• Title/Summary/Keyword: Span-80

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The Characteristic Control of Spherical Silica Particle Using by W/O Type Emulsion(I);The analysis of Particle shape and size distribution of silica as a function mixing speed (W/O형 에멀젼을 이용한 구형 실리카 입자의 특성제어(제1보);교반속도에 따른 실리카 입자의 형태 및 입도 분석)

  • Park, Heung-Cho;Kim, Sang-Chun
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.1
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    • pp.1-11
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    • 2006
  • The W/O emulsion was formed by mixing hydrophobic nonion surfactants of span 80 and tween 60 with kerosine, and by adding sodium silicate aqueous solution. Precipitating the W/O emulsion by sodium bicarbonate resulted in spherical silica particles. Shape and size distribution of silica particles were observed. The particles were spherical and they have narrow size distribution. Particle sizes were 9.29, 7.39 and $5.73\;{\mu}m$ at homogenizer speed of 2500, 3000, and 3500 rpm, respectively. The particle size was decreased by increasing agitation speed due to the formation of emulsion droplet. At fixed agitation speed, absorbed paraffin oil weight were measured and the $SiO_2/Na_2O$ mole ratio effects on particle size were investigated. Particle size was decreased by increasing the mole ratio of $SiO_2/Na_2O$.

Antitumor Activity of Kp, a Protein-polysaccharide from the Mycelial Culture of Phellinus linteus (Phellinus linteus 균사 배양물로부터 분리한 단백다당체 Kp의 항암활성)

  • Chung, Kyeong-Soo;Kim, Shin-Sook;Kim, Hee-Soo;Han, Man-Woo;Kim, Byong-Kak
    • YAKHAK HOEJI
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    • v.38 no.2
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    • pp.158-165
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    • 1994
  • A protein-polysaccaride fraction Kp(53.9% polysaccharide, 14.2% protein) was separated from the shake-cultured mycelia of a basidiomycetous fungus, Phellinus linteus, and its antitumor activity against sarcoma 180 in ICR mice was investigated. When administered after the tumor implantation, Kp exerted antitumor activity by inhibiting the growth of the sarcoma 180 solid tumor by 71.5% and increasing the life span of the sarcoma 180 ascitic mice by 51.5% at 100 mg/kg. In pretreatment tests, in which Kp was administered once daily for 9 days before the tumor implantation, Kp inhibited the growth of the solid and ascites form of sarcoma 180, respectively, by 35.4% and by 80.3% at 100 mg/kg. However, Kp showed no in vitro cytotoxic activity against a murine leukemia L1210 and a human gastric tumor SNU.1 upto the concentration of $200\;{\mu}g/ml$. From these results, it is clear that the antitumor activity of Kp is exerted through its immunomodulating activity on the host's immune system.

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Synthesis of $LiMn_2O_4$ Cathode Materials by Emulsion Method and Its Electrochemical Properties

  • Youn Kyu Choi;Bok Hee Kim
    • The Korean Journal of Ceramics
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    • v.5 no.3
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    • pp.250-254
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    • 1999
  • Synthesis of the spinel $LiMn_2O_4$ by emulsion method was investigated. $LiOH.H_2O \;and \;Mn(NO_3)_2.6H_2O$ were used as starting materials to prepare mixed aqueous solution (0.5 mol/$\ell$ for the $LiMn_2O_4$). Kerosene, paraffin oil and span 80 were used for organic phase. The aqueous solutioin and organic phase were mixed in the ratio of 2:1 and emulsified at the speed of 4000 rpm for 5 min. The prepared emulsions were dropped into the petroleum heated at $170^{\circ}C$ to evaporate water in the silicon oil bath, dried at $120^{\circ}C$ in the oven the remove petroleum and calcined at temperature ranges from 600 to $900^{\circ}C$ for 48 hrs. The characteristics of powders were investigated by XRD, SEM, BET and electrochemical properties of synthesized cathode materials were measured with Galvanostatic system. $Li_{1.05}Mn_2O_4$ calcined at $800^{\circ}C$ for 48 hrs showed initial discharge capacity of 125.9mAH/g.

