• Title/Summary/Keyword: Specific conductivity

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Pore-filling anion conducting membranes and their cell performance for a solid alkaline fuel cell (세공충진 음이온 전도성막의 제조 및 이를 이용한 고체알칼리 연료전지 성능 평가)

  • Choi, Youngwoo;Lee, Misoon;Park, Gugon;Yim, Sungdae;Yang, Taehyun;Kim, Changsoo
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.129.2-129.2
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    • 2010
  • AEM which were used for solid alkaline fuel cell(SAFC) were prepared by photo polymerization in method pore-filling with various quaternary ammonium cationic monomers and crosslinkers without an amination process. Their specific thermal and chemical properties were characterized through various analyses and the physico-chemical properties of the prepared electrolyte membranes such as swelling behavior, ion exchange capacity and ionic conductivity were also investigated in correlation with the electrolyte composition. The polymer electrolyte membranes prepared in this study have a very wide hydroxyl ion conductivity range of 0.01 - 0.45S/cm depending on the composition ratio of the electrolyte monomer and crosslinking agent used for polymerization. However, the hydroxyl ion conductivity of the membranes was relatively higher at the whole cases than those of commercial products such as A201 membrane of Tokuyama. These pore-filling membranes have also excellent properties such as smaller dimensional affects when swollen in solvents, higher mechanical strength, lowest electrolyte crossover through the membranes, and easier preparation process compared of traditional cast membranes. The prepared membranes were then applied to solid alkaline fuel cell and it was found comparable fuel cell performance to A201 membrane of Tokuyama.

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Effect of Hydrogen Reduction Treatment on Room-Temperature Thermoelectric Performance of p-type Thermoelectric Powders (P형 열전분말의 수소환원처리가 상온열전특성에 미치는 영향)

  • Kim, Kyung-Tae;Jang, Kyeong-Mi;Ha, Gook-Hyun
    • Journal of Powder Materials
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    • v.17 no.2
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    • pp.136-141
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    • 2010
  • Bismuth-telluride based $(Bi_{0.2}Sb_{0.8})_2Te_3$ thermoelectric powders were fabricated by two-step planetary milling process which produces bimodal size distribution ranging $400\;nm\;{\sim}\;2\;{\mu}m$. The powders were reduced in hydrogen atmosphere to minimize oxygen contents which cause degradation of thermoelectric performance by decreasing electrical conductivity. Oxygen contents were decreased from 0.48% to 0.25% by the reduction process. In this study, both the as-synthesized and the reduced powders were consolidated by the spark plasma sintering process at $350^{\circ}C$ for 10 min at the heating rate of $100^{\circ}C/min$ and then their thermoelectric properties were investigated. The sintered samples using the reduced p-type thermoelectric powders show 15% lower specific electrical resistivity ($0.8\;m{\Omega}{\cdot}cm$) than those of the as-synthesized powders while Seebeck coefficient and thermal conductivity do not change a lot. The results confirmed that ZT value of thermoelectric performance at room temperature was improved by 15% due to high electric conductivity caused by the controlled oxygen contents present at bismuth telluride materials.

Study on the Thermal and Electrical Conductivity Properties of Titanium-sputtered Materials

  • Han, Hye Ree
    • Journal of the Korean Society of Clothing and Textiles
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    • v.46 no.3
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    • pp.530-544
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    • 2022
  • Titanium exhibits substantial corrosion resistance, strength, and ductility, with a specific gravity of approximately 4.5 and a melting point of approximately 1800℃. It is currently used in aircraft parts and space development. This study considered the thermal characteristics, stealth effects of infrared thermal imaging cameras, electromagnetic shielding, and electrical conductivity of Ti-sputtered materials. Base materials of different densities and types were treated using titanium sputtering. Infrared thermal imaging showed a better stealth effect when the titanium layer was directed toward the outside. The film sample presented a better stealth effect than the fabrics did. In each of the samples subjected to titanium sputtering, when the titanium layer was directed outward, the untreated sample or exposed titanium layer showed surface temperatures lower than those of the samples with the titanium layer oriented toward the heat source. Additionally, after the titanium sputtering treatment, the films conducted electricity (low resistance) better than the fabrics did. All titanium-sputtered specimens presented reduced electromagnetic wave transmission and significantly reduced infrared transmission. These results are expected to apply to military uniforms (soldiers' protective clothing to gain the upper hand on the battlefield), medical sensors, multifunctional intelligent textiles and etc.

