• 제목/요약/키워드: Space Velocity

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Comparative Study on the Performance of Small Satellites Launch Vehicle Employing ElecPump Cycle Upper Stage Engine (전기펌프 사이클 상단 엔진을 적용한 소형발사체 성능 비교연구)

  • Yu, Byungil;Kwak, Hyun-Duck;Kim, Hongjip
    • Journal of Aerospace System Engineering
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    • v.14 no.5
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    • pp.107-121
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    • 2020
  • The performance analysis of the small satellites launch vehicle using the electric pump cycle as the upper stage engines was performed. The first stage is the launch vehicle that uses the test launch vehicle of the Korea Space Launch Vehicle II and the second stage employs elecpump cycle engine that uses liquid methane and kerosene (RP-1) as fuel. A model for the mass estimation was presented and the analysis was conducted for the range of thrust of 20 to 40 kN and combustion pressure of 3 to 6 MPa with a nozzle expansion ratio of 60 to 100. The mixture ratio with the maximum velocity increment was calculated and the performance of the LEO and SSO payload were calculated from the stage mass estimation. In both the cases, liquid methane, and RP-1 showed maximum payload for 20 kN thrust, 3 MPa combustion pressure, and the nozzle expansion ratio of 100, with a mixture ratio of 3.49 for liquid methane and 2.75 for RP-1. In addition, the ditching points of the first stage and the fairing in the LEO mission were analyzed using ASTOS.

Practical Application of Mn-Cu Metal Catalyst for the Removal of Acetaldehyde (아세트알데히드 제거를 위한 Mn-Cu 금속촉매 실용화에 관한 연구)

  • Jung, Sung-Chul;Lee, Seung-Hwan
    • Journal of Digital Convergence
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    • v.10 no.8
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    • pp.201-210
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    • 2012
  • Because sensing odor varies depending on each person, even if the odor is released in line with the legal emission permission concentration levels, it can still become a social issue if a civil complaint is made. The purpose of this research is to study the possibility of putting Mn-Cu metallic oxide catalysts into practical use to economically eliminate acetaldehyde which produces a odor in the industrial process. An optimal operating parameter to eliminate acetaldehyde was deduced through a performance evaluation in the research laboratory and the performance was verified by applying the parameter into an actual facility as an on-the-site experiment through a Scale-up of pilot size. The operating temperature of the metallic oxide catalysts researched so far was at the minimum close to $220^{\circ}C$, and the $220^{\circ}C$ elimination efficiency was 50% or below. However, having experimented by using a Mn-Cu metallic oxide catalyst in this research, optimum elimination efficiency showed when space velocity (GHSV) was equal to or below 6,000 $hr^{-1}$. The average elimination efficiency was 61.2% when the catalyst controlling temperature was $120^{\circ}C$, 93.3% when the catalyst controlling temperature was $160^{\circ}C$, and 94.9% when catalyst controlling temperature was $180^{\circ}C$, thereby reflecting high elimination efficiency. The specific surface area of the catalyst was $200m^2/g$ before use, however, was reduced to $47.162m^2/g$ after 24 months and therefore showed that despite the decrease in specific surface area as time passed, there was no significant influence on the performance. Having operated Mn-Cu metallic oxide catalyst systems for at least two years on a site where there was no inflow of toxins like sulfur compounds and acidic gases, we were able to confirm that elimination efficiency of at least 90% was maintained.

The Effect of Nb2O5 on Cu-Nb-CeO2 Catalysts for Water Gas Shift Reaction of Compact Reformer (컴팩트 개질기용 수성가스전이 반응을 위한 Cu-CeO2 촉매에 대한 Nb2O5의 영향)

  • JEONG, CHANG-HOON;KIM, TAE-GWANG;BYON, HUI-JU;KIM, JU-HWAN;BAE, EUN-TAEK;SHEN, KAILIN;JEON, KYUNG-WON;JEONG, DAE-WOON
    • Journal of Hydrogen and New Energy
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    • v.31 no.1
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    • pp.57-64
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    • 2020
  • The water-gas shift reaction for the compact reformer was carried out at a gas hourly space velocity of 72,152 h-1 over the Cu-Nb-CeO2 catalysts prepared by co-precipitation method. In order to investigate the effect of Nb2O5 promotion over a Cu-CeO2 catalyst, the Nb2O5 loading amount was systematically changed from 0 to 5 wt.%. Among the prepared catalysts, the Cu-Nb-CeO2 (1%) catalyst showed the highest catalytic activity (CO conversion=61% at 400℃) as well as 100% CO2 selectivity. The high activity and stability of Cu-Nb-CeO2 (1%) catalyst are correlated to high Brunauer-Emmett-Teller surface area, small metallic Cu crystallite size, and enhanced redox property.

