• 한국안전학회지
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• 제16권4호
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• pp.160-167
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• 2001

Cracking in connote structures is one of the main issues of structural design next to ensuring the load-bearing capacity. Thermal analysis is used to prevent thermal mucking, but concrete properties are uncertain variable, and analysis results have uncertainty, too. In this study, sensitivity analysis is performed to investigate the effect of conductivity, specific heal and pouring temperature. The results show that lower conductivity and higher specific heat increase the maximum temperature and maximum tensile stress. The structure with internal restraint is mostly influenced by the change of conductivity and specific heat.

• Bulletin of the Korean Chemical Society
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• 제31권7호
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• pp.1988-1992
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• 2010

4-Amino-1,2,4-triazole copper complex (4-ATzCu) was synthesized, and its thermal behaviors, nonisothermal decomposition reaction kinetics were studied by DSC and TG-DTG techniques. The thermal decomposition reaction kinetic equation was obtained as: $d\alpha$ / dt =$10^{22.01}$ (1-$\alpha$)[-ln(1-$\alpha$)]$^{1/3}$ exp($-2.75\times10^4$ /T). The standard mole specific heat capacity of the complex was determined and the standard molar heat capacity is 305.66 $J{\cdot}mol^{-1}{\cdot}K^{-1}$ at 298.15 K. The entropy of activation $({\Delta}S^{\neq})$, enthalpy of activation $({\Delta}H^{\neq})$, and Gibbs free energy of activation $({\Delta}G^{\neq})$ are calculated as 171.88 $J{\cdot}mol^{-1}{\cdot}K^{-1}$ 225.81 $kJ{\cdot}mol^{-1}$ and 141.18 $kJ{\cdot}mol^{-1}$, and the adiabatic time-to-explosion of the complex was obtained as 389.20 s.

• 열처리공학회지
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• 제10권1호
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• pp.47-54
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• 1997

Flake graphite cast irons with the high damping capacity have been used for the control of vibration and noise occuring in the members of various mechanical structures under vibrating conditions. However, the damping capacity which is morphological characteristics of graphite is one of the important factors in reducing the vibration and noise, but hardly any work has deal with this problem. Therefore, the authors have examined the damping capacity of various cast irons with alloying elements and studied the influences of the matrix, mechanical properties and morphological characteristics of graphite. The main results obtained are as follows: Effects of Ni on the damping capacities and mechanical properties are investigated in 3.9%C-0.3% Cu gray cast iron. At 0.2% Ni content, specific damping capacity showed the maximum value, and decreased with further increase in Ni content, Graphite continuity also showed same behavior. This indicates that the specific damping capacity has a close relation with graphite continuity. On the other hand, the damping capacity in pearlite matrix showed superior to that in ferrite. In contrast, with increasing the Ni content, both tensile strength and hardness increased due to the decrease of graphite length and eutectic cell size.

• 한국태양에너지학회 논문집
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• 제24권1호
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• pp.7-12
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• 2004

Mixtures type PCM, $H_2O$-NaOH that has relatively large capacity of the latent heat and long duration of phase change temperature was developed and experimentally analyzed for the low temperature storage of the food and medical products. The results could be summarized as follows; 1. Borax as nucleating agent and acrylic polymer as thickening agent were added to $H_2O$ to prevent the supercooling and phase separation. 2. Phase change (solid$\leftrightarrows$liquid) duration of $H_2O$ added with NaOH was prolonged longer 50% than that of pure $H_2O$. 3. Phase change temperature of the latent heat material, $H_2O$-NaOH was $1.5\sim2^{\circ}C$ the maximum latent Heat was 279 kJ/kg at the NaOH addition of 1.3 wt.%. 4. The specific heat of $H_2O$-NaOH at the solid and liquid state was increased in proportion to the wt.% of NaOH, when NaOH of $1.15\sim1.60$ wt.% was added to $H_2O$, the specific heat of the solid state was increased from 3.19 kJ/kg to 5.84 kJ/kg and that of liquid state from 7.8 kJ/kg to 10.28 kJ/kg. 5. When NaOH of $1.15\sim1.60$ wt.% was added to $H_2O$, the total heat storage capacity composed of sensible and latent heat was $313\sim331.3$ kJ/kg and the maximum heat storage capacity was occurred at NaOH addition of 1.30 wt. %.

• Bulletin of the Korean Chemical Society
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• 제30권10호
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• pp.2259-2264
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• 2009

A new high-energy organic potassium salt, 2-(dinitromethylene)-1,3-diazepentane potassium salt K(DNDZ), was synthesized by reacting of 2-(dinitromethylene)-1,3-diazepentane (DNDZ) and potassium hydroxide. The thermal behavior and non-isothermal decomposition kinetics of K(DNDZ) were studied with DSC, TG/DTG methods. The kinetic equation is $\frac{d{\alpha}}{dT}$ = $\frac{10^{13.92}}{\beta}$3(1 - $\alpha$[-ln(1 - $\alpha$)]$^{\frac{2}{3}}$ exp(-1.52 ${\times}\;10^5$ / RT). The critical temperature of thermal explosion of K(DNDZ) is $208.63\;{^{\circ}C}$. The specific heat capacity of K(DNDZ) was determined with a micro-DSC method, and the molar heat capacity is 224.63 J $mol^{-1}\;K^{-1}$ at 298.15 K. Adiabatic time-to-explosion of K(DNDZ) obtained is 157.96 s.

