• 제목/요약/키워드: Solution processing

검색결과 2,279건 처리시간 0.027초

폐니켈-카드뮴 전지로부터 황산암모늄을 이용한 수산화니켈 제조 방안 연구 (A study on the Synthesis of Nickel Hydroxide by Ammonium Sulfate from Waste Nickel-Cadmium Batteries)

  • 김민준;박일정;김대원;정항철
    • 자원리싸이클링
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    • 제28권5호
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    • pp.51-59
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    • 2019
  • 폐니켈-카드뮴전지 내의 니켈과 카드뮴을 분리하기 위한 재활용 기술 중 황산암모늄($(NH_4)_2SO_4$)을 이용하여 니켈을 침전시킴으로써 분리하는 기술이 보고되고 있어, 실제 산업현장에서 사용 중인 침출액을 이용하여 pH, 온도, 황산암모늄의 투입량 등을 변수로 하여 최적의 니켈 회수 조건을 도출하였다. pH의 경우 중성, 염기성에 비해 산성의 침출액에 황산암모늄을 투입했을 때 안정적인 황산니켈암모늄($(NH_4)_2Ni(SO_4)_26H_2O$)이 형성되었으며, 침출액의 온도는 $60^{\circ}C$일 때 가장 높은 순도를 나타내었다. 황산암모늄의 투입량은 니켈 함량 대비 2배의 몰 비로 투입했을 때 높은 회수율과 가장 적은 불순물 함량을 나타내었다. 서로 다른 두 공정을 통한 수산화니켈 제조 결과, 황산니켈암모늄 이용 시 카드뮴이 1.4% 검출되었고 황화나트륨($Na_2S$)을 이용하여 카드뮴을 제거한 용액에서 수산화니켈 제조 시에는 침출액 내 포함되어 있던 철과 니켈이 동시에 석출되었다. 본 연구를 통해 황산암모늄을 이용한 니켈 회수가 유용한 재활용 기술이 될 수 있을 것으로 사료된다.

저온 용액 공정을 이용한 태양전지용 CdTe 박막 합성 (Synthesis of CdTe Thin Films for Solar Cell using Solution-based Deposition Method at Low Temperature)

  • 배은진;류시옥
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 추계학술대회 논문집
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    • pp.373-376
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    • 2009
  • CdTe thin films for photovoltaic cell devices were deposited on the glass substrates by solution-based deposition methods, at low temperature processing conditions. In order to characterize physical, optical, and electronic properties of CdTe light absorbing polycrystalline material, a series of analysis was carried out in this study.

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A Modified Scheme of OFDM Transceiver for Reduction of Its Natural Delay

  • Kim, Dongkyu;Kim, Juyon;Seungkwon Baek
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2002년도 ITC-CSCC -3
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    • pp.1905-1908
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    • 2002
  • In this paper, we analyze the natural processing delay of OFDM systems and proposed two modified unctional blocks to decrease about 25% of the total delay. e evaluate BER performance of the proposed scheme to e compared with that of classical one to confirm same performance between them.

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Modeling and Simulation of Intelligent Hierarchical Flexible Manufacturing

  • Cho, Tae-Ho;Bernard P. Zeigler;Seo, Hee-Suk
    • 정보처리학회지
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    • 제11권1호
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    • pp.8-19
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    • 2004
  • Many Researchers and practitioners have expressed the view that artificial intelligence(AI) may have significant application to solution of manufacturing problems. Expert systems have been developed for solving problem areas.(omitted)

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시.공간 상관성을 이용한 움직임 추정 연구

  • 임기영;이시현
    • 한국정보처리학회:학술대회논문집
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    • 한국정보처리학회 2000년도 제13회 춘계학술대회 및 임시총회 학술발표 논문집
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    • pp.858-863
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    • 2000
  • 동영상은 시간 및 공간적으로 많은 상관성을 지니고 있으며, 움직임추정 방법에서 움직임의 시 공간 상관성을 이용하면 정확한 움직임 추정과 성능 개선을 가져올 수 있다. 한편, Zafar와 Zhang은 웨이브릿 변환 영역에서 가변 블록 (variable block-size)을 이용한 다해상도 움직임 추정(multire-solution motion estimation) 기법을 제안하였다

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식각액에 따른 용융실리카의 레이저 습식 식각 특성 비교 연구 (A Comparative Study on the Influence of Etchant upon the Etching Rate and Quality in Laser Induced Wet Etching of Fused Silica)

  • 이종호;이종길;전병희
    • 소성∙가공
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    • 제13권3호
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    • pp.268-272
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    • 2004
  • Transparent materials such as fused silica are widely utilized in optical and optoelectronics field because of its outstanding properties, such as transparency in a wide wavelength range, strong damage resistance for laser irradiation, and high thermal and chemical stability. In this study, we made a few micro patterns on the surface of fused silica plate using laser induced wet etching. KrF excimer laser was used as a light source. There were no burrs and micro cracks on the etched surface of fused silica and the flatness of the etched surface was fairly good. We investigated the influence of etchant upon the etch rate and quality in laser induced wet etching. Pyrene-acetone solution and toluene were used as etchant. In the side of etch rate, toluene solution was better than pyrene-acetone solution. But we made in wider range of energy density using pyrene-acetone solution. But pyrene-acetone solution gave us wider window of energy density for successful micro patterning.