Pharyngeal Airway Dimensions in Skeletal Class II Young Adolescents : Cephalometric Study (측모두부 방사선사진을 이용한 골격성 II급 부정교합 청소년의 성장 단계별 상기도부의 계측 분석)

  • Cheon, Minkyoung;Yang, Sunmi;Kim, Jaehwan;Kim, Seonmi;Choi, Namki
    • Journal of the korean academy of Pediatric Dentistry
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    • v.45 no.1
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    • pp.98-108
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    • 2018
  • This study aimed to evaluate the nasopharyngeal and oropharyngeal dimensions of the patients with skeletal class II division 1 or division 2 patterns during the pre-peak, peak, and post-peak growth periods for comparison with a skeletal class I control group (79 for pre-peak, 40 for peak, 40 for post-peak). Total 159 lateral cephalograms (70 for skeletal class I, 51 for skeletal class II, division 1, and 38 for skeletal class II, division 2) were selected. The growth of anteroposterior dimension of the pharyngeal airway were statistically significant among growth periods. The dimension for the nasopharyngeal and oropharyngeal airway space was the smallest in the division 1 skeletal class II group followed by class II division 2 and skeletal class I.

Catalytic Combustion of Soot Particulate over Perovskite-Type Oxides (폐롭스카이트형 촉매에서 입자상물질의 촉매연소반응)

  • Yang, Jin-Sup;Hong, Seong-Soo;Jung, Duck-Young;Oh, Kwang-Jung;Cho, Kyung-Mok;Ryu, Bong-Ki;Park, Dae-Won
    • Applied Chemistry for Engineering
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    • v.9 no.6
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    • pp.803-810
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    • 1998
  • We have studied the catalytic combustion of soot particulate over perovskite-type oxides prepared by malic acid method. The catalysts were modified to enhance the activity by substitution of metal into A or B site of perovskite oxide. In addition, the reaction conditions, such as temperature, $O_2$ concentration, space velocity have been studied. The effect of $SO_2$ pretreatment and water introduced into reactants were also examined. In the $LaCoO_3$ catalyst, the partial substitution of alkali metals into A site enhanced the catalytic activity in the combustion of soot particulate and the activity was shown in the order : Cs>K>Na; In the $La_{0.6}Cs_{0.4}CoO_3 $; catalyst, the substitution of Fe or Mn showed no effect on the ignition temperature. The ignition temperature decreased with increasing $O_2$ concentration and contact time. The introduction of water into reactants feed decreased the ignition temperature and the pretreatment of $SO_2$ showed no effect on the catalytic activity.

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The effects of ipriflavone on the periodontal reorganization following experimental tooth movement in the rat (Ipriflavone 투여가 백서의 실험적 치아이동 후 치주조직의 재형성에 미치는 영향)

  • Min, Ji-Hyun;Cho, Jin-Hyoung;Lee, Ki-Heon;Hwang, Hyeon-Shik
    • The korean journal of orthodontics
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    • v.38 no.5
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    • pp.347-357
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    • 2008
  • Objective: The purpose of this study was to examine the effect of ipriflavone on periodontal reorganization and prevention of relapse following tooth movement. Methods: Orthodontic rubber bands were inserted between the first and second maxillary molars of 27 white male rats for 3 weeks for experimental tooth movement. From one day before the removal of orthodontic rubber band, ipriflavone was administered 50 or 400 mg/kg daily in each experimental group whereas carboxymethyl cellulose solution was administered in the control group. They were sacrificed at the 5, 10, and 15th day from the day of removal of orthodontic rubber bands. The amount of relapse was evaluated by measuring the interdental space, and the extent of periodontal reorganization was compared through histological examination. Results: In case of ipriflavone administration, the amount and velocity of relapse was less and slower compared to the control group. In addition, the ipriflavone group showed more rapid periodontal reorganization compared to the control group. Conclusions: The results of the present study suggest that ipriflavone administration can be used effectively in the prevention of relapse following orthodontic tooth movement through the acceleration of periodontal reorganization.

A Study on Low-Temperature Oxidation Reactivity of Pt/ZrO2·SO42-Catalyst (ZrO2·SO42-에 담지된 백금촉매의 저온산화반응성에 대한 연구)

  • Kim, Kiseok;Lee, Tae Jung;Kim, Byoung Sam;Kim, Du Soung
    • Applied Chemistry for Engineering
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    • v.9 no.1
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    • pp.141-148
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    • 1998
  • Reactivity of Pt catalysts(0.2, 0.5 wt% Pt) supported on solid super acid, $ZrO_2$ $SO_4{^{2-}}$ for low-temperature oxidation was investigated for complete oxidation of cyclohexane. Catalytic activity measured as reactant conversion in a packed-bed tubular reactor increased in accordance with the acidity and specific surface area of the catalyst activity and specific surface area of $Pt/ZrO_2$ $SO_4{^{2-}}$ catalyst were diminished by adding potassium during catalyst preparation. the catalyst activity decreased in accordance with the amount of potassium added. In addition, $Pt/ZrO_2$ $SO_4{^{2-}}$ catalyst exhibited an activity greater than that of a $Pt/SiO_2$ or $Pt/Al_2O_3$ catalyst possessing much larger specific surface area at $250^{\circ}C$ for the reactant stream of 15.000 ppm cyclohexane concentration and $18,000hr^{-1}$ space velocity, a cyclohexane conversion as high as 96% was obtained over 0.2 wt% $Pt/ZrO_2$ $SO_4{^{2-}}$, whereas cyclohexane conversions over 0.2 wt% $Pt/SiO_2$ and 0.2 wt% $Pt/Al_2O_3$ were 83 and 79%, respectively.

