• Journal of the Korean Society of Safety
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• v.16 no.4
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• pp.160-167
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• 2001

Cracking in connote structures is one of the main issues of structural design next to ensuring the load-bearing capacity. Thermal analysis is used to prevent thermal mucking, but concrete properties are uncertain variable, and analysis results have uncertainty, too. In this study, sensitivity analysis is performed to investigate the effect of conductivity, specific heal and pouring temperature. The results show that lower conductivity and higher specific heat increase the maximum temperature and maximum tensile stress. The structure with internal restraint is mostly influenced by the change of conductivity and specific heat.

• Bulletin of the Korean Chemical Society
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• v.31 no.7
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• pp.1988-1992
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• 2010

4-Amino-1,2,4-triazole copper complex (4-ATzCu) was synthesized, and its thermal behaviors, nonisothermal decomposition reaction kinetics were studied by DSC and TG-DTG techniques. The thermal decomposition reaction kinetic equation was obtained as: $d\alpha$ / dt =$10^{22.01}$ (1-$\alpha$)[-ln(1-$\alpha$)]$^{1/3}$ exp($-2.75\times10^4$ /T). The standard mole specific heat capacity of the complex was determined and the standard molar heat capacity is 305.66 $J{\cdot}mol^{-1}{\cdot}K^{-1}$ at 298.15 K. The entropy of activation $({\Delta}S^{\neq})$, enthalpy of activation $({\Delta}H^{\neq})$, and Gibbs free energy of activation $({\Delta}G^{\neq})$ are calculated as 171.88 $J{\cdot}mol^{-1}{\cdot}K^{-1}$ 225.81 $kJ{\cdot}mol^{-1}$ and 141.18 $kJ{\cdot}mol^{-1}$, and the adiabatic time-to-explosion of the complex was obtained as 389.20 s.

• Journal of the Korean Society for Heat Treatment
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• v.10 no.1
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• pp.47-54
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• 1997

Flake graphite cast irons with the high damping capacity have been used for the control of vibration and noise occuring in the members of various mechanical structures under vibrating conditions. However, the damping capacity which is morphological characteristics of graphite is one of the important factors in reducing the vibration and noise, but hardly any work has deal with this problem. Therefore, the authors have examined the damping capacity of various cast irons with alloying elements and studied the influences of the matrix, mechanical properties and morphological characteristics of graphite. The main results obtained are as follows: Effects of Ni on the damping capacities and mechanical properties are investigated in 3.9%C-0.3% Cu gray cast iron. At 0.2% Ni content, specific damping capacity showed the maximum value, and decreased with further increase in Ni content, Graphite continuity also showed same behavior. This indicates that the specific damping capacity has a close relation with graphite continuity. On the other hand, the damping capacity in pearlite matrix showed superior to that in ferrite. In contrast, with increasing the Ni content, both tensile strength and hardness increased due to the decrease of graphite length and eutectic cell size.

• Journal of the Korean Solar Energy Society
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• v.24 no.1
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• pp.7-12
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• 2004

Mixtures type PCM, $H_2O$-NaOH that has relatively large capacity of the latent heat and long duration of phase change temperature was developed and experimentally analyzed for the low temperature storage of the food and medical products. The results could be summarized as follows; 1. Borax as nucleating agent and acrylic polymer as thickening agent were added to $H_2O$ to prevent the supercooling and phase separation. 2. Phase change (solid$\leftrightarrows$liquid) duration of $H_2O$ added with NaOH was prolonged longer 50% than that of pure $H_2O$. 3. Phase change temperature of the latent heat material, $H_2O$-NaOH was $1.5\sim2^{\circ}C$ the maximum latent Heat was 279 kJ/kg at the NaOH addition of 1.3 wt.%. 4. The specific heat of $H_2O$-NaOH at the solid and liquid state was increased in proportion to the wt.% of NaOH, when NaOH of $1.15\sim1.60$ wt.% was added to $H_2O$, the specific heat of the solid state was increased from 3.19 kJ/kg to 5.84 kJ/kg and that of liquid state from 7.8 kJ/kg to 10.28 kJ/kg. 5. When NaOH of $1.15\sim1.60$ wt.% was added to $H_2O$, the total heat storage capacity composed of sensible and latent heat was $313\sim331.3$ kJ/kg and the maximum heat storage capacity was occurred at NaOH addition of 1.30 wt. %.