• 한국산학기술학회논문지
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• 제21권1호
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• pp.717-724
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• 2020

일반적으로 아스팔트 포장체의 열전달에 영향을 미치는 인자는 크게 날씨와 포장체의 재료로 나뉘며, 그 중 포장체의 재료 요인으로는 열-물리적 인자(Thermophysical properties)과 포장체 표면의 인자(Surface property)으로 나뉜다. 본 연구에서는 포장체 전반적인 파손 모형에 기본이 되는 아스팔트의 열-물리적 인자에 대한 실험을 진행하였으며, 평가한 아스팔트의 열전달 특성 인자로는 열전도도(Thermal Conductivity), 비열용량(Specific Heat Capacity), 열확산특성(Thermal Diffusivity), 열방사률(Thermal Emissivity)를 평가하였다. 샘플로 사용한 표층용 혼합물 입도는 밀입도 포장 WC-2와 배수성 포장 PA-13으로 선회다짐기를 이용하여 제작하였다. WC-2와 PA-13의 실험결과로 열전도도는 1.18W/m·K과 0.9W/m·K로 나타났고, 비열용량은 970.8J/kg·K과 960.1J/kg·K으로 공극률이 더 낮은 혼합물인 WC-2가 혼합된 재료의 량이 많아 비열용량이 더 높은 나타나는 것을 알 수 있었다. 또한 열방사률은 0.9와 0.91, 열확산률은 5.15㎡/s와 4.66㎡/s으로 WC-2가 PA-13 대비 약 10% 더 빠른 열 확산을 보이는 것을 알 수 있다. 이러한 결과는 향후 아스팔트 포장의 열에너지 활용 및 열에너지에 의한 아스팔트 포장의 파손평가 및 모형개발 등에 연구 및 활용에 가장 근간이 되는 자료가 될 것이라 판단되다.

• 한국태양에너지학회:학술대회논문집
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• 한국태양에너지학회 2009년도 춘계학술발표대회 논문집
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• pp.296-301
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• 2009

The ice storage system uses water for low temperature latent heat storage. However, a refrigerator capacity is increased and COP is decreased due to supercooling of water in the course of phase change from solid to liquid. This study investigates the cooling characteristics of the TMA-water clathrate compound including TMA (Tri-methyl-amine, $(CH_3)_3N)$ of $20{\sim}25wt%$ as a low temperature latent heat storage material. The results showed that the phase change temperature and the specific heat is increased and the supercooling degree is decreased as the weight concentration of TMA increased. Especially, the clathrate compound containing TMA 25wt% has the average phase change temperature of $5.8^{\circ}C$, the supercooling degree of $8.0^{\circ}C$ and the specific heat of 3.499 kJ/kgK in the cooling process. This can lead to reduction of operation time of refrigerator in low temperature latent heat storage system and efficiency improvement of refrigerator COP and overall system. Therefore, energy saving and improvement of utilization efficiency are expected.

• 동력기계공학회지
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• 제18권4호
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• pp.66-71
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• 2014

In this study, effect of heat treatment on the microstructure and damping capacity of hot rolled magnesium alloys was investigated. The microstructure of hot rolled magnesium consisted of dendrite structure and $Mg_{17}Al_{12}$ compounds precipitated along the grain boundry. The dendrite structure was dissipated and $Mg_{17}Al_{12}$ compounds was decomposed by annealing treatment, and then they dissolved in ${\alpha}-Mg$. With an increasing the annealing temperature and time, damping capacity was slowly increased by the growth of grain size and decreasing of defects induced by hot rolling. Two kinds of magnesium alloys AZ 31 and AZ 61 after annealing showed no difference in damping capacity.

• 대한설비공학회지:설비저널
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• 제15권4호
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• pp.356-361
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• 1986

An optimum design condition for a basic refrigeration cycle is defined as the condition which minimizes the total cost of heat exchanges (condenser and evaporator) and compressor for the refrigeration effect. Thermodynamic properties of ammonia (R717) are approximated by rational functions in order to obtain the optimum condition for a basic refrigeration cycle. Optimum condition depends on the heat capacity rates (mass flow rate times specific heat) of cooling water and brine used in condenser and evaporator. The difference between the cooling water temperature and condensation temperature at the optimum condition increases as the heat capacity rates and the coat of heat exchangers relative to the cost of compressor increase. Numerical examples of optimum conditions are obtained when the condensation temperature is $30^{\circ}C$ and the evaporator temperature is $-10^{\circ}C$.

• 공업화학
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• 제8권4호
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• pp.631-636
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• 1997

흡착제로 널리 쓰이는 다공성탄소의 흡착성능을 증가시키는 연구를 수행하였다. 열처리에 의하여 다공성탄소의 흡착성능을 증가시킨 후, 유해중금속의 일종인 $Cr^{+6}$의 선택적 흡착을 시행하였다. 다공성탄소의 적정 열처리 온도는 $340{\sim}350^{\circ}C$가 가장 적절하였으며, 이때의 평균 비표면적은 Brunauer-Emmett-Teller(BET) 방법에 의해 $1380m^2/g$로 측정되었다. 열처리 과정에서 전체중량의 약 10%의 감소가 있었으나, 비표면적의 증가로 고품질의 흡착제가 되었다. 또한 열처리된 다공성탄소에 의하여 액상에서의 $Cr^{+6}$의 제거가 성공적으로 수행되었다.