Phonon Dispersion and Specific Heat in FCC Structure (FCC구조에서 포논분산과 비열)

  • Chung, Jae-Dong;Lee, Kyung-Tae
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1207-1212
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    • 2004
  • A model for the phonon dispersion relationship for cubic zinc sulfide structure, for example SiC, is developed in terms of two unknown force constants. Born model that incorporates bond bending and bond stretching, is used for the force constants. The force constants are determined by fitting to experimental data. Using only the nearest-neighbor coupling results in $6{\times}6$ sized dynamic matrix. The eigenvalues of dynamics matrix for each wavenumber in 3-D ${\kappa}$ space correspond to frequencies, 3 for optical phonon and 3 for acoustic phonon, which is so-called dispersion relation (${\kappa}$-${\omega}$). The density of state is determined by counting the states for each frequency bin, and the properties such as specific heat and thermal conductivity can be obtained. The specific heat is estimated on this model and compared with experiment and other models, i.e. Debye model, Einstein model and combined Debye-Einstein model. In spite of the simple bond potential model, reasonable agreements are found.

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Characteristics of Specific Absorption Rate (SAR) in Electromagnetic (EM) Dosimetry

  • Hwang, Sun-Tae;Choi, Kil-Oung
    • Journal of Radiation Protection and Research
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    • v.25 no.2
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    • pp.109-114
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    • 2000
  • The SI unit of specific absorption rate (SAR) in W/kg in the electromagnetic (EM) field as non-ionizing radiation is exactly same as the SI unit of absorbed dose rate in Gy/s in the ionizing radiation field. The SI unit of both physical quantities can be expressed in $[m^{\cdot}s^{-3}]$. Where, the unit of absorbed dose, Gy stands for Gray. In EM biological interactions, the SAR equations are derived and the characteristics of EM field energy absorption in terms of the SAR are discussed and described on the mathematical basis.

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A Study on the Physical Properties of Mineral Hydrate Insulation Material Mixed with Basalt Fiber

  • Park, Jae-Wan;Chu, Yong-Sik;Seo, Sung-Kwan;Jeong, Jae-Hyen
    • Journal of the Korean Ceramic Society
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    • v.53 no.1
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    • pp.63-67
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    • 2016
  • Mineral hydrate is a new insulation material that compensates for the defects of existing materials. Mineral hydrate is made of inorganic ingredients; therefore, it is nonflammable. The porous structure of mineral hydrate makes the material lightweight and insulating. Mineral hydrate insulation and similar products have been studied and manufactured in Korea and abroad. However, these insulation materials need to improve in terms of strength. In this study, basalt fiber was used to enhance the strength. In order to observe the property changes, compressive strength, heat conductivity, and specific gravity were measured and XRD pattern analysis was performed. These tests confirmed that basalt fiber was effective at improving the strength and lowering the heat conductivity of mineral hydrate insulation.

NUMERICAL STUDY OF DROPLET VAPORIZATION AND COMBUSTION AT HIGH PRESSURE AND HIGH TEMPERATURE

  • KOO J.-Y.;KO J.-B.
    • International Journal of Automotive Technology
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    • v.6 no.6
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    • pp.563-570
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    • 2005
  • A numerical study of high pressure and temperature droplet vaporization and combustion is conducted by formulating one dimensional evaporation model and single-step chemical reaction in the mixture of hydrocarbon fuel and air. The ambient pressure ranged from atmospheric conditions to the supercritical conditions. In order to account for the real gas effect on fluid p-v-T properties in high pressure conditions, the modified Soave-Redlich-Kwong state equation is used in the evaluation of thermophysical properties. Some computational results are compared with Sato's experimental data for the validation of calculations in case of vaporization. The comparison between predictions and experiments showed quite a good agreement. Droplet surface temperature increased with increasing pressure. Ignition time increased with increasing initial droplet diameter. Temporal or spatial distribution of mass fraction, mass diffusivity, Lewis number, thermal conductivity, and specific heat were presented.

