• Journal of Industrial and Engineering Chemistry
• /
• v.68
• /
• pp.117-123
• /
• 2018

Recently, aqueous method has attracted lots of attention because it enables the solution-processed metal oxide thin film with high electrical properties in low temperature fabrication condition to various flexible devices. Focusing the development of aqueous route, many researchers are only focused on metal oxide materials. However, for expansive application of the aqueous-based metal oxide films, the systematic study of performance change with process variables for the development of aqueous-based metal oxide insulator film is urgently required. Here, we propose importance of process variables to achieve high electrical-performance metal oxide insulator based on the aqueous method. We found that the significant process variables including precursor solution temperature and humidity during the spincoating process strongly affect chemical, physical, and electrical properties of $AlO_x$ insulators. Through the optimization of significant variables in process, an $AlO_x$ insulator with a leakage current value approximately $10^5$ times smaller and a breakdown voltage value approximately 2-3 times greater than un-optimized $AlO_x$ was realized. Finally, by introducing the optimized $AlO_x$ insulators to solutionprocessed $InO_x$ TFTs, we successfully achieved $InO_x/AlO_x$ TFTs with remarkably high average field-effect mobility of ${\sim}52cm^2V^{-1}\;s^{-1}$ and on/off current ratio of 106 at fabrication temperature of $250^{\circ}C$.

• Journal of the Korean Society for Heat Treatment
• /
• v.28 no.3
• /
• pp.126-133
• /
• 2015

The aim of this study is to investigate the effect of solution treatment on the corrosion behavior of Mg-8%Al-(0-1)%Zn casting alloys in 1M NaCl aqueous solution. After the solution treatment, all alloys showed single ${\alpha}$-(Mg) phase microstructure by dissolution of ${\beta}(Mg_{17}Al_{12})$ phase into the ${\alpha}$-(Mg) matrix. The $H_2$ evolution volume decreased with an increase in Zn content, which indicates that the addition of Zn plays a beneficial role in decreasing corrosion rate of the Mg-Al-Zn alloy in solution-treated state. The microstructural evaluations on the corrosion products and corroded surfaces after the immersion test in 1 M NaCl solution revealed that the incorporation of more $Al_2O_3$ and ZnO into the corrosion product, by which the penetration of $Cl^-$ ions is impeded, are thought to be responsible for the better corrosion resistance in relation with the Zn addition.

• Journal of Korea Technical Association of The Pulp and Paper Industry
• /
• v.47 no.3
• /
• pp.11-17
• /
• 2015

In acid hydrolysis process of biomass saccharification. neutralization of acid hydrolyzate is essential step, which resulted in dissolved cations in glucose solution. Impact of cations to Kluyveromyces marxianus in glucose solution was investigated focused on ethanol fermentation. Either potassium or sodium cations decreased the ethanol fermentation and glucose to ethanol conversion. Glucose consumption by K. marxianus was delayed by increasing potassium cation concentration as completely consumed within 12 h in potassium cation 0.46 mol and 0.92 mol but within 24 h in potassium cation 1.38 mol. Also, ethanol fermentation process was slowed down with increasing concentration of the potassium sulfate. Fermentation of glucose solution to ethanol was more inhibited by sodium cation than potassium cation in glucose solution. Glucose was completely consumed within 24 h in sodium cation 0.95 mol. but at 1.90 mol or 2.84 mol in sodium cation could not finish the fermentation within 48 hour. Ethanol concentration was 22.26 g/L at low sodium cation in glucose solution with complete fermentation within 24 h. With increasing sodium cation in glucose solution, final ethanol concentration was reached at 14.10 g/L (sodium cation con) and 0.21 g/L (sodium cation con), which meant delaying of fermentation by sodium cations.

• Proceedings of the Membrane Society of Korea Conference
• /
• 1995.04a
• /
• pp.26-27
• /
• 1995

Most of synthetic polymeric membranes used in ultrafiltration, reverse osmosis and microfiltration processes are prepared by phase inversion(or phase separation) technique. In this technique, a homogeneous polymer solution is cast into thin film or hollow fiber shape and then immersed into a nonsolvent coagulant bath. The exchange of solvent and nonsolvent across the interface between casting solution and coagu!ant can make the casting solution phase-separate and form a membrane with a symmetric or asymmetric structure. Because of importance of this technique in membrane field, many investigations have been dedicated to elucidate the mechanism of membrane formation by phase inversion technique.[1-10] These investigation have suggested that the structure formation and permeation properties of phase inversion membrane depend on the variables such as the nature and content of casting solution and coagulant, temperature of casting solution and coagulant, and the diffusional exchange rate of solvent and nonsolvent etc. which can be related to the thermodynamic and kinetic properties of the casting system. The variables such as the nature and content of casting solution can also be the important factor affecting the structure formation and permeation property of the phase inversion membrane.