우렁쉥이 건제품 개발에 관한 연구 (Processing of Dried Products of Ascidian , Halocynthia roretzi)

  • 이강호;홍병일;정병천;조호성;이동호;정우진
    • 한국식품영양과학회지
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    • 제23권4호
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    • pp.625-633
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    • 1994
  • In this study, processing of dried products of adcidian , Haocynthia roretzi, were investigated, which has been cultured in the south and east coast of Korea in recent years. Raw ascidians were shucked , gutted, soaked and then drained. Seven kinds of dried ascidian meats were prepared : boiled in 5% slat solution for 10 min and hot-air dried (A)-sun dried (B) or hot-air dried (C) after soaking for 1 min in 0.2% NaHSO3 solution , sun dried (D) or hot -air dried (G) after treating for 15 sec in 5% liquid smoke solution, and sun dried (E) or hot -air dried (F) after blanching for 30 sec in boiling 5% salt solution added with 0.2% NaHSO3. The moisture contents, water activity of the products showed little change and VBN gradually increased during storage at 25 $\pm$2$^{\circ}C$. The TBA and POV values of the liquid smoked dried ascidian (product D, G0 were considerably lower than those of others, In fatty acid composition 22 : 6 , 20 : 5 : 16: 0 and 18 : 1 acid were predominant. Conditions adopted in products D and G had a good antioxidative effect on highly unsatuated fatty acids during the storage. The contents of inosine and AMP of products were higher than those of other nucleotide and their related compounds. Judging from the results of chemical experiments and sensory evaluation, the sample A, D and G were most desirable and they could be preserved more than 120 days at room temperature(25$\pm$2$^{\circ}C$).

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Shear-induced structure and dynamics of hydrophobically modified hydroxy ethyl cellulose (hmHEC) in the presence of SDS

  • Tirtaatmadija, Viyada;Cooper-white, Justin J.;Gason, Samuel J.
    • Korea-Australia Rheology Journal
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    • 제14권4호
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    • pp.189-201
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    • 2002
  • The interaction between hydrophobically modified hydroxyethyl cellulose (hmHEC), containing approximately 1 wt% side-alkyl chains of $C_{16}$, and an anionic sodium dodecyl sulphate (SDS) surfactant was investigated. For a semi-dilute solution of 0.5 wt% hmHEC, the previously observed behaviour of a maximum in solution viscosity at intermediate SDS concentrations, followed by a drop at higher SDS concentrations, until above the cmc of surfactant when the solution resembles that of the unsubstituted polymer, was confirmed. Additionally, a two-phase region containing a hydrogel phase and a water-like supernatant was found at low SDS concentrations up to 0.2 wt%, a concentration which is akin to the critical association concentration, cac, of SDS in the presence of hmHEC. Above this concentration, SDS molecules bind strongly to form mixed micellar aggregates with the polymer alkyl side-chains, thus strengthening the network junctions, resulting in the observed increase in viscosity and elastic modulus of the solution. The shear behaviour of this polymer-surfactant complex during steady and step stress experiments was examined In great detail. Between SDS concentrations of 0.2 and 0.25 wt%, the shear viscosity of the hmHEC-polymer complex network undergoes shear-induced thickening, followed by a two-stage shear-induced fracture or break-up of the network. The thickening is thought to be due to structural rearrangement, causing the network of flexible polymers to expand, enabling some polymer hydrophobic groups to be converted from intra- to inter-chain associations. At higher applied stress, a partial local break-up of the network occurs, while at even higher stress, above the critical or network yield stress, a complete fracture of the network into small microgel-like units, Is believed to occur. This second network rupture is progressive with time of shear and no steady state in viscosity was observed even after 300 s. The structure which was reformed after the cessation of shear is found to be significantly different from the original state.

QoS Constrained Optimization of Cell Association and Resource Allocation for Load Balancing in Downlink Heterogeneous Cellular Networks

  • Su, Gongchao;Chen, Bin;Lin, Xiaohui;Wang, Hui;Li, Lemin
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • 제9권5호
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    • pp.1569-1586
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    • 2015
  • This paper considers the optimal cell association and resource allocation for load balancing in a heterogeneous cellular network subject to user's quality-of-service (QoS) constraints. We adopt the proportional fairness (PF) utility maximization formulation which also accommodates the QoS constraints in terms of minimum rate requirements. With equal resource allocation this joint optimization problem is either infeasible or requires relaxation that yields a solution which is difficult to implement. Nevertheless, we show that this joint optimization problem can be effectively solved without any priori assumption on resource allocation and yields a cell association scheme which enforces single BS association for each user. We re-formulated the joint optimization problem as a network-wide resource allocation problem with cardinality constraints. A reweighted heuristic l1-norm regularization method is used to obtain a sparse solution to the re-formulated problem. The cell association scheme is then derived from the sparsity pattern of the solution, which guarantees a single BS association for each user. Compared with the previously proposed method based on equal resource allocation, the proposed framework results in a feasible cell association scheme and yields a robust solution on resource allocation that satisfies the QoS constraints. Our simulations illustrate the impact of user's minimum rate requirements on cell association and demonstrate that the proposed approach achieves load balancing and enforces single BS association for users.