• 제목/요약/키워드: Source-receptor

검색결과 195건 처리시간 0.023초

CCSEM을 이용한 대기 중 개별분진의 분류에 관한 연구 (Classification of Individual Ambient Particles by CCSEM)

  • 장여진;김동술
    • 한국대기환경학회지
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    • 제13권5호
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    • pp.345-353
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    • 1997
  • The purpose of the study was to stastically classify individual PM-10 measured by SEM/EDX (scanning electron microscopy/energy dispersive x-ray analyzer). The SEM/EDX provided various physical parameters like optical diameter, as well as major 18 chemical information (Mg, Al, Si, P, S, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Br, Pb) for a particle-by-particle basis. The total of 1,419 particles were analyzed for the study. Thus density and mass of each particle can be estimated based on its chemical composition. Further the study developed 4 semisource profiles including highway, oil boiler, incinerator, and soil emissions, where each sample was collected near the source in the ambient air The profiles developed were consisted of mass fractions and their uncertainties based on a particle class concept. To obtain mass fraction of each particle class, an agglomerative hierarchical cluster analysis was initially applied to create particle classes for each sample. Then uncertainties were calculated for each class based on the jacknife method. The 1,258 particles out of 1,419 (88.7%) were assorted in newly generated particle classes. The study provides opportunities to identify particle's source quantitatively and to develope various receptor models.

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대단위배출원에서 기인한 입자상오염물질의 확산ㆍ추적을 통한 ISCST3모델과 수용모델의 비교연구 (The Study on the Comparison of the ISCST3 Model and Receptor Model by Dispersion Tracing of Particulate Matter from Large Scale Pollution Sources)

  • 전상기;이성철;박경선
    • 한국대기환경학회지
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    • 제19권6호
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    • pp.789-803
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    • 2003
  • The purpose of this study is to compare the usefulness between Gaussian dispersion model and receptor model with the experimental result of the dispersion tracing of the particulate pollutants from Taean coal-fired power plants. For this purpose, the component analysis of the collected PM 10 samples was performed. In order to trace the pollution sources, factor analysis was done with the result of the component analysis. As a result of the correlativity analysis of the fifteen power plants' profiles offered by US EPA, the correlativity of No.11202 source profile showed highest rate up to 84.5%. Thus it was adopted as proper one and the contribution rate by each pollution source was calculated by Chemical Mass Balance (CMB)-8 model. The contribution rate, which was the effect rate of the power plants on each measuring point, were calculated with a range of 24∼52% and the standard error was below 0.9 $\mu\textrm{g}$/㎥. This indicates the selection of the source profile was appropriate. Also, the concentrations of each point were calculated by the ISCST3 which is suggested by US EPA as one of the regulatory Gaussian dispersion model. The calculation result showed that the predicted concentration was 50∼58 $\mu\textrm{g}$/㎥, comparing with the measured result of 9∼65 $\mu\textrm{g}$/㎥. It was found that the concentration calculated by ISCST3 was underpredicted. It was thought that the receptor model was more favorable than the Gaussian dispersion model in estimating the effect of the particulate matter on a certain receptive point.

배출원-수용지 관계와 위성 관측자료를 이용한 배출량 개선 방법에 대한 연구 (Study of the Emission Correcting Methods Using Source-receptor Relationship and Satellite Observing Data)

  • 최원준;정부전
    • 한국콘텐츠학회논문지
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    • 제19권3호
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    • pp.485-493
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    • 2019
  • 원격탐사 기술 발달로 대기 중 미량기체 농도 측정이 가능하게 됨에 따라 환경부는 1,525여억원을 투입하여 정지궤도 환경위성과 운영 기반을 구축하고 있다. 또한, 막대한 비용이 투입되는 환경위성의 편익을 높이기 위해 활용을 위한 다양한 콘텐츠를 개발하고 있다. 본 연구는 위성 활용을 위한 배출량 정확도 개선 연구로, 현재 상향식 방식으로 산정되고 있는 배출량을 위성에서 관측된 자료를 이용하여 하향식 방식으로 정확도를 개선하는 연구를 수행하였다. $NO_2$ 배출량 개선을 위해 두 가지 방법론을 분석하였으며, 하나는 $NO_2$의 이동을 고려하지 않은 방법(method-1), 다른 하나는 $NO_2$의 이동 영향을 반영하기 위해 배출원-수용지 관계식을 도입(method-2)한 방법으로 상호 결과를 비교하였다. 해당 방법론은 본 연구에서 대상물질인 $NO_2$ 뿐만 아니라 위성에서 관측되는 대기오염물질 전부에 적용 가능할 것으로 판단된다.

