• Title/Summary/Keyword: Solution-diffusion Model

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Evaluation of Electron Beam Dose Distribution by Age Diffusion Equation (연령 확산 이론에 의한 전자선의 조직내 선량분포 평가)

  • 추성실
    • Progress in Medical Physics
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    • v.4 no.1
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    • pp.29-39
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    • 1993
  • Electron beams have found unique and complementary used in the treatment of cancer, but it's very difficult to delineate dose distribution, because of multi-collisions. Numerical solution is more usefull to describe electron distributed in tissue. A semi-empirical eqution is given for the dose at any point at various depths in water. This equation is a modificated model which was based on solutions of a general age diffusion equation. Parameters have been calulated from electron beams data with energies 6~18MeV form a LINAC for use in computerised dosimetry calculations. The depth doses and isodose curves are predicted as a function of the practical range, source skin distance and field size. Depth dose accuracy have been achieved 2% above 50% depth dose and 5% at lower doses, relative to maximum dose. Also, the shape of the isodose curves with the constrictions at higher dose and bulging ot lower values are accurately predicted. Computer calculated beams have been used to generate ever isodose distribution for certain clinical situations.

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Effect of Hypotonic and Hypertonic Solution on Brining Process for Pork Loin Cube: Mass Transfer Kinetics (돼지고기 등심의 염지공정에서 소금농도의 영향: 물질전달 동역학을 중심으로)

  • Park, Min;Lee, Nak Hun;In, Ye-Won;Oh, Sang-Yup;Cho, Hyung-Yong
    • Food Engineering Progress
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    • v.23 no.1
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    • pp.7-15
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    • 2019
  • The impregnation of solid foods into the surrounding hypotonic or hypertonic solution was explored as a method to infuse NaCl in pork loin cube without altering its matrix. Mass transfer kinetics using a diffusive model as the mathematical model for moisture gain/loss and salt gain and the resulting textural properties were studied for the surrounding solutions of NaCl 2.5, 5.0, 10.0 and 15% (w/w). It was possible to access the effects of brine concentration on the direction of the resulting water flow, quantify water and salt transfer, and confirm tenderization effect by salt infusion. For brine concentrations up to 10% it was verified that meat samples gained water, while for processes with 15% concentration, pork loin cubes lost water. The effective diffusion coefficients of salt ranged from 2.43×10-9 to 3.53×10-9 m2/s, while for the values of water ranged from 1.22×10-9 to 1.88×10-9 m2/s. The diffusive model was able to represent well salt gain rates using a single parameter, i.e. an effective diffusion coefficient of salt through the meat. However, it was not possible to find a characteristic effective diffusion coefficient for water transfer. Within the range of experimental conditions studied, salt-impregnated samples by 5% (w/w) brine were shown with minimum hardness, chewiness and shear force.

Time Dependent Chloride Transport Evaluation of Concrete Structures Exposed to Marine Environment (해안 환경 하에 있는 콘크리트 구조물의 시간의존적 염화물침투 평가)

  • Song, Ha-Won;Pack, Seung-Woo;Ann, Ki-Yong
    • Journal of the Korea Concrete Institute
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    • v.19 no.5
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    • pp.585-593
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    • 2007
  • This paper presents a model for durability evaluation of concrete structures exposed to marine environment, considering mainly a build-up of surface chloride $(C_s)$ as well as diffusion coefficient (D) and chloride threshold level $(C_{lim})$. In this study, time dependency of $C_s$ and D were extensively studied for more accurate evaluation of service life of concrete structures. An analytical solution to the Fick's second law was presented for prediction of chloride ingress for time varying $C_s$. For the time varying $C_s$, a refined model using a logarithm function for time dependent $C_s$ was proposed by the regression analysis, and averaging integrated values of the D with time over exposed duration were calculated and then used for prediction of the chloride ingress to consider time dependency of D. Durability design was also carried out for railway concrete structures exposed to marine environment to ensure 100 years of service life by using the proposed models along with the standard specification on durability in Korea. The proposed model was verified by the so-called performance-based durability design, which is widely used in Europe. Results show that the standard specification underestimates durability performances of concrete structures exposed to marine environment, so the cover depth design using current durability evaluation in the standard specifications is very much conservative. Therefore, it is found that utilizing proposed models considering time dependent characteristics of $C_s$ and D can evaluate service lift of concrete structures in marine environment more accurately.

