• Title/Summary/Keyword: Specific electric resistance

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Electrochemical Characteristics of the Activated Carbon Electrode Modified with the Microwave Radiation in the Electric Double Layer Capacitor (전기이중층캐패시터에서 마이크로파에 의해 개질된 활성탄소전극의 전기화학적 특성)

  • Sun, Jin-Kyu;Um, Eui-Heum;Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.21 no.1
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    • pp.11-17
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    • 2010
  • Modifying surface of activated carbon for the electrode of EDLC with an organic electrolyte was investigated to improve the electrochemical performance of EDLC by the microwave radiation. Three kinds of activated carbons, prepared activated carbon from petroleum cokes and pitch cokes and commercial activated carbon BP-25, were used for this study. For all investigated activated carbons, hydrophilic functional groups-containing oxygen disappeared from the surface of activated carbon as microwave radiation. And as microwave radiation time was increased, the specific surface area and total pore volume of activated carbons were reduced and average pore diameter were increased. From theses effects, interfacial resistance of EDLC with the modified activated carbon electrode was drastically decreased, and discharge capacitance was increased although the specific surface area of activated carbon was reduced by this microwave radiation.

A Study on Sensing Characteristics of Carbon Nanotube Smart Composite Nano Sensors Based on Electrical Impedance Measurement (탄소나노튜브 스마트 복합소재의 전기적 임피던스 변화를 이용한 나노센서의 센싱 특성 연구)

  • Kang, I.P.
    • Journal of Power System Engineering
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    • v.13 no.1
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    • pp.65-71
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    • 2009
  • To address the need for new intelligent sensing, this paper introduces nano sensors made of carbon nanotube (CNT) composites and presents their preliminary experiments. Having smart material properties such as piezoresistivity, chemical and bio selectivity, the nano composite can be used as smart electrodes of the nano sensors. The nano composite sensor can detect structural deterioration, chemical contamination and bio signal by means of its impedance measurement (resistance and capacitance). For a structural application, the change of impedance shows specific patterns depending on the structural deterioration and this characteristic is available for an in-situ multi-functional sensor, which can simultaneously detect multi symptoms of the structure. This study is anticipated to develop a new nano sensor detecting multiple symptoms in structural, chemical and bio applications with simple electric circuits.

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Grafting of Casein onto Polyacrylonitrile Fiber for Surface Modification

  • Jia Zhao;Du Shanyi
    • Fibers and Polymers
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    • v.7 no.3
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    • pp.235-240
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    • 2006
  • Polyacrylonitrile (PAN) fiber was grafted with casein after alkaline hydrolysis and chlorination reactions of the original fiber. The structures and morphologies of the casein grafted fiber were characterized by Fourier transform infrared spectroscopy (FTIR), X-Ray diffraction (XRD), and scanning electron microscope (SEM). Moisture absorption, specific electric resistance, water retention value, and mechanical properties were also investigated. The results showed that casein was grafted onto the surface of the PAN fiber and the grafted PAN fiber presented better hygroscopicity compared with the untreated fiber. With proper tensile strength, the modified fiber could still meet the requirement for wearing. A mechanism was proposed to explain the deposit of casein on the synthetic acrylic fiber.

The Electrochemical Characteristics of Mesopore Active Carbon Fiber for EDLC Electrode (EDLC 전극용 메조기공 활성탄소 섬유의 전기화학적 특성)

  • Kang, Chae-Yoen;Shin, Yun-Sung;Lee, Jong-Dae
    • Korean Chemical Engineering Research
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    • v.49 no.1
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    • pp.10-14
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    • 2011
  • The electrode material performances of electric double layer capacitor(EDLC) were investigated using mesopous active carbon fiber(ACF), which was prepared by the iron exchange method. The mesoporous ACF had pore characteristics of specific surface area around 1249, 664 $m^2$/g, mesoporous fraction around 70.6-81.3% and meanpore size around 2.78-4.14 nm. The results showed that as HNO3 treatment time decreased, the specific surface area increased and mesoporous fraction decreased. To investigate electrochemical performance of EDLC, unit cell was manufactured using mesoporus ACF, conducting material and binder; organic elctrolyte was used on this experiment. The specific capacitance of ACF treated with HNO3 for 2 hours turned out to be 0.47 $F/cm^2$and the results of the cyclic charge-discharge tests were stable. Thus, the electrochemical performance of EDLC was mainly dependent on specific surface area of ACF electrode and the diffusion resistance of charge decreased as the mesopore increased.

