• Title/Summary/Keyword: Solution-process

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Efficient Selective Recovery of Lithium from Waste LiFePO4 Cathode Materials using Low Concentration Sulfuric Solution and 2-step Leaching Method (저농도 황산 용액 및 2-스텝 침출 방법을 이용한 폐LiFePO4 양극재로부터 효율적인 리튬의 선택적 회수)

  • Dae-Weon Kim;Hee-Seon Kim
    • Clean Technology
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    • v.29 no.2
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    • pp.87-94
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    • 2023
  • The recovery of valuable metals from waste lithium-based secondary batteries is very important in terms of efficiently utilizing earth's limited number of resources. Currently, the cathode material of a LiFePO4 battery, a type of battery which is widely used in automobiles, contains approximately 5% lithium. After use, the lithium in these batteries can be used again as a raw material for new batteries through lithium recycling. In this study, low-concentration sulfuric acid, a commonly used type of inorganic acid, was used to selectively leach the lithium contained in a waste LiFePO4 cathode material powder. In addition, in order to compare and analyze the leaching efficiency and separation efficiency of each component, the optimalleaching conditions were derived by applying a two-step leaching process with pulp density being used as a variable during leaching. When leaching with pulp density as a variable, it was confirmed that at a pulp density of 200 g/L, the separation efficiency was approximately 200 times higher than at other pulp densities because the iron and phosphorus components were hardly leached at this pulp density. Accordingly, the pulp density of 200 g/L was used tooptimize the leaching conditions for the selective leaching and recovery of lithium.

Propagation Analysis of Dam Break Wave using Approximate Riemann solver (Riemann 해법을 이용한 댐 붕괴파의 전파 해석)

  • Kim, Byung Hyun;Han, Kun Yeon;Ahn, Ki Hong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.5B
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    • pp.429-439
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    • 2009
  • When Catastrophic extreme flood occurs due to dam break, the response time for flood warning is much shorter than for natural floods. Numerical models can be powerful tools to predict behaviors in flood wave propagation and to provide the information about the flooded area, wave front arrival time and water depth and so on. But flood wave propagation due to dam break can be a process of difficult mathematical characterization since the flood wave includes discontinuous flow and dry bed propagation. Nevertheless, a lot of numerical models using finite volume method have been recently developed to simulate flood inundation due to dam break. As Finite volume methods are based on the integral form of the conservation equations, finite volume model can easily capture discontinuous flows and shock wave. In this study the numerical model using Riemann approximate solvers and finite volume method applied to the conservative form for two-dimensional shallow water equation was developed. The MUSCL scheme with surface gradient method for reconstruction of conservation variables in continuity and momentum equations is used in the predictor-corrector procedure and the scheme is second order accurate both in space and time. The developed finite volume model is applied to 2D partial dam break flows and dam break flows with triangular bump and validated by comparing numerical solution with laboratory measurements data and other researcher's data.

A Servicism Model of the New Society and Education System (서비스주의 사회교육시스템의 구조와 운용 연구)

  • Hyunsoo Kim
    • Journal of Service Research and Studies
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    • v.11 no.3
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    • pp.75-97
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    • 2021
  • This study was conducted to derive a society and education system model that will improve the happiness and sustainability of human society. An ideological model for making human society a happy society was derived, and a society and education system structure and operation model based on this was presented. A fair society, a justice society, a mutually considerate society, and a society where individuals are happy are the conditions for a sustainable society. After analyzing the current situation of freedom and equality pursued by capitalism and democracy, which are currently adopted by most societies, an improvement model was derived from the perspective of a sustainable society. The cost of freedom and equality were analyzed and a new alternative system was discussed. The social solidarity and class mobility issues were discussed together and servicism was derived as an alternative solution. It is a system in which two opposing opponents of individual freedom and social norms form a symmetrical balance, and material and spiritual values are balanced. Servicism is a dynamic balance model. That is, the dimensions of time and space are involved. It is a model that maintains a thorough balance through a dialectical process as time and space change, and one value can dominate the other at a specific time or space. The service-oriented society and education system is a system that simultaneously pursues the goals of individual happiness and sustainable development of the social community.

