• Korean Chemical Engineering Research
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• 제47권3호
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• pp.373-379
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• 2009

고정층 반응기에서 cesium carbonate 흡착제를 사용하여 이산화탄소($CO_2$), 질소 및 수분의 혼합기체로부터 $CO_2$를 수착하여 $CO_2$-cesium carbonate의 반응속도론을 구하기 위하여 $CO_2$의 파과곡선을 측정하였다. 비촉매 불균일반응계에서 반응속도론을 해석하기 위하여 $CO_2$의 파과곡선을 사용하여 비활성화 모델로부터 반응속도론을 구하고 $CO_2$의 파과곡선의 비선형해석으로부터 비활성화 모델에서 수착속도상수와 비활성속도상수를 구하였다.

• Advances in environmental research
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• 제1권2호
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• pp.167-179
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• 2012

Pistachio shell (Pistacia vera) (PS), a low-cost material, has been utilized for the removal of the Cr(VI) ions after treatment with citric acid. Batch experimental steps were applied to obtain Cr(VI) ion adsorption details for the equilibrium between Cr(VI) and modified pistachio shell (MPS). The influences of contact time, pH, adsorbent dose and initial chromium concentration on the adsorption performance of MPS was investigated in detail. The results displayed that adsorption of Cr(VI) by MPS reached to equilibrium after 2 h and after that a little change of Cr(VI) removal efficiency was observed. The sorption percent is higher at lower pH and lower chromium concentration. Two possible mechanisms for reduction of Cr(VI) to Cr(III) can be suggested in Cr(VI) removal. In the first mechanism, Cr(VI) is reduced to Cr(III) by surface electron-donor groups of the adsorbent and the reduced Cr(III) forms complexes with adsorbent or remains in the solution. This Cr(III) is not adsorbed by adsorbent at pH 1.8. But in second mechanism, the adsorption-coupled reduction of Cr(VI) to Cr(III) occurred on the adsorbent sites. The equilibrium sorption capacity of Cr(VI) ion after 2 h was 64.35 mg/g for MPS.

• 상하수도학회지
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• 제21권1호
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• pp.27-36
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• 2007

Milled Korean pine (Pinus densiflora) wood was used to evaluate its adsorption capacity of Cu(II) ions from aqueous solution by running a series of batch experiments. Prior to the tests, the milled woods were pretreated with 1N NaOH, 1N $NHO_3$, and distilled water, respectively, to examine the effect of pretreatment. Within the tested pH range in this study between 3 and 6, copper adsorption efficiency of NaOH-treated wood(96~99%) was superior than $NHO_3$-treated wood(19~31%) and distilled water-treated wood(18~35%). Adsorption behavior of copper onto both raw and $NHO_3$-treated woods was mainly attributed to interaction with carboxylic acid group. For NaOH-treated wood, carboxylate ion produced by hydrolysis was a major functional group responsible for Cu sorption. NaOH treatment of wood changed the ester and carboxylic acid groups into carboxylate group, whereas $NHO_3$ treatment did not affect the production of functional groups which could bind copper. A pseudo second-order kinetic model fitted well for the sorption of copper ion onto NaOH-treated wood. A batch isotherm test using NaOH-treated wood showed that equilibrium sorption data were better represented by the Langmuir model than the Freundlich model.

• 상하수도학회지
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• 제23권1호
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• pp.113-119
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• 2009

The feasibility of using cork oak bark for phosphorus removal from wastewater was evaluated in this study. Recently, development of more cost-effective media while maintaining high efficiency in pollutants removal has received concern. Barks have a negative surface charge and, hence, tend to show a high affinity to bind cations, and they need to undergo chemical modification to increase their adsorption capacity of anions. Bark was hydrolyzed by HCl solution and it received modification using an aqueous solution of high molecular weight polyethylenimine(PEI). Surface modification with HCl and PEI resulted in a decrease of specific surface area of the bark from $1.932 m^2/g$ to $1.094 m^2/g$. The adsorption experiments were carried out in batch tests and the data were fitted to the Langmuir isotherm and Freundlich isotherm equations. Phosphate removal rate was higher at the lower solution pH possibly due to the form of phosphate ion in solution. For the initial phosphate concentration of 10 mg/L, maximum adsorption was 20.88 mg P/g at pH 3 and 12.02 mg P/g at pH 5. Mechanism of phosphorus sorption onto the HCl-PEI bark was examined through FT-IR spectrometer. Ion exchange between $NH^+$ and $H_2PO_4{^-}$ appeared to be a key mechanism of phosphate adsorption onto the HCl-PEI bark surface.