Crystallographic study of in-plane aligned hybrid perovskite thin film

  • Lee, Rin;Kim, Se-Jun;Seong, Myeong-Mo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.163.1-163.1
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    • 2016
  • Lead halide perovskites CH3NH3PbX3 (X=Cl, Br, I) have received great interest in the past few years because of their excellent photoelectronic properties as well as their low-cost solution process. Their theoretical efficiency limit of the solar cell devices was predicted around 31% by a detailed balance model for the reason that exceptional light-harvesting and superior carrier transport properties. Additionally, these excellent properties contribute to the applications of optoelectronic devices such as LASERs, LEDs, and photodetectors. Since these devices are mainly using perovskite thin film, one of the most important factor to decide the efficiency of these applications is the quality of the film. Even though, optoelectrical devices are composed of polycrystalline thin film in general, not a single crystalline form which has longer carrier diffusion length and lower trap density. For these reasons, monodomain perovskite thin films have potential to elicit an optimized device efficiency. In this study, we analyzed the crystallography of the in-plane aligned perovskite thin film by X-ray diffraction (XRD) and selected area electron diffraction (SAED). Also the basic optic properties of perovskites were checked using scanning electron microscopy (SEM) and UV-Vis spectrum. From this work, the perovskite which is aligned in all directions both of out-of-plane and in-plane was fabricated and analyzed.

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Removal of Cu(II) and Pb(II) by Solid-Phase Extractant Prepared by Immobilizing D2EHPA with Polysulfone (D2EHPA를 Polysulfone으로 고정화하여 제조한 고체상 추출제에 의한 Cu(II)와 Pb(II)의 제거)

  • Kam, Sang-Kyu;Jeon, Jin-Woo;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.23 no.11
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    • pp.1843-1850
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    • 2014
  • PS-D2EHPA beads were prepared by immobilizing di-2-ethylhexyl-phosphoric acid (D2EHPA) with polysulfone (PSf). The removal experiments of Cu(II) and Pb(II) by the prepared PS-D2EHPA beads were conducted batchwise. The removal efficiency of Cu(II) and Pb(II) by PS-D2EHPA beads was increased with increasing pH of solution. The removal rate of Cu(II) and Pb(II) was well described by the pseudo-second-order kinetic model. The maximum removal capacity of Cu(II) and Pb(II) obtained from Langmuir isotherm were 2.58 mg/g and 12.63 mg/g, respectively. External mass transfer coefficients for the removal of Cu(II) and Pb(II) by PS-D2EHPA beads were obtained $0.61{\times}10^{-2}{\sim}5.87{\times}10^{-2}/min$ and $1.55{\times}10^{-2}{\sim}8.53{\times}10^{-2}/min$, respectively and diffusion coefficients were obtained $1.32{\times}10^{-4}{\sim}3.98{\times}10^{-4}cm^2/min$ and $1.80{\times}10^{-4}{\sim}2.28{\times}10^{-4}cm^2/min$, respectively.

Oxygen Permeability, Electronic and ionic Conductivities and Defect Chemistry of Ceria-Zirconia-Calcia

  • Kawamura, Ken-ichi;Watanabe, Kensuke;Nigara, Yutaka;Kaimai, Atsushi;Kawada, Tatsuya;Mizusaki, Junichiro
    • The Korean Journal of Ceramics
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    • v.4 no.2
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    • pp.146-150
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    • 1998
  • The total conductivity and oxygen permeation in (Ce1-xZrxO2)0.9(CaO)0.1 solid solutions were measure das a function of temperature and oxygen partial pressure. Empirically, σ at given x and T was expressed essentially by σ=σo2+σeo Po2-1/4, where σo2 and σeo are constant. Applying a standard defect model in which major defects are Cace", Cece' and Vo in ideal solution, we can assign σo2 as the oxide ion conductivity decreases while the electronic conductivity increases with the increase in Zr content. Using the oxide ion and electronic conductivities thus determined, the oxygen permeation flux was calculated for respective Po2 and T conditions at which the measurements were made. The calculated values were found to agree with the observed ones.

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The Impact of Organization Member's Self-Congruity on the Performance of the Acquisition of New Information Technology (조직 구성원의 자아 일치성이 신규 정보기술 도입의 성과에 미치는 영향)

  • Bae, Seon-Jin;Suh, Bomil
    • Journal of Information Technology Applications and Management
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    • v.23 no.2
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    • pp.29-59
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    • 2016
  • These days, the business environment such as Information Technology (IT) is rapidly changing, and organizations are consistently trying to change themselves for the survival and success under the changing environment. In this situation, change management is very important because it draws the change behaviors of organization members for the success of organizational change. The purpose of this study is to investigate the effect of the organization members' psychological factors on the performance of the acquisition of new IT, which is one of the most important organizational change. Based on previous studies in the area of organizational change, organization members' resistance to change, self-congruity theory, change activities and organizational performance, the research model is developed for validating the effect of organization members' self-congruity on the performance of the acquisition of new IT. Statistical analyses show that self-congruity has a significant effect on the change activities. In particular, private self-congruity has more impact on the change activities than public self-congruity. In addition, self-leadership, rewards and recognitions, and the diffusion of change activities have significant effects on job satisfaction. Self-leadership has a significant effect on organizational commitment.