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A Study on the Relation Characteristics between Bubble Size Distribution and Floating Time (버블의 크기별 입도분포와 부상시간과의 상관특성에 관한 연구)

  • Jeon, Gun;Park, Chul-Hwi
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.5
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    • pp.277-281
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    • 2017
  • Lately rainfall characteristics that it rains a lot in a short space of time often occurs. Because of this meteorological phenomena, the flow rate and concentration of initial rainfall for runoff and combined sewer overflows are changed. In the case of this inlet fluctuation, the flotation method at high surface loading rate is suitable for water quality management. the flotation method is able to meet the removal rate requirements of water public zone in 5 to 10 min which is irelatively short period. For assessment and diagonision of flotation method, A/S ratio is applied until now. But unfortunately, this has some limits for evaluation standard for certification and assessment of technical diagnosis and operation. This is why there is different efficiency in the bubble distribution at the same A/S ratio. The velocity and time of floating is changed by the different bubble distributions. The floating time affects the plant volume because the time factor make size dicision. Therefore the charateristics of bubble distribution and floating time at the same A/S ratio is necessary to apply to evaluation standard for certification and assessment of technical diagnosis and operation. For generalization of the method in certification and assessment, the characteristics of bubble distribution was studied. Until recently, using the optical device and shooting live video, there are some analysis technology of the floating factors. But this kind of technology is influenced by the equipment. with this level of confidence about the results, it is difficult to apply to generalize. According this reasons, this study should be applied on experiment generalization of method about measurement of relation between bubble distribution and floating time.

Carbon Dioxide Reforming of Methane over a Ni/KIT-1 Catalyst (Ni/KIT-1 촉매를 이용한 메탄의 이산화탄소 개질반응 연구)

  • Ryn, Seong-Yun;Ahn, Wha-Seung;Park, Sang-Eon
    • Applied Chemistry for Engineering
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    • v.9 no.7
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    • pp.1070-1078
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    • 1998
  • Thermodynamic analysis on carbon dioxide reforming of methane was performed using a computer program which can handle condensed species in the products, and the reforming experiments were conducted over $Al_2O_3$, $La_2O_3$, ZSM-5, MCM-41, KIT-1 supported nickel catalysts, and a commercial ICI 46-1. It was estabished that a system which consists of $CH_4$, $CO_2$, CO, $H_2$, $H_2O$, and C is appropriate for theoretical equilibrium calculations and addition of water vapor or oxygen was found to diminish the contribution of carbon dioxide in reforming. Silicate molecular sieve-supported catalysts such as Ni/ZSM-5, Ni/MCM-41, Ni/KIT-1 were effective for high $CH_4$ and $CO_2$ conversions as well as for high CO yield. Coke formation was suppressed when CaO was added as a promoter. Ni/Ca/KIT-1 which contains 10% Ni with 3% Ca showed conversion approaching equilibrium levels above $650^{\circ}C$ and maintained constant activity over 20 h. Despite increased space velocity, relatively high conversion and CO yield were observed.

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Reaction characteristics of hydrocarbon fuels under various operation conditions of hydro-upgrading process for vegetable oil-based bio-jet fuel production (식물성 오일 기반 바이오항공유 제조공정에서 수소첨가 업그레이딩을 위한 운전조건에 따른 탄화수소화합물의 특성)

  • Kwak, Yeonsu;Jang, Jung Hee;Kim, Sungtak;Ahn, Minhwei;Lee, Eun-Sil;Han, Gi Bo;Jeong, Byung Hun;Han, Jeong Sik;Jeon, Cheol-Hwan
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.3
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    • pp.731-743
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    • 2018
  • In bio-jet fuel production, selecting operating conditions of hydro-upgrading is of great importance to make iso-Paraffin rich hydrocarbons with carbon distribution including jet fuel range. Herein, iso-Paraffin rich biofuel including jet fuel range hydrocarbons ($C_8-C_{16}$) is produced from simultaneous cracking and isomerization using n-Paraffin rich hydrocarbon derived from hydrotreated vegetable oil over 0.5 wt..% Pt/Zeolite catalyst. We report and analyze the yields and compositions in the produced hydrocarbons affected by various operating conditions, such as reaction temperature, reaction pressure, molar ratio of reactants, and weight hourly space velocity. Aforementioned operating conditions not only can help interpret the reaction dynamics of hydro-upgrading, but also further produce bio jet-fuel after distillation.