• 한국토양비료학회지
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• 제41권6호
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• pp.369-373
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• 2008

Mg-Al LDH를 이용하여 수용액중 비소와의 반응특성을 규명하고 비소 제거제로서 활용가능성을 규명하기 위하여 비소의 흡착특성, 제거효율 및 제거기작에 대한 조사를 하였다. Mg-Al LDH는 소성(calcination)에 의한 탈수로 Mg oxide 형태를 나타내었고 비소를 흡착시킨 결과 반응 22시간 이후에 흡착평형에 도달하였으며 흡착량은 약 530 mmol/kg정도였다. 반응농도별 LDH의 등온흡착은 L-type의 흡착반응을 나타내었다. 소성된 Mg-Al LDH는 용액중에서 재수화(rehydration) 될 때 비소가 LDH의 구조의 복구과정(reconstruction)에서 이온교환 반응에 의해 층간삽입이 일어나는 것으로 나타났다. LDH에 대한 arsenate와 phosphate, arsenate와 sulfate의 경쟁흡착 결과 arsenate와 phosphate의 선택성은 비슷한 편이었고, arsenate는 sulfate에 비해 선택성이 우수하였다. 따라서 calcined Mg-Al LDH는 비교적 높은 비소 제거효율을 나타내므로 비소 제거제로서 사용 가능성이 매우 높은 것으로 판단된다.

• 한국수산과학회지
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• 제34권5호
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• pp.521-525
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• 2001

국내에서 다량 생산되는 갈조류인 미역포자엽, 다시마, 톳, 모자반으로부터 fucoidan을 추출, 분획하여 Pb와 Cd의 흡착 특성을 조사하였다. 4종의 갈조류에서 추출한 fucoidan의 분획물 모두 Pb의 흡착량이 Cd보다 높았으며, 시료간에는 미역포자엽 분획물 (Fr-3.0)이 Pb와 Cd 모두 흡착력이 상대적으로 우수하였다. pH와 농도 변화에 따른 홉착력의 변화는 $C_f$ (잔류농도)가 50mg/L까지는 pH 간 차이가 없었으나, 농로가 증가함에 따라 pH 5.5 처리구가 다른 처리구에 비하여 흡착량이 증가하였다. 실험을 통하여 얻은 Pb 와 Cd의 최대 흡착량은 pH 5.5에서 각각 94mg/g ($C_f$164mg/L), 64mg/g ($C_f$197mg/L)였으며 Langmuir sorption model을 통해 구한 최대 흡착량은 pH 5.5에서 각각 178mg/g, 122mg/g이었다. Cd 공존시 Pb 흘착량은 $C_f$가 낮을 범위에서는 변화가 없었으나 $C_f$가 증가함에 따라 공존 이온의 흡착 방해로 인하여 감소하였다.

• 한국식품과학회지
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• 제17권2호
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• pp.101-106
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• 1985