Optimization of 1.2 kV 4H-SiC MOSFETs with Vertical Variation Doping Structure (Vertical Variation Doping 구조를 도입한 1.2 kV 4H-SiC MOSFET 최적화)

  • Ye-Jin Kim;Seung-Hyun Park;Tae-Hee Lee;Ji-Soo Choi;Se-Rim Park;Geon-Hee Lee;Jong-Min Oh;Weon Ho Shin;Sang-Mo Koo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.37 no.3
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    • pp.332-336
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    • 2024
  • High-energy bandgap material silicon carbide (SiC) is gaining attention as a next-generation power semiconductor material, and in particular, SiC-based MOSFETs are developed as representative power semiconductors to increase the breakdown voltage (BV) of conventional planar structures. However, as the size of SJ (Super Junction) MOSFET devices decreases and the depth of pillars increases, it becomes challenging to uniformly form the doping concentration of pillars. Therefore, a structure with different doping concentrations segmented within the pillar is being researched. Using Silvaco TCAD simulation, a SJ VVD (vertical variation doping profile) MOSFET with three different doping concentrations in the pillar was studied. Simulations were conducted for the width of the pillar and the doping concentration of N-epi, revealing that as the width of the pillar increases, the depletion region widens, leading to an increase in on-specific resistance (Ron,sp) and breakdown voltage (BV). Additionally, as the doping concentration of N-epi increases, the number of carriers increases, and the depletion region narrows, resulting in a decrease in Ron,sp and BV. The optimized SJ VVD MOSFET exhibits a very high figure of merit (BFOM) of 13,400 KW/cm2, indicating excellent performance characteristics and suggesting its potential as a next-generation highperformance power device suitable for practical applications.

Development of Thermoplastic Carbon Composite Bipolar Plates for High-temperature PEM Fuel Cells (고온 양성자 교환막 연료전지용 열가소성 탄소 복합재료 분리판 개발)

  • Lim, Jun Woo;Kim, Minkook;Lee, Dai Gil
    • Composites Research
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    • v.29 no.5
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    • pp.243-248
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    • 2016
  • Although thermoset carbon fiber composite bipolar plates not only have high mechanical properties but also high corrosion resistance in acid environment, high manufacturing cost and low bulk electrical conductivity are the biggest obstacle to overcome. In this research, thermoplastic polymer is employed for the matrix of carbon composite bipolar plate to increase both the manufacturing productivity and bulk electric conductivity of the bipolar plate. In order to increase the electrical conductivity and strength, plain type carbon fabric rather than chopped or unidirectional fibers is used. Also nano particles are embedded in the thermoplastic matrix to increase the bulk resistance of the bipolar plate. The area specific resistance and the mechanical strength of the developed bipolar plate are measured with respect to the environmental temperature and stack compaction pressure.

Fabrication and Characterization of Silver Copper(I) Oxide Nanoparticles for a Conductive Paste (은이 코팅된 Copper(I) Oxide 나노 입자 및 도전성 페이스트의 제조 특성)

  • Park, Seung Woo;Son, Jae Hong;Sim, Sang Bo;Choi, Yeon Bin;Bae, Dong Sik
    • Korean Journal of Materials Research
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    • v.29 no.1
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    • pp.37-42
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    • 2019
  • This study investigates Ag coated $Cu_2O$ nanoparticles that are produced with a changing molar ratio of Ag and $Cu_2O$. The results of XRD analysis reveal that each nanoparticle has a diffraction pattern peculiar to Ag and $Cu_2O$ determination, and SEM image analysis confirms that Ag is partially coated on the surface of $Cu_2O$ nanoparticles. The conductive paste with Ag coated $Cu_2O$ nanoparticles approaches the specific resistance of $6.4{\Omega}{\cdot}cm$ for silver paste(SP) as $(Ag)/(Cu_2O)$ the molar ratio increases. The paste(containing 70 % content and average a 100 nm particle size for the silver nanoparticles) for commercial use for mounting with a fine line width of $100{\mu}m$ or less has a surface resistance of 5 to $20{\mu}{\Omega}{\cdot}cm$, while in this research an Ag coated $Cu_2O$ paste has a larger surface resistance, which is disadvantageous. Its performance deteriorates as a material required for application of a fine line width electrode for a touch panel. A touch panel module that utilizes a nano imprinting technique of $10{\mu}m$ or less is expected to be used as an electrode material for electric and electronic parts where large precision(mounting with fine line width) is not required.

