• Journal of Hydrogen and New Energy
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• v.26 no.1
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• pp.21-27
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• 2015

Hydrogen production from commercial diesel fuels is an attactive option for energy generation purpose due to the low cost and good availability of diesel fuels. However, in order to utilize commercial diesel fuels, the sulfur contents must be removed down to approximately 0.1 ppm level to protect the fuel cell catalysts from poisoning. Commercial catalysts $CoMo/Al_2O_3$ and $NiMo/Al_2O_3$ were tested for HDS (Hydrodesulfurization) of model diesel and commercial diesel. The experimental conditions were $250-400^{\circ}C$ and LHSV (Liquid Hourly Space Velocity) $0.27-2.12hr^{-1}$. $NiMo/Al_2O_3$ was found to be more effective than $CoMo/Al_2O_3$ in removing sulfur from model diesel. Based on the experimental results of model diesel, commercial diesel fuel purchased from a local petrol station was tested for HDS using $NiMo/Al_2O_3$. The GC-SCD (Gas Chromatography Sulfur Chemiluminescence Detector) results showed that the DMDBT (Dimethyldibenzothiophene) derivatives were fully removed from the commercial diesel fuel proving that HDS with $NiMo/Al_2O_3$ is technically feasible for industrial applications.

• Journal of the Korean Geophysical Society
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• v.4 no.2
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• pp.103-111
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• 2001

Geophysical survey was carried out to derive some information on the existence of near-surface anomalous body at Reung-Chi area in Kongju. Resistivity, seismic, magnetic and gravity method were applied. Geophysical survey that was applied was the electrical resistivity survey, seismic survey, magnetic survey, gravity survey. These surveys are analyzed to provide data of high resolution. As a result of analysis of resistivity survey, anomalies showing high resistivity anomaly than around appeared, and the one showing M-shape out of those explains the possibility that underground common or other underground structure or geographical anomalous zone could exist in the underground. As a result of analysis of seismic survey, it is clear that the low velocity layer is spread as far as the bottom of the underground. It is possible to presume that it is a phenomenon appearing while going through the underground space where it is lying in the underground. Area that shows unusual situation in interpretation of data on seismic waves are included into the area that once showed resistivity anomaly, the results of both seismic surveys come in accord. As a result of magnetic survey, a circle-shape of twin magnetic fields in the area where abnormalities are shown between electrical resistivity survey and seismic survey is appeared. Given the area of gravity survey, abnormalities whose density is different from the one around the bottom of the underground. As a result of analogizing the data of underground of the subsurface based on analysis of data from each survey, it was interpreted that anomalous zone exists commonly in the research areas.

• Tunnel and Underground Space
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• v.25 no.1
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• pp.56-67
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• 2015

In this study, a source locating technique applicable to transversely isotropic media was developed. Wave velocity anisotropy was considered based on the partition approximation method, which simply enabled AE source locating. Sets of P wave arrival time were decided by the two-step AIC algorithm and they were later used to locate the AE sources when having the least error compared with the partitioned elements. In order to validate the technique, pencil lead break test on artificial transversely isotropic mortar specimen was carried out. Defining the absolute error as the distance between the pencil lead break point and the located point, 1.60 mm ~ 14.46 mm of range and 8.57 mm of average were estimated therefore it was regarded as thought to be 'acceptable' considering the size of the specimen and the AE sensors. Comparing each absolute error under different threshold levels, results showed small discrepancies therefore this technique was hardly affected by background noise. Absolute error could be decomposed into each coordinate axis error and through it, effect of AE sensor position could be understood so if optimum sensor position was able to be decided, one could get more precise outcome.