콩우유 비지를 acetone과 ethyl alcohol로 세척한뒤 $60^{\circ}C$에서 건조시킨 건조비지의 흡습특성(吸濕特性)과 건조비지를 밀가루에 혼합하였을때 수분함량과 수분활성도 간의 관계를 밝히고져 본 연구를 시행하였다. 건조비지는 상대습도(相對濕度)(RH)별(別)로 $20^{\circ}C$에서 저장중 평형 수분함량에 도달하기 전에 과흡습(過吸濕) 경향을 보였으며 저장중의 흡습농도(吸濕溫度)는 모든 RH에서 높은 상관계수를 갖는 log(dw/dt)=b log t+log a의 관계식으로 계산이 가능하였다. 또한 건조비지를 밀가루와 혼합하였을때 등온흡습곡선(等溫吸濕曲線)으로부터 얻어지는 수분함량(Mi)과 수분활성도(Aw)간의 관계는 Mi=b Aw+ a의 직선 관계식을 보여 주었다. 이 식(式)을 타연구자(他硏究者)들이 제안한 식(式)들과 비교할때 실측치(實測値)에 더 유사한 계산값을 보여 본 연구에서 제안한 식(式)이 건조 비지와 밀가루의 혼합물(混合物)에는 적합(適合)한 관계식이라 할 수 있었다.

• Nuclear Engineering and Technology
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• 제54권2호
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• pp.627-636
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• 2022

In nuclear power plants and other nuclear facilities the removal of cobalt from radioactive liquid waste is needed to reduce the radioactivity concentration in effluents. In liquid wastes containing strong organic complexing agents such as EDTA cobalt removal can be problematic due to the high stability of the Co-EDTA complex. In this study, the removal of cobalt from NaNO₃ solutions using antimony oxide (Sb₂O₃) synthesized from potassium hexahydroxoantimonate was investigated in the absence and presence of EDTA. The uptake studies on the ion exchange material were conducted both in the dark (absence of UV-light) and under UV-C irradiation. Ca²⁺ or Ni²⁺ were included in the experiments as competing cations to test the selectivity of the ion exchanger. Results show that UV-C irradiation noticeably enhances the cobalt sorption efficiency on the antimony oxide. It was shown that nickel decreased the sorption of cobalt to a higher extent than calcium. Finally, the sorption data collected for Co²⁺ on antimony oxide was modeled using six different isotherm models. The Sips model was found to be the most suitable model to describe the sorption process. The Dubinin-Radushkevich model was further used to calculate the adsorption energy, which was found to be 6.2 kJ mol^-1.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1992년도 봄 학술발표회 논문집
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• pp.13-18
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• 1992

Moisture movement which is controlled by water potential and permeability of concrete is a very important phenomenon which affects the shrinkage of concrete. Thermocouple psychrometer were used to measure the moisture potentials in concrete. Based on the measured moisture potentials, three method have been proposed to calculate hycraulic conductivity and diffusivity. And also the hystresis of sorption isotherm due to drying and wetting cycle has been crawn.

• Applied Biological Chemistry
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• 제33권1호
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• pp.14-17
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• 1990

7개 품종의 콩(팔달, 단엽, 장백, 백운, 장엽, Local 1, Local 2)에 대한 흡습특성이 온도, 상대습도를 달리한 조건에서 조사되었다. 이들 콩의 평형상대습도는 $4^{\circ}C$가 $25^{\circ}C$보다 전반적으로 높았으며 탈습은$4^{\circ}C$에서는 RH 44 % 이하에서, $25^{\circ}C$에서는 RH 52 % 이하에서 일어났다. 또한 흡습은 $25^{\circ}C$에서는 RH 80% 이하에서 저장 10일에 평형수분함량에 도달하였으나 $4^{\circ}C$에서는 RH 73 % 이상에서 부터 저장 10일 후 계속 수분함량이 증가하였다. $4^{\circ}C$에서 팔달의 평형수분함량이 높게 나타났으며 $25^{\circ}C$에서는 백운의 평형 수분함량이 비교적 높게 나타났다. 저장시간별 수분함량의 변화속도를 log(dw/dt)=b log(t)+log a의 식을 이용하여 예측한 결과 저장시간이 증가함에 따라 (dw/dt)${\times}10^3$의 값은 대수함수적으로 감소하였으며 상대 습도가 높아지면서 -b 값은 낮아졌다. 초기흡습속도는 상대습도가 증가할수록 높아졌으며 시료품종중 팔달의 값이 비교적 가장 높았다.