Driver Route Choice Models for Developing Real-Time VMS Operation Strategies (VMS 실시간 운영전략 구축을 위한 운전자 경로선택모형)

  • Kim, SukHee;Choi, Keechoo;Yu, JeongWhon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.3D
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    • pp.409-416
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    • 2006
  • Real-time traveler information disseminated through Variable Message Signs (VMS) is known to have effects on driver route choice decisions. In the past, many studies have attempted to optimize the system performance using VMS message content as the primary control variable of driver route choice. This research proposes a VMS information provision optimization model which searches the best combination of VMS message contents and display sequence to minimize the total travel time on a highway network considered. The driver route choice models under VMS information provision are developed using a stated preference (SP) survey data in order to realistically capture driver response behavior. The genetic algorithm (GA) is used to find the optimal VMS information provision strategies which consists of the VMS message contents and the sequence of message display. In the process of the GA module, the system performance is measured using micro traffic simulation. The experiment results highlight the capability of the proposed model to search the optimal solution in an efficient way. The results show that the traveler information conveyed via VMS can reduce the total travel time on a highway network. They also suggest that as the frequency of VMS message update gets shorter, a smaller number of VMS message contents performs better to reduce the total travel time, all other things being equal.

The Study of Digitalization of Analog Gauge using Image Processing (이미지 처리를 이용한 아날로그 게이지 디지털화에 관한 연구)

  • Seon-Deok Kim;Cherl-O Bae;Kyung-Min Park;Jae-Hoon Jee
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.29 no.4
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    • pp.389-394
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    • 2023
  • In recent years, use of machine automation is rising in the industry. Ships also obtain machine condition information from sensor as digital information. However, on ships, crew members regularly surveil the engine room to check the condition of equipment and their information through analog gauges. This is a time-consuming and tedious process and poses safety risks to the crew while on surveillance. To address this, engine room surveillance using an autonomous mobile robot is being actively explored as a solution because it can reduce time, costs, and the safety risks for crew. Analog gauge reading using an autonomous mobile robot requires digitization for the robot to recognize the gauge value. In this study, image processing techniques were applied to achieve this. Analog gauge images were subjected to image preprocessing to remove noise and highlight their features. The center point, indicator point, minimum value and maximum value of the analog gauge were detected through image processing. Through the straight line connecting these points, the angle from the minimum value to the maximum value and the angle from the minimum value to indicator point were obtained. The obtained angle is digitized as the value currently indicated by the analog gauge through a formula. It was confirmed from the experiments that the digitization of the analog gauge using image processing was successful, indicating the equivalent current value shown by the gauge. When applied to surveillance robots, this algorithm can minimize safety risks and time and opportunity costs of crew members for engine room surveillance.

A Study on the Solution of Product Particle Attachment Problem using Practical TRIZ (실용 트리즈를 활용한 제품 Particle 부착 문제의 해결 방안 연구)

  • Kyu-Han Jeong;In-Kwang Song;Jang-Hee Lee
    • Journal of Practical Engineering Education
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    • v.15 no.1
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    • pp.209-221
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    • 2023
  • In the external inspection and packaging stages of products used in the semiconductor manufacturing process, there is a problem in which particles are adsorbed to the product itself or a carrying tool due to electrostatic discharge. This study presents a methodology that can improve the problem of adsorption of particles to a product by using a practical TRIZ technique. By applying the proposed practical TRIZ-based methodology, the problem was defined, and contradictions caused by product waiting time were derived. Among the derived contradictions, physical contradictions were set and the concept of 'space separation' was applied to derive solutions such as 'installation of Ionizer' and 'improvement of the layout of the workroom'. As a result of the experiment by applying 'Ionizer Installation' and 'Workroom Layout Improvement' derived through the application of practical TRIZ, it was confirmed that the particle adsorption problem that occurs during the waiting time of the product can be solved.Through this study, it is expected that workers, facility engineers, and technical engineers working at manufacturing processes will be able to effectively solve the problems they face through creative thinking and change of ideas by using practical TRIZ techniques, and contribute to innovative technology development and productivity improvement.

Dimensional Stability and Mechanical Properties of Citric Acid Impregnated Samama Wood (Anthocephalus macrophyllus (Roxb) Havil) at High Curing Temperatures

  • Sarah AUGUSTINA;Sari Delviana MARBUN;SUDARMANTO;NARTO;Deazy Rachmi TRISATYA;Eko Budi SANTOSO;Dhimas PRAMADANI;Nanda Nur AFNI;Tushliha Ayyuni FARIHA;Gabriel Wiwinda L. TOBING;Wasrin SYAFI'I;Tekat Dwi CAHYONO;Eka NOVRIYANTI;Muhammad BULA;Adik BAHANAWAN;Prabu Satria SEJATI;Nam Hun KIM;Wahyu DWIANTO;Philippe GERARDIN
    • Journal of the Korean Wood Science and Technology
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    • v.51 no.6
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    • pp.431-446
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    • 2023
  • Samama wood (Anthocephalus macrophyllus (Roxb) Havil) is a fast-growing and lesser-utilized wood species that has inferior properties; therefore, its quality needs to be improved. This research aimed to determine the effect of citric acid impregnation at high curing temperatures on the dimensional stability and mechanical properties of wood. Citric acid solution with 10% concentration (w/w) was impregnated into wood samples by vacuum-pressure method (-0.5 cmHg, 30 min; 0.7 MPa, 3 h), followed by curing process at 140℃, 160℃, and 180℃ of temperature for 1 h. In comparison, the other wood samples were heat treated at the same temperatures and time. The results showed that the increase in curing and heat temperatures for both treatments were directly proportional to the dimensional stability, but inversely proportional to the mechanical properties. Citric acid impregnated had higher density, dimensional stability, and mechanical properties, except for modulus of rupture, than that of heat treatment. The optimum temperature is suggested at 160℃ in both treatments.