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A Study on the Establishment Feature and the Development of Large Space Buildings in Korea (국내 대공간 건축의 발달과정과 건립특성에 관한 연구)

  • Lee, Ju-Na
    • Journal of Korean Association for Spatial Structures
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    • v.9 no.2
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    • pp.65-75
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    • 2009
  • For the large space buildings since 1960s in Korea spanned more than 30m, the establishment feature and the development process were examined. As the Results, physical facilities with 40-70m span were mainly established in 1980s-1990s, but large scale convention centers have been establishing after 2000s as the used of large space buildings are varied. Also, a space frame has been generally used in 1980s while the unique structural shapes were builded in the early age(1960s), the structural design with concerns a form and using various structural systems have been attempting after 2000s.

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Higher Extraction of Phytochemical Compounds from Tartary Buckwheat Seeds by the Application of Surfactant Formulation

  • Park, Cheol Ho;Azad, Md Obyedul Kalam;Heo, Jeong Won;Kang, Wie Soo
    • Korean Journal of Plant Resources
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    • v.30 no.6
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    • pp.686-692
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    • 2017
  • The aim of this study was to determine the suitability of surfactant to extract higher phenolic compound, flavonoid and antioxidant activity from Tartary buckwheat and evaluate the potentiality of surfactant as a screening agent for breeding purpose. Primarily, we employed two types of surfactant (Hydrophilic: Tween 20 and Lipophilic: Span 80) to select the suitable surfactant agent for the extraction of optimum bioactive compounds. Between two surfactants, Tween 20 showed highest efficiency at 4 mM concentration to extract total phenolic content (TP), total flavonoid (TF) and antioxidant activity (AA). Tween 20 at 4 mM concentration was fixed for further analysis along with hot water ($90^{\circ}C$) treatment as a control. In our findings, highest TP (118 mg/g), TF (38 mg/g) and AA (76%) was achieved in KW21 and KW22 among the fifteen accessions of Tartary buckwheat. In other way, TP, TF and AA was 200%, 120% and 110% higher in surfactant formulation compared with control treatment, respectively.

Improvement of Liquid Wetting and Retention Properties of Wool Fabric in Nonionic Surfactant Solutions (비이온계 계면활성제 수용액에서 모직물의 표면적심과 액체보유력 향상)

  • Kim, Chun-Hee
    • Textile Coloration and Finishing
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    • v.21 no.2
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    • pp.7-13
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    • 2009
  • The effects of 0.1g/dl nonionic surfactant solutions on liquid wetting and retention properties of wool fabric are reported. The 10 different nonionic surfactants (Span 20, Tween 20, 40, 60, 80, 21, 61, 81, 65, 85), wool cloth (EMPA 217), and wool soiled cloth (EMPA 107) are used in the study. Both EMPA 217 and 107 have water contact angle($\Theta$)>$90^{\circ}$, which indicates that water spreading over a fabric surface and penetration into the fabric rarely occur. However, EMPA 217 and 107 are easily wetted with perchloroethylene(PCE) having very low values of $\Theta$'s and high values of liquid retention. Water wetting properties are greatly improved by adding nonionic surfactants into the system. Generally, hydrophilic surfactants which have low number of carbon atoms or unsaturated hydrophobic structures are effective in improving water wetting of wool fabrics. The water retention of EMPA 217 and 107 in surfactant solutions have positive relations with $cos{\Theta}$, adhesion tension, and work of adhesion. 40.3% pore volume of EMPA 217 and 26.1% pore volume of EMPA 217 can be filled with water even when we assume $cos{\Theta}=1$ (${\Theta}=0^{\circ}$).

Magnetic refrigerator for hydrogen liquefaction

  • Numazawa, T.;Kamiya, K.;Utaki, T.;Matsumoto, K.
    • Progress in Superconductivity and Cryogenics
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    • v.15 no.2
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    • pp.1-8
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    • 2013
  • This paper reviews the development status of magnetic refrigeration system for hydrogen liquefaction. There is no doubt that hydrogen is one of most important energy sources in the near future. In particular, liquid hydrogen can be utilized for infrastructure construction consisting of storage and transportation. Liquid hydrogen is in cryogenic temperatures and therefore high efficient liquefaction method must be studied. Magnetic refrigeration which uses the magneto-caloric effect has potential to realize not only the higher liquefaction efficiency > 50 %, but also to be environmentally friendly and cost effective. Our hydrogen magnetic refrigeration system consists of Carnot cycle for liquefaction stage and AMR (active magnetic regenerator) cycle for precooling stages. For the Carnot cycle, we develop the high efficient system > 80 % liquefaction efficiency by using the heat pipe. For the AMR cycle, we studied two kinds of displacer systems, which transferred the working fluid. We confirmed the AMR effect with the cooling temperature span of 12 K for 1.8 T of the magnetic field and 6 second of the cycle. By using the simulation, we estimate the total efficiency of the hydrogen liquefaction plant for 10 kg/day. A FOM of 0.47 is obtained in the magnetic refrigeration system operation temperature between 20 K and 77 K including LN2 work input.