두부 측 방향 방사선검사 시 선원 영상수용체간 거리와 검사 자세 변화가 선량과 영상품질에 미치는 영향 (Assessment of Dose and Image Quality according to the Change of Distance from Source to Image Receptor and the Examination Posture during the Skull Lateral Radiography)

  • 김은혜;주영철;김한용;김동환
    • 대한방사선기술학회지:방사선기술과학
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    • 제45권6호
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    • pp.483-489
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    • 2022
  • This study proposes a new skull lateral examination, and provides an improved examination environment for patients and radiologists. The study was divided into three groups. One group was divided into the SID (source to image receptor distance) 110 ㎝ and 180 ㎝ in the skull lateral posture, the other group The other group was divided into an position in contact with the detector and an position without contact with the detector, and the other group was divided into male and female groups, considering that the difference in shoulder width between adult males and females would affect the dose and image quality. For dose evaluation, the ESD (entrance surface dose) was measured at the EAM (external auditory meatus), and the conditions were applied equally at 70 ㎸p, 200 ㎃, and 10 ㎃s. For image quality evaluation, SNR (signal to noise ratio) and CNR (contrast to noise ratio) were measured in frontal sinus, EAM, and sella turcica. As a result of ESD comparison, when sid 110 ㎝ to sid 180 ㎝ was changed among the three groups, ESD values decreased the most to 729.18±4.62 μ㏉ and 224.18±0.74 μ㏉ at 180 ㎝ (p<0.01). The values of SNR and CNR were statistically significant (p<0.01), but there was no qualitative difference. This shows that when the SID is 180 ㎝, it is possible to reduce the dose without lowering the image quality. So, It is suggested that the SID 180 ㎝ is used without contacting the detector when examining the skull lateral.

Source Identification and Quantification of Coarse and Fine Particles by TTFA and PMF

  • Hwang, In-Jo;Bong, Choon-Keun;Lee, Tae-Jung;Kim, Dong-Sool
    • Journal of Korean Society for Atmospheric Environment
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    • 제18권E4호
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    • pp.203-213
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    • 2002
  • Receptor modeling is one of statistical methods to achieve reasonable air pollution strategies. In order to maintain and manage ambient air quality, it is necessary to identify sources and to apportion its sources for ambient particulate matters. The main purpose of the study was to survey seasonal trends of inorganic elements in the coarse and fine particles. Second, this study has attempted emission sources qualitatively by a receptor method, the PMF mo-del. After that. both PMF (positive matrix factorization) model and TTFA (target transformation factor analysis) model were applied to compare and to estimate mass contribution of coarse and fine particle sources at the receptor. A total of 138 sets of samples was collected from 1989 to 1996 by a low volume cascade impactor with 9 size fraction stages at Kyung Hee University in Korea. Sixteen chemical species (Si, Ca, Fe, K, Pb, Na, Zn, Mg, Ba, Ni, V, Mn, Cr, Br, Cu. Co) were characterized by XRF. The study result showed that the weighted arithmetic mean of coarse and fine particles were 51.3 and 54.4 $\mu\textrm{g}$/㎥, respectively. Contribution of both particle fractions were esti-mated using TTFA and PMF models. The number of estimated sources was seven according to TTFA model and 8 according to PMF model. Comparison of TTFA and PMF revealed that both methodologies exhibited similar trends in their contribution pattern. However, large differences between contributions were observed in some sour-ces. The results of this study may help to suggest control strategies in local countries where known source profiles do not exist.

