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http://dx.doi.org/10.12925/jkocs.2006.23.1.1

The Characteristic Control of Spherical Silica Particle Using by W/O Type Emulsion(I);The analysis of Particle shape and size distribution of silica as a function mixing speed  

Park, Heung-Cho (Department of Polymer Science & Engineering, Chungju National University)
Kim, Sang-Chun (Bo-Kwang Chemical Co., Ltd.)
Publication Information
Journal of the Korean Applied Science and Technology / v.23, no.1, 2006 , pp. 1-11 More about this Journal
Abstract
The W/O emulsion was formed by mixing hydrophobic nonion surfactants of span 80 and tween 60 with kerosine, and by adding sodium silicate aqueous solution. Precipitating the W/O emulsion by sodium bicarbonate resulted in spherical silica particles. Shape and size distribution of silica particles were observed. The particles were spherical and they have narrow size distribution. Particle sizes were 9.29, 7.39 and $5.73\;{\mu}m$ at homogenizer speed of 2500, 3000, and 3500 rpm, respectively. The particle size was decreased by increasing agitation speed due to the formation of emulsion droplet. At fixed agitation speed, absorbed paraffin oil weight were measured and the $SiO_2/Na_2O$ mole ratio effects on particle size were investigated. Particle size was decreased by increasing the mole ratio of $SiO_2/Na_2O$.
Keywords
sodium metasilicate; W/O type emulsion; kerosine; silica; oil absorbing capacity;
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