• Journal of Conservation Science
• /
• v.32 no.3
• /
• pp.417-423
• /
• 2016

The effect of the glue solution were investigated in the grinding and elutriation process for manufacturing of White clay pigment. In grinding process, glue solution decreased the production of a too fine powder and enhanced the degree of sorting of ground pigments. The grinding performance and limit are generally influenced by the frictional force. Therefore, the friction force was measured in accordance with the grinding conditions. As a result of measuring a friction force, when using glue solution it showed the lowest friction. Finally, the application of glue solution in grinding process is believed to enhance the degree of sorting of ground pigments by reducing frictional force. In elutriation process, the application of glue solution enabled the screening of larger particles in the same conditions by reducing the sedimentation velocity. This result is due to increase in the viscosity of the glue solution according to glue concentration. As a result, the application of glue solution in elutriation process is though to enlarges the range of the selectable particle size and to enable the segmentation of the particles.

• Applied Chemistry for Engineering
• /
• v.18 no.4
• /
• pp.391-395
• /
• 2007

This study investigated the feasibility of enhanced electrokinetic (EK) remediation of soil contaminated with approximately 20000 Pb-mg/kg. Enhanced EK remediation was evaluated by using mixed solution (0.3 M acetic acid and 0.03 M EDTA, EK-M) and by exchanging electrodes for preventing precipitation of metal hydrate. For the EK-M, the lead removal efficiency was only 2% lower than the case where 0.03 M EDTA was solely used (EK-Blank, EK-B). Considering the costly expense of EDTA, the application of EK-M would be economically viable. The efficiency of of EK-E was higher by 2% than the EK-B method. More impertantly, the pH values of entire soil packed column presented to be neutral (7~8) in the EK-E process. Unlike to EK-B and EK-M, the deposition of heavy metals to any specific area was avoided in the EK-E process.

• Proceedings of the Korean Society of Precision Engineering Conference
• /
• 2004.10a
• /
• pp.1315-1318
• /
• 2004

Nano-scale fabrication of silicon substrate in an aqueous solution based on the use of atomic force microscopy was demonstrated. A specially designed cantilever with diamond tip, allowing the formation of damaged layer on silicon substrate easily by a simple scratching process (Tribo-Nanolithography, TNL), has been applied instead of conventional silicon cantilever for scanning. A slant nanostructure can be fabricated by a process in which a thin damaged layer rapidly forms in the substrate at the diamond tip-sample junction along scanning path of the tip and simultaneously the area uncovered with the damaged layer is being etched. This study demonstrates how the TNL parameters can affect the formation of damaged layer and the shape of 3-D structure, hence introducing a new process of proximal nanolithography in aqueous solution.

• 한국정보디스플레이학회:학술대회논문집
• /
• 2008.10a
• /
• pp.98-100
• /
• 2008

A series of new channel materials using triisopropylsilylethynyl anthracene(TIPSAN) derivatives are synthesized by well known reaction. The TIPSAN derivatives exhibit an excellent field-effect mobility with hole mobility as high as 0.1 cm2V-1s-1 by solution-process and slip stack structure of core and end groups with short $\pi-\pi$ stacking distance of $3.525{\sim}3.485\;{\AA}$ by single crystal structures.

• Research in Mathematical Education
• /
• v.14 no.1
• /
• pp.33-50
• /
• 2010

The mathematical thinking which transforms important mathematical content and developed into mathematical structure is a vital process in building up mathematical ability as mathematical knowledge based on structure. Such process based on students' recognition of mathematical concept. Developing mathematical thinking into mathematical structure happens when different cognitive units are connected and compressed to form schema of solution, which could happen through some guided problems. The effort of arithmetic approach in problem solving did not necessarily provide students the structure schema of solution. The using of equation to solve the problem is based on the schema of building equation, and is not necessary recognizing the structure of the solution, as the recognition of structure may be lost in the process of simplification of algebraic expressions, leaving only the final numeric answer of the problem.

• Journal of the Korean Society for Industrial and Applied Mathematics
• /
• v.15 no.2
• /
• pp.151-160
• /
• 2011

Typically, it is hard to find a closed form solution of option pricing formula under an asset governed by a change point process. In this paper we derive a closed-form solution of the valuation function for an American perpetual put option under an asset having a change point. Structural changes are formulated through a change-point process with a Markov chain. The modified smooth-fit technique is used to obtain the closed-form valuation function. We also guarantee the optimality of the solution via the proof of a corresponding verification theorem. Numerical examples are included to illustrate the results.