• Title/Summary/Keyword: Specific capacity

검색결과 1,551건 처리시간 0.036초

A techno-economic analysis of partial repowering of a 210 MW coal fired power plant

  • Samanta, Samiran;Ghosh, Sudip
    • Advances in Energy Research
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    • 제3권3호
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    • pp.167-179
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    • 2015
  • This paper presents a techno-economic analysis of a partial repowering scheme for an existing 210 MW coal fired power plant by integrating a gas turbine and by employing waste heat recovery. In this repowering scheme, one of the four operating coal mills is taken out and a new natural gas fired gas turbine (GT) block is considered to be integrated, whose exhaust is fed to the furnace of the existing boiler. Feedwater heating is proposed through the utilization of waste heat of the boiler exhaust gas. From the thermodynamic analysis it is seen that the proposed repowering scheme helps to increase the plant capacity by about 28% and the overall efficiency by 27%. It also results in 21% reduction in the plant heat rate and 29% reduction in the specific $CO_2$ emissions. The economic analysis reveals that the partial repowering scheme is cost effective resulting in a reduction of the unit cost of electricity (UCOE) by 8.4%. The economic analysis further shows that the UCOE of the repowered plant is lower than that of a new green-field power plant of similar capacity.

Dependence of Thermal Properties on Crystallization Behavior of CaMgSi2O6 Glass-Ceramics

  • Jeon, Chang-Jun;Yeo, Won-Jae;Kim, Eung-Soo
    • 한국재료학회지
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    • 제19권12호
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    • pp.686-691
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    • 2009
  • The effects of thermal properties on the crystallization behavior of $CaMgSi_2O_6$ glass-ceramics were investigated as a function of sintering temperature from 800$^{\circ}C$ to 900$^{\circ}C$. The crystallization behavior of the specimens depended on the sintering temperature, which could be evaluated from the differential thermal analysis, X-ray diffraction and Fourier transform infrared spectroscopy. With increasing sintering temperature, the thermal conductivity of the sintered specimens increased, while the coefficient of thermal expansion (CTE) of the sintered specimens decreased. These results could be attributed to the increase of crystallization, confirmed from the estimation by density measurements. Also, the thermal diffusivity and specific heat capacity of the sintered specimens were discussed with relation to the sintering temperature. Typically, a thermal conductivity of 3.084 $W/m^{\circ}C$, CTE of 8.049 $ppm/^{\circ}C$, thermal diffusivity of 1.389 $mm^2/s$ and specific heat capacity of 0.752 $J/g^{\circ}C$ were obtained for $CaMgSi_2O_6$ specimens sintered at 900$^{\circ}C$ for 5 h.

슈퍼커패시터용 DAAQ/CNFs 전극의 전기화학적 특성 (Electrochemical Characteristics of DAAQ/CNFs electrode for Supercapacitor)

  • 김홍일;최원경;박수길
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
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    • pp.1184-1187
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    • 2003
  • Electrochemical capacitors are becoming attractive energy storage systems particularly for applications involving high power requirements such as hybrid systems consisting of batteries and electrochemical capacitors for electric vehicle propulsion. A new type electric double layer capacitor (EDLC) was constructed by using carbon nanofibers (CNFs) and DAAQ(1,5-diaminoanthraquinone) electrode. Carbonaceous materials are found in variety forms such as graphite, diamond, carbon fibers etc. While all the carbon nanofibers include impurities such as amorphous carbon, nanoparticles, catalytic metals and incompletely grown carbons. We have eliminated of Ni particles and some carbonaceous particles in nitric acid. Nitric acid treated CNFs could be covered with very thin DAAQ oligomer from the results of CV and TG analyses and SEM images. DAAQ oligomer film exhibited a specific capacity as 45-50 Ah/kg in 4M $H_2SO_4$. We established Process Parameters of the technique for the formation of nano-structured materials. Furthermore, improved the capacitive properties of the nano structured CNFs electrodes using controlled solution chemistry. As a result, CNFs coated by DAAQ composite electrode showed relatively good electrochemical behaviors in acidic electrolyte system with respect to specific capacity and scan rate dependency.

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Relationship between executive function and cue weighting in Korean stop perception across different dialects and ages

  • Kong, Eun Jong;Lee, Hyunjung
    • 말소리와 음성과학
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    • 제13권3호
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    • pp.21-29
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    • 2021
  • The present study investigated how one's cognitive resources are related to speech perception by examining Korean speakers' executive function (EF) capacity and its association with voice onset time (VOT) and f0 sensitivity in identifying Korean stop laryngeal categories (/t'/ vs. /t/ vs. /th/). Previously, Kong et al. (under revision) reported that Korean listeners (N = 154) in Seoul and Changwon (Gyeongsang) showed differential group patterns in dialect-specific cue weightings across educational institutions (college, high school, and elementary school). We follow up this study by further relating their EF control (working memory, mental flexibility, and inhibition) to their speech perception patterns to examine whether better cognitive ability would control attention to multiple acoustic dimensions. Partial correlation analyses revealed that better EFs in Korean listeners were associated with greater sensitivity to available acoustic details and with greater suppression of irrelevant acoustic information across subgroups, although only a small set of EF components turned out to be relevant. Unlike Seoul participants, Gyeongsang listeners' f0 use was not correlated with any EF task scores, reflecting dialect-specific cue primacy using f0 as a secondary cue. The findings confirm the link between speech perception and general cognitive ability, providing experimental evidence from Korean listeners.

