constant. When heat capacity flow rates(product of the specific heat and the mass flow rate) of the working fluid as well as the heat source are constant, the values of those of working fluid exist between those of two heat sources. The relation of the temperature and the heat capacity flow rate is established without the states of the heat sources and the capacities of heat exchangers, which is ( $T_{h}$/ $T_{H}$)( $C_{h}$/ $C_{H}$)=( $T_{1}$/ $T_{L}$)( $c_{1}$/ $c_{L}$)=1. The capacity of the heat exchanger of hot side is equal to that of cold side regardless of the states of the heat sources and the total capacities of heat exchangers.hangers.ers.

Electrochemical Characteristics of Setaria viridis-Based Carbon Anode Materials Prepared by Thermal Treatment for Lithium-Ion Secondary Batteries (열처리에 의해 제조된 강아지풀 기반 리튬 이온 이차전지용 탄소 음극재의 전기화학적 특성)

  • Dong Ki Kim;Chaehun Lim;Seongjae Myeong;Naeun Ha;Chung Gi Min;Young-Seak Lee
    • Applied Chemistry for Engineering
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    • v.35 no.2
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    • pp.140-147
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    • 2024
  • In order to increase the utilization of biomass, an electrochemical performance was considered after manufacturing a carbon anode material (SV-C) for a Setaria viridis-based lithium ion secondary battery through a heat treatment process. When the heat treatment temperature of the Setaria viridis is as low as 750 ℃, the capacitance (1003.3 mAh/g, at 0.1 C) is high due to the negative (-) charge of oxygen present on the surface attracting lithium, along with the low crystallinity and high specific surface area (126 m2/g), but the capacity retention rate is believed to be as low as 61.0% (at 500 cycles and 1 C). In addition, it was confirmed that when the heat treatment temperature increased to 1150 ℃, the carbon layer was condensed to be excellent in arrangement, and the structural defects were reduced, resulting in a significant reduction in the specific surface area (32 m2/g) of the pores. Furthermore, when the surface defects of the anode material are reduced and the crystallinity is increased, the capacity retention rate is as high as 89.7% (at 500 cycles and 1 C), but the degree of defects is small, the active point is reduced, and the specific capacity is considered to be very low at 471.7 mAh/g. In the scope of this study, it was found that in the case of the Setaria viridis-based carbon anode material manufactured according to the heat treatment temperature, the surface oxygen content and crystallinity have higher reliability on the electrochemical properties of the anode material than the specific surface area.

Thermodynamic Properties of the Modified Yukawa Potential

  • Okorie, U.S.;Ibekwe, E.E.;Ikot, A.N.;Onyeaju, M.C.;Chukwuocha, E.O.
    • Journal of the Korean Physical Society
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    • v.73 no.9
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    • pp.1211-1218
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    • 2018
  • Within the framework of the modified factorization method, we solve the $Schr{\ddot{o}}dinger$ equation with the modified Yukawa potential. The energy spectrum is obtained using the Pekeris approximation scheme for the centrifugal term. The thermodynamic properties, including the vibrational partition function, vibrational mean energy, vibrational mean free energy, vibrational specific heat capacity and vibrational entropy, are calculated. As a special case, we compare our result with that work of Dong [Int. J. Quant. Chem. 107, 366 (2007)] and find good agreement.

Performance Analysis of a Multi-type Inverter Heat Pump (멀티형 인버터 열펌프의 냉방성능해석에 관한 연구)

  • Kim, Y. C.;Park, G. W.;Youn, Y.;Min, M. K.;Choi, Y, D,
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.3
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    • pp.153-159
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    • 2001
  • A system simulation program was developed for a multi-type inverter heat pump. Electronic expansion valve(EEV) was used to extend the capacity modulating range of the heat pump as expansion device. The program was also developed to calculate actual system performance with the building load variation with climate during a year. The performance variation of a multi-type hat pump with two EEV and an inverter compressor was simulated with compressor speed, capacity, and flow area of the EEV. As a result, the optimum operating frequency of the compressor and openings of the expansion device were decided at a given load. As compressor speed increased, he capacity of heat pump increased, the capacity of heat pump increased. Therefore flow area of EEV should be adjusted to have wide openness. Thus the coefficient of performance(COP) of the heat pump decreased due to increasement of compressor power input. The maximum COP point at a given load was decided according to the compressor speed. And under the given specific compressor speed and the load, the optimum openings point of EEV was also decided. Although the total load of indoor units was constant, the operating frequency increased as the fraction of load in a room increased. Finally ad the compressor power input increased, the coefficient of performance decreased.