수도권지역에서의 권역간 대기오염물질 상호영향 연구 (A Regional Source-Receptor Analysis for Air Pollutants in Seoul Metropolitan Area)

  • 이용미;홍성철;유철;김정수;홍지형;박일수
    • 한국환경과학회지
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    • 제19권5호
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    • pp.591-605
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    • 2010
  • This study were to simulate major criteria air pollutants and estimate regional source-receptor relationship using air quality prediction model (TAPM ; The Air Pollution Model) in the Seoul Metropolitan area. Source-receptor relationship was estimated by contribution of each region to other regions and region itself through dividing the Seoul metropolitan area into five regions. According to administrative boundary, region I and region II were Seoul and Incheon in order. Gyeonggi was divided into three regions by directions like southern(region III), northern(IV) and eastern(V) area. Gridded emissions ($1km{\times}1km$) by Clean Air Pollicy Support System (CAPSS) of National Institute of Environmental Research (NIER) was prepared for TAPM simulation. The operational weather prediction system, Regional Data Assimilation and Prediction System (RDAPS) operated by the Korean Meteorology Administration (KMA) was used for the regional weather forecasting with 30km grid resolution. Modeling period was 5 continuous days for each season with non-precipitation. The results showed that region I was the most air-polluted area and it was 3~4 times more polluted region than other regions for $NO_2$, $SO_2$ and PM10. Contributions of $SO_2$ $NO_2$ and PM10 to region I, II and III were more than 50 percent for their own sources. However region IV and V were mostly affected by sources of region I, II and III. When emissions of all regions were assumed to reduce 10 and 20 percent separately, air pollution of each region was reduced linearly and the contributions of reduction scenario were similar to those of base case. As input emissions were reduced according to different ratio - region I 40 percent, region II and III 20 percent, region IV and V 10 percent, air pollutions of region I and III were decreased remarkably. The contributions to region I, II, III were also reduced for their own sources. However, region I, II and III affected more regions IV and V. Shortly, graded reduction of emission could be more effective to control air pollution in emission imbalanced area.

Identification of Source Locations for Atmospheric Dry Deposition of Heavy Metals during Yellow-Sand Events in Seoul, Korea in 1998 Using Hybrid Receptor Models

  • Han, Young-Ji;Holsen, Thomas M.;Hopke, Philip K.;Cheong, Jang-Pyo;Kim, Ho;Yi, Seung-Muk
    • 한국환경보건학회:학술대회논문집
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    • 한국환경보건학회 2004년도 International Conference Global Environmental Problems and their Health Consequences
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    • pp.92-106
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    • 2004
  • Elemental dry deposition fluxes were measured using dry deposition plates from March to June 1998 in Seoul, Korea. During this spring sampling period several yellow sand events characterized by long-range transport from China and Mongolia impacted the area. Understanding the impact of yellow-sand events on atmospheric dry deposition is critical to managing the heavy metal levels in the environment in Korea. In this study, the measured flux of a primarily crustal metal, Al and an anthropogenic metal, Pb was used with two hybrid receptor models, potential source contribution function (PSCF) and residence time weighted concentration (RTWC) for locating sources of heavy metals associated with atmospheric dry deposition fluxes during the yellow-sand events in Seoul, Korea. The PSCF using a criterion value of the 75th percentile of the measured dry deposition fluxes and RTWC results using the measured elemental dry deposition fluxes agreed well and consistently showed that there were large potential source areas in the Gobi Desert in China and Mongolia and industrial areas near Tianjin, Tangshan, and Shenyang in China. Major industrial areas of Shenyang, Fushun, and Anshan, the Central China loess plateau, the Gobi Desert, and the Alaskan semi-desert in China were identified to be major source areas for the measured Pb flux in Seoul, Korea. For Al, the main industrial areas of Tangshan, Tianjin and Beijing, the Gobi Desert, the Alashan semi-desert, and the Central China loess plateau were found to be the major source areas. These results indicate that both anthropogenic sources such as industrial areas and natural sources such as deserts contribute to the high dry deposition fluxes of both Pb and Al in Seoul, Korea during yellow-sand events. RTWC resolved several high potential source areas. Modeling results indicated that the long-range transport of Al and Pb from China during yellow-sand events as well as non yellow-sand spring daytimes increased atmospheric dry deposition of heavy metals in Korea.