Self-Assembled Polymeric Nanoparticles of Poly(ethylene glycol) Grafted Pullulan Acetate as a Novel Drug Carrier

  • Jung, Sun-Woong;Jeong, Young-Il;Kim, Young-Hoon;Kim, Sung-Ho
    • Archives of Pharmacal Research
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    • v.27 no.5
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    • pp.562-569
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    • 2004
  • Self-assembling nanospheres of hydrophobized pullulan have been developed. Pullulan acetate (PA), as hydrophobized pullulan, was synthesized by acetylation. Carboxymethylated poly(ethylene-glycol) (CMPEG) was introduced into pullulan acetate (PA) through a coupling reaction using N, N'-dicyclohexyl carbodiimide (DCC). A synthesized PA-PEG-PA (abbreviated as PEP) conjugate was confirmed by Fourier transform-infrared (FT-IR) spectroscopy. Since PEP conjugates have amphiphilic characteristics in aqueous solution, polymeric nanoparticles of PEP conjugates were prepared using a simple dialysis method in water. From the analysis of fluorescence excitation spectra primarily, the critical association concentration (CAC) of this conjugate was found to be 0.0063 g/L. Observations by scanning electron microscopy (SEM) showed the spherical morphologies of the PEP nanoparticles. The particle size distribution of the PEP conjugates was determined using photon correlation spectroscopy (PCS) and the intensity-average particle size was 193.3 ${\pm}$ 13.53 nm with a unimodal distribution. Clonazepam (CNZ), as a model drug, was easy to entrap into polymeric nanoparticles of the PEP conjugates. The drug release behavior was mainly diffusion controlled from the core portion.

Finding the best combination of numerical schemes for 2-D SPH simulation of wedge water entry for a wide range of deadrise angles

  • Farsi, Mohammad;Ghadimi, Parviz
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.6 no.3
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    • pp.638-651
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    • 2014
  • Main aim of this paper is to find the best combination of numerical schemes for 2-D SPH simulation of wedge water entry. Diffusion term is considered as laminar, turbulent, and artificial viscosity. Density filter that seriously affects the pressure distribution is investigated by adopting no filter, first order filter, and second order filter. Validation of the results indicates that turbulent model and first order density filter can lead to more reasonable solutions. This simulation was then conducted for wedge water entry with wide range of deadrise angles including 10 degrees, 20 degrees, 30 degrees, 45 degrees, 60 degrees and 81 degrees, with extreme deadrise angles of 10 degrees, 60 degrees and 81 degrees being considered. Comparison of SPH results with BEM solutions has displayed favorable agreement. In two particular cases where experimental data are available, the SPH results are shown to be closer to the experiments than BEM solution. While, accuracy of the obtained results for moderate deadrise angles is desirable, numerical findings for very small or very large deadrise angles are also very reasonable.

Analysis of Space Charge Propagation in a Dielectric liquid Employing Field-Thermal Electron Emission Model and Finite Element Method (유한요소법과 전계-열전자 방출 모델에 의한 절연유체 내 공간전하 전파해석)

  • Lee, Ho-Young;Lee, Se-Hee
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.10
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    • pp.2011-2015
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    • 2009
  • In an insulating dielectric liquid such as transformer oil, space charge injection and propagation were analyzed under the Fowler-Nordheim and Richardson-Dushman's thermal emission charge injection conditions for blade-plane electrodes stressed by a step voltage. The governing equations were composed of all five equations such as the Poisson's equation for electric fields, three continuity equations for electrons, negative, and positive ions, and energy balanced equation for temperature distributions. The governing equations for each carrier, the continuity equations, belong to the hyperbolic-type PDE of which the solution has a step change at the space charge front resulting in numerical instabilities. To decrease these instabilities, the governing equations were solved simultaneously by the Finite Element Method (FEM) employing the artificial diffusion scheme as a stabilization technique. Additionally, the terminal current was calculated by using the generalized energy method which is based on the Poynting's theorem, and represents more reliable and stable approach for evaluating discharge current. To verify the proposed method, the discharge phenomena were successfully applied to the blade~plane electrodes, where the radius of blade cap was $50{\mu}m$.