Ionic Additives to Increase Electrochemical Utilization of Sulfur Cathode for Li-S Batteries

  • Seong, Min Ji;Yim, Taeeun
    • Journal of Electrochemical Science and Technology
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    • 제12권2호
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    • pp.279-284
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    • 2021
  • The high theoretical specific capacity of lithium-sulfur (Li-S) batteries makes them a more promising energy storage system than conventional lithium-ion batteries (LIBs). However, the slow kinetics of the electrochemical conversion reaction seriously hinders the utilization of Li-S as an active battery material and has prevented the successful application of Li-S cells. Therefore, exploration of alternatives that can overcome the sluggish electrochemical reaction is necessary to increase the performance of Li-S batteries. In this work, an ionic liquid (IL) is proposed as a functional additive to promote the electrochemical reactivity of the Li-S cell. The sluggish electrochemical reaction is mainly caused by precipitation of low-order polysulfide (l-PS) onto the positive electrode, so the IL is adopted as a solubilizer to remove the precipitated l-PS from the positive electrode to promote additional electron transfer reactions. The ILs effectively dissolve l-PS and greatly improve the electrochemical performance by allowing greater utilization of l-PS, which results in a higher initial specific capacity, together with a moderate retention rate. The results presented here confirmed that the use of an IL as an additive is quite effective at enhancing the overall performance of the Li-S cell and this understanding will enable the construction of highly efficient Li-S batteries.

Evaluation of Thermal Properties for the Bentonil-WRK Bentonite

  • Seok Yoon;Gi-Jun Lee;Deuk-Hwan Lee;Min-Seop Kim;Jung-Tae Kim;Jin-Seop Kim
    • 방사성폐기물학회지
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    • 제22권1호
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    • pp.9-16
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    • 2024
  • The bentonite buffer material is a crucial component in an engineered barrier system used for the disposal of high-level radioactive waste. Because a large amount of heat from the disposal canister is released into the bentonite buffer material, the thermal conductivity of the bentonite buffer is a crucial parameter that determines the design temperature. At the Korea Atomic Energy Research Institute (KAERI), a new standard bentonite (Bentonil-WRK) has been used since 2022 because Gyeongju (KJ) bentonite is no longer produced. However, the currently available data are insufficient, making it essential to investigate both the basic and complex properties of Bentonil-WRK. Thus, this study evaluated its geotechnical and thermal properties and developed a thermal conductivity empirical model that considers its dry density, water content, and temperature variations from room temperature to 90℃. The coefficient of determination (R2) for the model was found to be 0.986. The thermal conductivity values of Bentonil-WRK were 1-10% lower than those of KJ bentonite and 10-40% higher than those of MX-80 bentonites, which were attributable to mineral-composition differences. The thermal conductivity of Bentonil-WRK ranged between 0.504 and 1.149 W·(m-1·K-1), while the specific heat capacity varied from 0.826 to 1.138 (kJ·(kg-1·K-1)).

Mechanisms of immune tolerance to allergens in children

  • Kucuksezer, Umut C.;Ozdemir, Cevdet;Akdis, Mubeccel;Akdis, Cezmi A.
    • Clinical and Experimental Pediatrics
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    • 제56권12호
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    • pp.505-513
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    • 2013
  • Because the prevalence of allergic diseases has significantly increased in recent years, understanding the causes and mechanisms of these disorders is of high importance, and intense investigations are ongoing. Current knowledge pinpoints immune tolerance mechanisms as indispensable for healthy immune response to allergens in daily life. It is evident that development and maintenance of allergen-specific T cell tolerance is of vital importance for a healthy immune response to allergens. Such tolerance can be gained spontaneously by dose-dependent exposures to allergens in nature or by allergen-specific immunotherapy. Allergen-specific immunotherapy induces regulatory T cells with the capacity to secrete interleukin-10 and transforming growth factor-${\beta}$, limits activation of effector cells of allergic inflammation (such as mast cells and basophils), and switches antibody isotype from IgE to the noninflammatory type IgG4. Although allergen-specific immunotherapy is the only method of tolerance induction in allergic individuals, several factors, such as long duration of treatment, compliance problems, and life-threatening side effects, have limited widespread applicability of this immunomodulatory treatment. To overcome these limitations, current research focuses on the introduction of allergens in more efficient and safer ways. Defining the endotypes and phenotypes of allergic diseases might provide the ability to select ideal patients, and novel biomarkers might ensure new custom-tailored therapy modalities.