Experimental studies and numerical analysis of the shear behavior of fin plates to tubular columns at ambient and elevated temperatures

  • Jones, M.H.;Wang, Y.C.
    • Steel and Composite Structures
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    • v.8 no.3
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    • pp.179-200
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    • 2008
  • This paper reports the results of a recent experimental study into the behavior of welded fin-plate connections to both hollow and concrete filled tubular (CFT) columns under shear. Experiments have been performed at both ambient and elevated temperatures with the aid of an electric kiln. The observed failure modes include fracture of the fin plate and tearing out of the tube around the welds. By considering the results of previously published research, the current design method for similar connections under purely tensile load, in CIDECT Guide 9, based on a deformation limit of 3% of the tube width is shown to be inadequate when evaluating the ultimate strength of such connections. By comparing the results from the current test program which failed in the fin-plate with Eurocode guidance for failure of a fin-plate alone under shear and bending load it is shown that the column face influences the overall connection strength regardless of failure mode. Concrete in-fill is observed to significantly increase the strength of connections over empty specimens, and circular column specimens were observed to exhibit greater strength than similarly proportioned square columns. A finite element (F.E.) model, developed using ABAQUS, is presented and validated against the experimental results in order that extensive parametric tests may be subsequently performed. When validating the model against elevated temperature tests it was found that using reduction factors suggested in published research for the specific steel grades improved results over applying the generic Eurocode elevated temperature steel strength reduction factors.

An analysis on the Causes of the Under-Potential in the Electric Anti-corrosion Section (전기방식(電氣防蝕) 적용구간의 전위 미달 원인 분석)

  • Lee, Eun-Chun;Ryu, Keong-Man;Yoon, Han-Bong;Shin, Gang-Wook;Hong, Sung-Taek;Lee, Eun-Woong
    • Proceedings of the KIEE Conference
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    • 2005.07e
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    • pp.55-57
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    • 2005
  • Along with the development of the industrial society, as the transportation of water which is the indirect capital of society and petroleum, gas, etc used as energy sources is rapidly increased. the underground material is being expanded. Like this, the pipes laid under the ground not only bring the corrosion to the land circumstances to reduce the life of the pipes, but also raise the social problem of leakage accidents and the economic loss by Pin Hole. By reason of this, for the purpose of protecting the corrosion of the underground material, we are constructing and operating the electrolytic protection facilities. In case of a region of which specific resistance is high, however, we are not keeping proper protection potential(that is -850mV) to get protection effects. In this study, for the water pipes that under-voltage phenomena occur in the protection potential, we made a spot survey on the under-voltage section and normal-voltage section, compared, analyzed each of the contents and examined the under-voltage causes of the protection potential.

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Partial Safety Factor of Offshore Wind Turbine Pile Foundation in West-South Mainland Sea (서남해안 해상풍력단지 말뚝기초의 부분안전계수)

  • Yoon, Gil Lim;Kim, Sun Bin;Kwon, O Soon;Yoo, Moo Sung
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.34 no.5
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    • pp.1489-1504
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    • 2014
  • This paper is aimed to suggest a site specific partial safety factor of offshore wind turbine (OWT) pile foundation design for the offshore wind turbine complex at a West-South mainland sea in Korea. International offshore wind design standards such as IEC, GL, DNV, API, ISO and EUROCODE were compared with each partial safety factor and resistance factor. Soil uncertainty analysis using a large number of soil data sampled was carried out, and their results were adapted to estimate partial safety factor of OWT pile foundation through reliability analyses. The representative partial safety factor has been estimated as 1.3. When a proposed partial factor is willing to use to other sites, it is recommended that further studies on code calibration are required to validate their accuracy using more site characterization data.