• Journal of the Korean Association of Geographic Information Studies
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• v.11 no.2
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• pp.85-92
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• 2008

This study, the one concerning the evaluation analysis of the function of the wind generation using KLAM_21, has examined closely how the wind really flows on the space of the city, working with the object of case location. In the first place, the cold air formed at upper stream of Sincheon river, a ravine of whole area of Gachang gully and an inclined plane of neighboring mountainous district, flows to the north and expands itself along the upper stream of the Sincheon river, and as the time passes, it is tending upwards in the change of the volume and height as well as of the velocity and direction, of the cold air. It was learned that this phenomenon has made it clear that the spatial features of this area give rise to very good condition in generating and flowing the cold air. Meanwhile, it has been shown that in the area of park in the Ap-mountain, the generation and flow of the cold air are much interrupted because of the overpass traversing the whole area of the park of Ap-mountain, the congested area of large-scaled apartments and the urban development activities constructing the building in the park, and the volume and height of the cold air has been grown very small. In conclusion, It has been learned that for maximization of the spatial effect of the wind corridor, the areas where the cold air is generated, flowed, accumulated, and maintained, have to be connected spatially, and this spatial connection has a close relation with spatial features of the area.

• Tunnel and Underground Space
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• v.19 no.2
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• pp.146-157
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• 2009

An experimental study of accelerated weathering on mudstone sample specimens from Haman, Gyeongnam was performed to investigate the variations of physico-mechanical properties of deteriorated rocks due to freeze-thaw weathering. Each complete cycle of freeze and thaw lasted 24 hours, comprising 2 hours of saturating in vacuum chamber, 8 hours of freezing at $-16{\pm}1^{\circ}C$ and 14 hours of thawing at room temperature. Total of 55 cycles of freeze-thaw were completed with measuring the index properties as well as geometries of microfractures. The measured specific gravity and P-wave velocity found to decrease with increasing freeze-thaw cycles. On the other hand, absorption ratio and effective porosity were continuously increased with increasing freeze-thaw cycles. It was found that the index properties of deteriorated sample specimen depend on its initial properties and flaws in rock. The size and density of the traces of the microfracture on slab specimen exhibited abrupt changes after 30 cycles of freeze-thaw weathering. The results obtained in this study show that the box fractal dimension($D_B$) given in this paper has the strong capability of quantifying the size and density of the microfracture.

• Journal of Science Education
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• v.38 no.3
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• pp.569-584
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• 2014

The Purpose of this study was an analysis of high school student's understanding level about concepts of special relativity through in-depth interview. The 8 participants were 10th grade students in H high school in Ulsan city, who were interviewed and analyzed in the results of the interview about basic concepts of special relativity using achievement checklist in 6 situations(principle of constancy of light velocity, principle of relativity, relativity of simultaneity, garage paradox, rocket paradox). As results of the checklist, the participants showed high achievement in the content level of simple phenomena and simple concepts related to special relativity. But they showed low achievement in the concept level for fundamental understanding of special relativity. As results of the interview, it was found that the participants decided the order of events depending on their intuition and had a difficulty to apply the coordinate system to real situation, even though they mathematically understood it. In addition, some participants who could not understand the inertial coordinate system explained paradoxes of relativity depending on their intuition and had learner's chaos. Finally, though high school students usually being in formal operational stage, some students had difficulty to draw phenomena of space and time in two dimensional plane.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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• v.28 no.2
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• pp.247-254
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• 2010

In this paper, a new approach has been studied correcting the geometric distortion of SPOT 4 imagery. Two new equations were induced by the relationship between satellite and the Earth in the space. line-of-sight (LOS) vector adjustment model for SPOT 4 imagery was implemented in this study. This model is to adjust LOS vector under the assumption that the orbital information of satellite provided by receiving station is uncertain and this uncertainty makes a constant error over the image. This model is verified using SPOT 4 satellite image with high look angle and thirty five ground points, which include 10 GCPs(Ground Control Points) and 25 check points, measured by the GPS. In total thirty five points, the geometry of satellite image calculated by given satellite information(such as satellite position, velocity, attitude and look angles, etc) from SPOT 4 satellite image was distorted with a constant error. Through out the study, it was confirmed that the LOS vector adjustment model was able to be applied to SPOT4 satellite image. Using this model, RMSEs (Root Mean Square Errors) of twenty five check points taken by increasing the number of GCPs from two to ten were less than one pixel. As a result, LOS vector adjustment model could efficiently correct the geometry of SPOT4 images with only two GCPs. This method also is expected to get good results for the different satellite images that are similar to the geometry of SPOT images.