Characterization of a Substance from Photobacterium damsela subsp. piscicida that Non-specifically Binds to Streptavidin

  • Jung Tae Sung;Kim D. Thompson;Adams Aelexandra;Oh Myung Joo
    • Fisheries and Aquatic Sciences
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    • 제3권1호
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    • pp.52-63
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    • 2000
  • Non-specific reaction has been a problem in doing, especially, research and diagnosis for infectious agents. Avidin-biotin-peroxidase complex (ABC) techniques has widely been used to amplify a reaction. Photobacterium damse1a subsp. piscicdia (formerly Pasteurella piscicida) exhibited a capacity to bind with streptavidin non-specifically. The band, estimated 26 K Da in Western blotted paper, was blocked with biotin but incompletely. In an attempt to explore an involvement of the non-specific substance in attaching piscine cells, cell attachment test performed using anti- Ph. d. subsp piscicida sera raised mouse and rabbit exhibited slightly blocking effects for Mediterranean (1736) and significantly for Japanese (Sp 92144) isolate. Biotin decreased the attachment ability significantly for Sp92144 but it was not effective to 1736. Both isolates showed greatly enhanced attachment ability with poly-L-lysin. The non-specific binding substance was contained in bacterial extracellular products (ECPs). The substance was able to purified with 2-imminobiotin affinity column, the purified substance appeared to have 4 bands in silver staining, and had a carbohydrate branch. This purified substance showed cytotoxic effects selectively between 5 piscine cell lines. Moreover, it stimulated rainbow trout macrophage in terms of reduction of cytochrome cas well as yeast phagocytosis, significantly.

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The Rat Myosin Light Chain Promoter-Driven DsRed Reporter System Allows Specific Monitoring of Bone Marrow Mesenchymal Stem Cell- Derived Cardiomyocytes

  • Choi, Seung-Cheol;Lim, Do-Sun
    • Reproductive and Developmental Biology
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    • 제32권1호
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    • pp.21-25
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    • 2008
  • Bone marrow mesenchymal stem cells (BMMSCs) have the capacity for self-renewal and differentiation into a variety of cell types. They represent an attractive source of cells for gene and cell therapy. The purpose of this study is to direct the specific expression of the DsRed reporter gene in $Sca-1^+$ BMMSCs differentiated into a cardiomyogenic lineage. We constructed the prMLC-2v-DsRed vector expressing DsRed under the control of the 309 tp fragment of the rat MLC-2v 5'-flanking region. The specific expression of the DsRed reporter gene under the transcriptional control of the 309 bp fragment of the rat MLC-2v promoter was tested in 5-azacytidine healed-$Sca-1^+$ BMMSCs over 2 weeks after the prMLC-2v-DsRed transfection. The prMLC-2v-DsRed was specifically expressed in the $Sca-1^+$ BMMSCs with cardiomyogenic lineage differentiation and it demonstrates that the 309 bp sequences of the rat MLC-2v 5'-flanking region is sufficient to confer cardiac specific expression on a DsRed reporter gene. The cardiac-specific promoter-driven reporter vector provides an important tool for the study of stem cell differentiation and cell replacement therapy in ischemic cardiomyopathy.

폴리피롤 첨가에 의한 supercapacitor용 저 임피던스 전극 (Electrode of Low Impedance by Polypyrrole Addition for Supercapacitor)

  • 김경민;장인영;강안수
    • 대한안전경영과학회:학술대회논문집
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    • 대한안전경영과학회 2003년도 추계학술대회
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    • pp.343-350
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    • 2003
  • The best Ppy weight ratio was 7 wt% and the optimal electrode composition ratio was 78 : 17 : 5 wt.% of (MSP-20 : BP-20 =1 : 1), (Super P : Ppy =10 : 7) and P(VdF-co-HFP). Implantation of Ppy as the conducting agents have led to superior electrochemical characteristics because of the low of internal resistance and faradaic capacitance. The result of unit cell with Ppy 7 wt% were as follows: 28.02 Fig of specific capacitance, 1.34 Ω of DC-ESR and 0.36 Ω of AC-ESR. Unit cell showed a good stability up to 200 charge-discharge cycles, retaining 82% of their original capacity at 200 cycles. From the analysis of impedance, the electrodes with Ppy 7 wt% showed low ESR, low charge transfer resistance and quick reaction rate. It was inferred that quick charge-discharge was possible. As compared with the specific capacitance (rectangular shape) of CV, it was also concluded that the specific capacitance originated from thecompound phenomena of the faradaic capacitance by oxidation and reduction of Ppy and the non-faradaic capacitance by adsorption-desorption of activated carbon.

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