• Bulletin of the Korean Chemical Society
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• v.30 no.10
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• pp.2259-2264
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• 2009

A new high-energy organic potassium salt, 2-(dinitromethylene)-1,3-diazepentane potassium salt K(DNDZ), was synthesized by reacting of 2-(dinitromethylene)-1,3-diazepentane (DNDZ) and potassium hydroxide. The thermal behavior and non-isothermal decomposition kinetics of K(DNDZ) were studied with DSC, TG/DTG methods. The kinetic equation is $\frac{d{\alpha}}{dT}$ = $\frac{10^{13.92}}{\beta}$3(1 - $\alpha$[-ln(1 - $\alpha$)]$^{\frac{2}{3}}$ exp(-1.52 ${\times}\;10^5$ / RT). The critical temperature of thermal explosion of K(DNDZ) is $208.63\;{^{\circ}C}$. The specific heat capacity of K(DNDZ) was determined with a micro-DSC method, and the molar heat capacity is 224.63 J $mol^{-1}\;K^{-1}$ at 298.15 K. Adiabatic time-to-explosion of K(DNDZ) obtained is 157.96 s.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.1
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• pp.717-724
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• 2020

In general, the factors affecting the heat transfer of asphalt pavement are divided into weather factors and pavement materials. Among them, material factors include the thermophysical and surface properties. An experiment was conducted on the thermal-physical factors of asphalt, which are the basis for the pavement failure model. The thermal conductivity, specific heat capacity, thermal diffusivity, and thermal emissivity were evaluated as the thermo-physical properties of asphalt. The specimens (WC-2 & PA-13) used in the experiment were compacted with a Gyratory Compactor. The experimental results of WC-2 and PA-13 showed a thermal conductivity of 1.18W/m·K and 0.9W/m·K, specific heat capacity of 970.8J/kg·K and 960.1J/kg·K, thermal emissivity of 0.9 and 0.91, and thermal diffusivity of 5.15㎡/s and 4.66㎡/s, respectively. Experiments on the heat transfer characteristics (thermo-physical properties) of asphalt pavement that can be used for thermal failure modeling of asphalt were conducted.

• 한국태양에너지학회:학술대회논문집
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• 2009.04a
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• pp.296-301
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• 2009

The ice storage system uses water for low temperature latent heat storage. However, a refrigerator capacity is increased and COP is decreased due to supercooling of water in the course of phase change from solid to liquid. This study investigates the cooling characteristics of the TMA-water clathrate compound including TMA (Tri-methyl-amine, $(CH_3)_3N)$ of $20{\sim}25wt%$ as a low temperature latent heat storage material. The results showed that the phase change temperature and the specific heat is increased and the supercooling degree is decreased as the weight concentration of TMA increased. Especially, the clathrate compound containing TMA 25wt% has the average phase change temperature of $5.8^{\circ}C$, the supercooling degree of $8.0^{\circ}C$ and the specific heat of 3.499 kJ/kgK in the cooling process. This can lead to reduction of operation time of refrigerator in low temperature latent heat storage system and efficiency improvement of refrigerator COP and overall system. Therefore, energy saving and improvement of utilization efficiency are expected.

• Journal of Power System Engineering
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• v.18 no.4
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• pp.66-71
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• 2014

In this study, effect of heat treatment on the microstructure and damping capacity of hot rolled magnesium alloys was investigated. The microstructure of hot rolled magnesium consisted of dendrite structure and $Mg_{17}Al_{12}$ compounds precipitated along the grain boundry. The dendrite structure was dissipated and $Mg_{17}Al_{12}$ compounds was decomposed by annealing treatment, and then they dissolved in ${\alpha}-Mg$. With an increasing the annealing temperature and time, damping capacity was slowly increased by the growth of grain size and decreasing of defects induced by hot rolling. Two kinds of magnesium alloys AZ 31 and AZ 61 after annealing showed no difference in damping capacity.

• The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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• v.15 no.4
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• pp.356-361
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• 1986

An optimum design condition for a basic refrigeration cycle is defined as the condition which minimizes the total cost of heat exchanges (condenser and evaporator) and compressor for the refrigeration effect. Thermodynamic properties of ammonia (R717) are approximated by rational functions in order to obtain the optimum condition for a basic refrigeration cycle. Optimum condition depends on the heat capacity rates (mass flow rate times specific heat) of cooling water and brine used in condenser and evaporator. The difference between the cooling water temperature and condensation temperature at the optimum condition increases as the heat capacity rates and the coat of heat exchangers relative to the cost of compressor increase. Numerical examples of optimum conditions are obtained when the condensation temperature is $30^{\circ}C$ and the evaporator temperature is $-10^{\circ}C$.

• Applied Chemistry for Engineering
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• v.8 no.4
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• pp.631-636
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• 1997

This study was conducted to increase the adorption capacity of microporous carbon which is widely used as an adsorbent. After increasing the adsorption capacity of microporous carbon by heat-treatment, chromium($Cr^{+6}$) solution, which is the one of hazardous heavy metals, was selectively adsorbed on microporous carbon. Optimum temperature range for the heat-treatment of microporous carbon was $340{\sim}350^{\circ}C$, and the average specific surface area was measured as $1380m^2/g$ by BET (Brunauer-Emmett-Teller) method. The weight loss was about 10 percents during the heating to optimum temperature. However, It became a qualitative adsorbent due to a larger specific surface area. Removal of chromium($Cr^{+6}$) in solution by heat-treated microporous carbon was successfully carried out.