• Applied Chemistry for Engineering
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• v.17 no.5
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• pp.451-457
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• 2006

We synthesized phase pure CrN having surface areas up to $47m^2/g$ starting from $CrCl_{3}$ with $NH_{3}$. Thermal Gravimetric Analysis coupled with X-ray diffraction was carried out to identify solid state transition temperatures and the phase after each transition. In addition, the BET surface areas, pore size distributions, and crystalline diameters for the synthesized materials were analyzed. Space velocity influenced a little to the surface areas of the prepared materials, while heating rate did not. We believe it is due to the fast removal of reaction by-products from the system. Temperature programmed reduction results revealed that the CrN was hardly passivated by 1% $O_{2}$. Molecular nitrogen was detected from CrN at 700 and $950^{\circ}C$, which may be from lattice nitrogen. In temperature programmed oxidation with heating rate of 10 K/min in flowing air, oxidation started at or higher than $300^{\circ}C$ and resulting $Cr_{2}O_{3}$ phase was observed with XRD at around $800^{\circ}C$. However the oxidation was not completed even at $900^{\circ}C$. CrN catalysts were highly active for n-butane dehydrogenation reaction. Their activity is even higher than that of a commercial $Pt-Sn/Al_{2}O_{3}$ dehydrogenation catalyst in terms of volumetric reaction rate. However, CrN was not active in pyridine hydrodenitrogenation.

• Journal of the Korean Magnetics Society
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• v.22 no.1
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• pp.19-22
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• 2012

$Ba_2Mg_{0.5}Co_{1.5}(Fe_{0.99}In_{0.01})_{12}O_{22}$ was prepared by the conventional solid-state reaction method, and studied by x-ray diffractometer, vibrating sample magnetometer, and Mossbauer spectrometer. The crystal structure was determined to be a single-phased rhombohedral with space group R-3m. Magnetization value were $M_s$ = 28.6 emu/g at 295 K. The hysteresis loops indicate that all the samples are ferrimagnetic behaviors. Mossbauer spectra of $Ba_2Mg_{0.5}Co_{1.5}(Fe_{0.99}In_{0.01})_{12}O_{22}$ have been 6-sextet taken at various temperatures ranging from 4.2 to 620 K. Based on the isomer shift (${\delta}$) values of all samples, the charge states were found to be $Fe^{3+}$ state at all temperatures, the Curie temperature was determined to be 630 K by the ZVC curve.

• Fire Science and Engineering
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• v.33 no.4
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• pp.35-40
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• 2019

In this study, the mass flow rate of the heat release rate equation, which is the major factor of the oxygen consumption method, was analyzed for the fundamental investigation of the cone-calorimeter (5 m length and 0.3 m diameter). The shapes of a completely empty inside, 3 mm pore diameter mesh and pore diameter 10 mm honeycomb with 0.76 porosity were constructed using the cone-calorimeter. To calculate the mass flow rate, four bi-directional probes and thermocouples were installed in a uniform position in the vertical direction of flow. The velocity gradient and flow perturbation were measured from the increase in Reynolds number. As the flow capacity increased, the speed gradient increased in all three shapes relative to the turbulence intensity. In addition, the deviation of extended uncertainty to the mass flow was completely low in the order of empty space, mesh (d_p = 3 mm) and honeycomb (d_p = 10 mm and 𝜖 = 0.76) at the 95% confidence level. The results can be used in designs to improve the flow stability of the cone calorimeter.