Study of Au-PTFE/Al Metallic bipolar plate for PEMFC (고분자 전해질형 연료전지용 Au-PTFE/Al 금속분리판 연구)

  • Yoo, Seung-Eul;Kim, Myong-Hwan;Goo, Young-Mo
    • New & Renewable Energy
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    • v.3 no.1 s.9
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    • pp.75-82
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    • 2007
  • Aluminum was used as metallic bipolar plate material to reduce a stack weight. The functional materials such as conductive material, Au and nonconductive material, PTFE [polytetrafluoroethylene] were coated on the bipolar plate to enhance electrical contact and corrosion prevention in PEMFC. The active area of bipolar plate is divided into the top layer part that electric current mainly passes, and the bottom layer part that gas and water pass. The bottom layer part in the flow channel needs not to have electrical conductivity because it doesn't pass electric current directly. In this reason, Au on the top layer and PTFE on the bottom layer were coated to apply high electrical conductivity and/or good corrosion resistance. Although the single cell performance using Au-PTFE/Al bipolar plate was shown 78% in comparison with that of graphite, specific power of Au-PTFE/Al bipolar plate(0.4 W/g) was twice as much as graphite bipolar plate.

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Hydrogen Supplying System using Metal Hydride (금속 수소화물을 이용한 수소공급시스템)

  • Bae, Sang-Chul;Katsuta, Masafumi
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.13-19
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    • 2007
  • To find out the optimum design of hydrogen storage and supply tank using Metal Hydride (briefly MH) and to make clear the performance characteristics under various conditions are our research purpose. In order to use the low-temperature exhaust heat, $LaNi_{4.7}Al_{0.3}$ which operates under the low pressure of 1 MPa is chosen, and we measure the basic properties, namely density, specific heat, PCT(Pressure-Concentration-Temperature) characteristics, and effective thermal conductivity. Then, a numerical calculation model of hydrogen storage using MH alloy is suggested and this thermal diffusion equation of model is solved by the backward difference method. This calculation results are compared with the experimental results of the systems which installed 1kg MH alloy and, it is found out that our calculation model can well predict the experimental results. By the experimental using MH alloy, it is recognized that the hydrogen flow rate can control by the step adjustment of brine temperature.

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Thermomechanical deformation in porous generalized thermoelastic body with variable material properties

  • Kumar, Rajneesh;Devi, Savita
    • Structural Engineering and Mechanics
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    • v.34 no.3
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    • pp.285-300
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    • 2010
  • The two-dimensional deformation of a homogeneous, isotropic thermoelastic half-space with voids with variable modulus of elasticity and thermal conductivity subjected to thermomechanical boundary conditions has been investigated. The formulation is applied to the coupled theory(CT) as well as generalized theories: Lord and Shulman theory with one relaxation time(LS), Green and Lindsay theory with two relaxation times(GL) Chandrasekharaiah and Tzou theory with dual phase lag(C-T) of thermoelasticity. The Laplace and Fourier transforms techniques are used to solve the problem. As an application, concentrated/uniformly distributed mechanical or thermal sources have been considered to illustrate the utility of the approach. The integral transforms have been inverted by using a numerical inversion technique to obtain the components of displacement, stress, changes in volume fraction field and temperature distribution in the physical domain. The effect of dependence of modulus of elasticity on the components of stress, changes in volume fraction field and temperature distribution are illustrated graphically for a specific model. Different special cases are also deduced.