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A techno-economic analysis of partial repowering of a 210 MW coal fired power plant

  • Samanta, Samiran;Ghosh, Sudip
    • Advances in Energy Research
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    • v.3 no.3
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    • pp.167-179
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    • 2015
  • This paper presents a techno-economic analysis of a partial repowering scheme for an existing 210 MW coal fired power plant by integrating a gas turbine and by employing waste heat recovery. In this repowering scheme, one of the four operating coal mills is taken out and a new natural gas fired gas turbine (GT) block is considered to be integrated, whose exhaust is fed to the furnace of the existing boiler. Feedwater heating is proposed through the utilization of waste heat of the boiler exhaust gas. From the thermodynamic analysis it is seen that the proposed repowering scheme helps to increase the plant capacity by about 28% and the overall efficiency by 27%. It also results in 21% reduction in the plant heat rate and 29% reduction in the specific $CO_2$ emissions. The economic analysis reveals that the partial repowering scheme is cost effective resulting in a reduction of the unit cost of electricity (UCOE) by 8.4%. The economic analysis further shows that the UCOE of the repowered plant is lower than that of a new green-field power plant of similar capacity.

Experiment and Electro-Thermo-Chemical Modeling on Rapid Resistive Discharge of Large-Capacity Lithium Ion Battery

  • Doh, Chil-Hoon;Ha, Yoon-Cheol;Eom, Seung-Wook;Yu, Jihyun;Choe, Seon-Hwa;Kim, Seog-Whan;Choi, Jae-Won
    • Journal of Electrochemical Science and Technology
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    • v.13 no.3
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    • pp.323-338
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    • 2022
  • Heat generation and temperature of a battery is usually presented by an equation of current. This means that we need to adopt time domain calculation to obtain thermal characteristics of the battery. To avoid the complicated calculations using time domain, 'state of charge (SOC)' can be used as an independent variable. A SOC based calculation method is elucidated through the comparison between the calculated results and experimental results together. Experiments are carried for rapid resistive discharge of a large-capacitive lithium secondary battery to evaluate variations of cell potential, current and temperature. Calculations are performed based on open-circuit cell potential (SOC,T), internal resistance (SOC,T) and entropy (SOC) with specific heat capacity.

Relationship between Tensile Strength and Damping Capacity of Annealed Magnesium Alloys after Hot Rolling (열간 압연 후 어닐링처리한 Mg 합금의 인장강도와 감쇠능과의 관계)

  • Lee, Gyu-Hyun;Oh, Eun-Ji;Kim, Kwon-Hoo;Kim, Jae-Nam;Kang, Chang-Yong
    • Journal of the Korean Society for Heat Treatment
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    • v.27 no.6
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    • pp.295-301
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    • 2014
  • In this study, the relationship between strength and damping capacity of annealed magnesium alloys after hot rolling was investigated. The microstructure of hot rolled magnesium consisted of dendrite structure and $Mg_{17}Al_{12}$ compounds precipitated along the grain boundary. The dendrite structure was dissipated, $Mg_{17}Al_{12}$ compounds was decomposed by annealing, and then its dissolved in ${\alpha}$-Mg. With an increasing the annealing temperature and time, strength was slowly decreased and damping capacity was slowly increased by the growth of grain size and decreasing of defects induced by hot rolling. In annealing treatmented magnesium alloys after hot rolling, damping capacity was decreased rapidly with an increase of strength. There was on proportional relationship between tensile strength, and damping capacity.

Characteristics of Friction Materials for Brake Disc in F-16 B32 Fighter (F-16 B32 전투기용 브레이크 디스크 소재의 물성특성 연구)

  • Kam, Moon-Gap;Kim, Won-Il;Kim, Tae-Gyu
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.6 no.3
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    • pp.98-104
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    • 2007
  • The carbon fiber reinforced carbon composite (CFRC) materials are necessary for the advanced industries that require the thermal resistance. And the development and research for CFRC has been in progress in the field of aerospace and defense industry. CFRC have several advantages and special properties such as excellent anti ablation, outstanding strength retention at very high temperature, high heat capacity and thermal transport, high specific stiffness and strength, and high thermal shock resistance. They have been used as aircraft brake, rocket nozzle, nose cones, jet engine turbine wheels, and high speed craft. Since the technology related to CFRC was prohibited from importing and exporting, we developed our own technology to produce F-16 B32 brake disk made out of CFRC, and then we performed various tests to observe the characteristics of CFRC-based brake disk developed in this study in view of density, strength, friction, specific heat, and heat conductivity.

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Heat Storage in a packed Bed (충전층내에서 축열에 따른 열전달)

  • Choi, Kyung-Jin;Ro, Sung-Tack
    • The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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    • v.7 no.1
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    • pp.13-19
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    • 1978
  • An experiment has been performed of find a temperature distribution of the circulating fluid in a packed bed thermal storage system when the inlet fluid temperature is constant. The thermal storage system is a specific-heat type in which the circulating fluid, hot air, exchanges heat directly with the heat storage materials, glass balls, in a heat storage bin. An empirical equation which includes two dimensionless variables $t^*\;and\;T_f^*$, is obtained. Also, heat storage efficiency and heat storage capacity are calculated from this equation, The heat transfer coefficient calculated by the suggested equation was compared with the value determined by the existing empirical equation.

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