Study on Changes in Vessel Traffic Services Due to Introduction of Maritime Autonomous Surface Ships (자율운항선박 도입에 따른 선박교통관제 업무 변화에 관한 연구)

  • Dae-won Kim;Myeong-ki Lee;Sang-won Park;Young-soo Park
    • Journal of Navigation and Port Research
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    • v.47 no.6
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    • pp.430-436
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    • 2023
  • Study on Changes in Vessel Traffic Services Due to Introduction of Maritime Autonomous Surface ShipsThe development of technologies related to Maritime Autonomous Surface Ships (MASS) has been actively progressing since the mid-2010s, focusing on themes such as collision avoidance, route planning, digital twin, and communication technologies. On the other hand, research on land-based infrastructure connected with MASS, such as logistics systems, port facilities, and vessel traffic services, has relatively received less attention. This study analyzed impact of emergence of MASS on existing vessel traffic service operations and proposed changes in control operations to prepare for its impact. To do this, current vessel traffic service operations were analyzed and elements of MASS technology that could affect vessel traffic control were identified. A survey was conducted among vessel traffic controllers to identify items related to the control of MASS. Results analyzed using the AHP method showed that preparation for emergency response and communication methods with MASS were the most important. Based on this, we were able to derive detailed plans for basic MASS control procedures and emergency response procedures based on data communication within maritime traffic control areas. MASS control procedures proposed in this study are expected to be used as a solution to resolve issues related to traffic safety of MASS in coastal areas.

A Study on the User-Based Small Fishing Boat Collision Alarm Classification Model Using Semi-supervised Learning (준지도 학습을 활용한 사용자 기반 소형 어선 충돌 경보 분류모델에대한 연구)

  • Ho-June Seok;Seung Sim;Jeong-Hun Woo;Jun-Rae Cho;Jaeyong Jung;DeukJae Cho;Jong-Hwa Baek
    • Journal of Navigation and Port Research
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    • v.47 no.6
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    • pp.358-366
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    • 2023
  • This study aimed to provide a solution for improving ship collision alert of the 'accident vulnerable ship monitoring service' among the 'intelligent marine traffic information system' services of the Ministry of Oceans and Fisheries. The current ship collision alert uses a supervised learning (SL) model with survey labels based on large ship-oriented data and its operators. Consequently, the small ship data and the operator's opinion are not reflected in the current collision-supervised learning model, and the effect is insufficient because the alarm is provided from a longer distance than the small ship operator feels. In addition, the supervised learning (SL) method requires a large number of labeled data, and the labeling process requires a lot of resources and time. To overcome these limitations, in this paper, the classification model of collision alerts for small ships using unlabeled data with the semi-supervised learning (SSL) algorithms (Label Propagation and TabNet) was studied. Results of real-time experiments on small ship operators using the classification model of collision alerts showed that the satisfaction of operators increased.

Algorithm for Maximum Degree Vertex Partition of Cutwidth Minimization Problem (절단 폭 최소화 문제의 최대차수 정점 분할 알고리즘)

  • Sang-Un Lee
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.24 no.1
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    • pp.37-42
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    • 2024
  • This paper suggests polynomial time algorithm for cutwidth minimization problem that classified as NP-complete because the polynomial time algorithm to find the optimal solution has been unknown yet. To find the minimum cutwidth CWf(G)=max𝜈VCWf(𝜈)for given graph G=(V,E),m=|V|, n=|E|, the proposed algorithm divides neighborhood NG[𝜈i] of the maximum degree vertex 𝜈i in graph G into left and right and decides the vertical cut plane with minimum number of edges pass through the vertex 𝜈i firstly. Then, we split the left and right NG[𝜈i] into horizontal sections with minimum pass through edges. Secondly, the inner-section vertices are connected into line graph and the inter-section lines are connected by one line layout. Finally, we perform the optimization process in order to obtain the minimum cutwidth using vertex moving method. Though the proposed algorithm requires O(n2) time complexity, that can be obtains the optimal solutions for all of various experimental data