Experimental Analysis of the Ground Take-off Flight of a Butterfly (지면이륙하는 나비의 날개짓 분석)

  • Jang, Young-Il;Lee, Sang-Joon
    • 한국전산유체공학회:학술대회논문집
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    • 2008.03b
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    • pp.142-143
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    • 2008
  • In the present work, high-speed video images of the ground take-off flight of a live butterfly were captured and their dynamic motions during the first full-stroke were analyzed. To capture the dynamic images of the take-off motion, the experimental setup consisted of a high-speed camera, a Xenon lamp as a light source and a transparent chamber of $15^W{\times}15^L{\times}17^H$ $cm^3$ in physical size. The ambient temperature and supplementary lighting devices were precisely controlled. The weight and wing span of the butterfly tested in this study was 104 mg and 63.14 mm, respectively. The ground take-off images were captured with 4000 fps with a spatial resolution of (1024${\times}$512) pixels. The period of the first full-stroke was 80.5ms and the flapping speed of downstroke was 2 times faster than that of upstroke. As a result, butterflies used the fling and near-clap motion to generate lifting force and an interesting take-off behavior of early pronation and downstroke was observed.

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Asymmetric Electrohydrodynamic Flow of Dielectric Liquid around Symmetric Coplanar Electrodes (대칭형상의 평판 전극 주위의 비대칭 절연유체 유동)

  • Baek, Kwang Hyun;Cho, Dong Sik;Suh, Yong Kweon
    • Journal of the Korean Society of Visualization
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    • v.11 no.1
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    • pp.48-52
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    • 2013
  • This paper presents experimental observation of asymmetric electrohydrodynamic flow generated around a pair of symmetric coplanar electrodes. Electrodes are attached on the bottom of the cavity containing a dielectric liquid, i.e., a mixture of dodecane and 0.5% wt Span80. In the first experiment, an AC voltage of 1500 V is applied with the frequency varying in the range 10~500 hz and the left electrode being grounded. The flow patterns show that the center line of vortices is unexpectedly tilted to the left side. If the right side electrode is grounded, the center line is tilted to the right side. The magnitude of the fluid velocity shows an irregular variation with the frequency in the range 10 Hz~100 Hz, beyond which it simply decays. In the second experiment, we applied fixed AC with 1000 V and 60 Hz superposed by DC voltage varying in the range -1000 V ~ +1000 V. The center line of the flow pattern is tilted to the right side with positive DC voltage and to the left side with negative DC. We have managed to show that the flow pattern can be symmetric with a suitable combination of DC and AC, e.g., DC 850 V plus AC 1000 V with the frequency 10 Hz.

Characteristics of Fine WO3 Powders Prepared by Emulsion Evaporation (에멀전증발법으로 제조된 미세 산화텅스텐 분말의 특성)

  • 안종관;신창훈;이만승;이충효
    • Journal of Powder Materials
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    • v.9 no.2
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    • pp.89-95
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    • 2002
  • Spherical fine powders of tungsten oxide powders were prepared by the emulsion evaporation method. The characteristics of the powders prepared were examined by means of TGA, X-ray diffraction, SEM and image analysis. The emulsions were prepared by fast mixing of aqueous phase containing tugsten and the organic phase which composed of kerosene, surfactant, and paraffin oil. Precursors were made by evaporating the emulsionin the kerosene bath at $160^{\circ}C$, and then calcined at $650^{\circ}C$ in order to produce tungsten oxide powders. The average particle size of the tungsten oxide powders was $0.5\mutextrm{m}$ and their shapes were spherical at the both case of w/o and o/w type emulsions. As the HLB value of the surfactant increased and the concentration of tungsten ions decreased the mean particle siqe of tungsten oxide powders decreased whereas agglomerationsize increased. The optimum concentration of Span 80 was 8 percent by volume, and the optimum stirring speed in the emulsion formation was 5000 rpm in order to obtain fine and well dispersed $WO_3$ powders.