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소염제로서의 살리씰산유도체의 구조-활성 상관관계에 관한 양자화학적 해석 (Quantum Chemical Analysis of Structure-Activity Relationships in Salicylic Acids as Anti-inflammatory Drugs)

  • 이종달;구본기
    • 약학회지
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    • 제33권2호
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    • pp.87-100
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    • 1989
  • Salicylic acids as anti-inflammatory agents were analyzed by ab initio, quantum chemical methods to study the possible modes of binding to the receptor. As the result of multiple regression analysis of reactivity indices and interpretation of normalized frontier orbital charges of drugs, potency seems to be related to energy of HOMO and LUMO at the 5 position of benzene ring, and in the 5-phenyl substituted case, the para position of substituting ring is important. The binding occurs first at the positive site of its receptor. The charge density exhibited by the frontier orbitals suggests that charge moves from receptor site to carboxyl group. The electrostatic orientation effect makes an important contribution to the binding of the active molecules to their receptors. Also the electrostatic potential model may be able to rationalize the source of activity or inactivity of the drugs under investigation.

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PMF 모델을 이용한 용인-수원경계지역에서의 부유분진의 크기별 오염원 확인 (Source Identification of Ambient Size-by-Size Particulate Using the Positive Matrix Factorization Model on the Border of Yongin and Suwon)

  • 오미석;이태정;김동술
    • 한국대기환경학회지
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    • 제25권2호
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    • pp.108-121
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    • 2009
  • The suspended particulate matters have been collected on membrane filters and glass fiber filters by an 8-stage cascade impactor for 2 years (Sep. 2005${\sim}$Sep. 2007) in Kyung Hee University-Global Campus located on the border of Yongin and Suwon. The 20 chemical species (Al, Mn, Si, Fe, Cu, Pb, Cr, Ni, V, Cd, Ba, $Na^+$, ${NH_4}^+$, $K^+$, $Mg^{2+}$, $Ca^{2+}$, $Cl^-$, ${NO_3}^-$, and ${SO_4}^{2-}$) were analyzed by an ICP-AES and an IC after performing proper pre-treatments of each sample filter. Based on these chemical information, the PMF receptor model was applied to identify the source of ambient size-by-size particulate matters. The receptor modeling is the one of the statistical methods to achieve resonable air pollution management strategies. A total of 10 sources was identified in 9 size-ranges such as long-range transport, secondary aerosol, $NH_{4}NO_{3}$ related source, coal combustion, sea-salt, soil, oil combustion, auto emission, incineration, and biomass burning. Especially, the secondary aerosol source assorted in fine and coarse modes was intensively studied.

PMF 모델을 이용한 경산지역 PM2.5의 오염원 기여도 추정 (Source Apportionment of PM2.5 in Gyeongsan Using the PMF Model)

  • 정영진;황인조
    • 한국대기환경학회지
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    • 제31권6호
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    • pp.508-519
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    • 2015
  • The objective of this study was to quantitatively estimate $PM_{2.5}$ source contribution in Gyeongsan. Ambient $PM_{2.5}$ samples have been collected on zefluor, quartz and nylasorb filter by $PM_{2.5}$ samplers of cyclone method from September 2010 to December 2012. Collected samples were analyzed for determining 17 inorganic elements, 8 ions, and 8 carbon components after pretreatment. Based on these chemical information, the PMF model was applied to estimate the quantitative contribution of air pollution sources. The results of the PMF modeling showed that the sources were apportioned by biomass burning source (15.5%), secondary sulfate source (16.0%), industry source (10.4%), soil source (7.0%), gasoline source (9.1%), incinerator source (10.4%), diesel emission source (11.0%), and secondary nitrate source (20.6%), respectively. To analyze local source impacts from various wind directions, the CPF analysis were performed using source contribution results with the wind direction values measured at the site.