• 제목/요약/키워드: Solution processing

검색결과 2,279건 처리시간 0.03초

Solution-based fabrication of germanium sulphide doped with or without Li ions for solid electrolyte applications

  • Jin, Byeong Kyou;Cho, Yun Gu;Shin, Dong Wook;Choi, Yong Gyu
    • Journal of Ceramic Processing Research
    • /
    • 제13권spc1호
    • /
    • pp.110-113
    • /
    • 2012
  • Ge-S and Li-Ge-S powders were synthesized via solution-based process in order to employ chalcogenide-based solid electrolyte for use in Li secondary batteries. GeCl4 and thioacetamide in combination result in Ge-S powders of which major crystalline phase becomes GeS2 where the tetragonal and orthorhombic phases coexist after heat treatment. A chemical treatment using NaOH brings about the reduction of chlorine in the powders obtained. However, the heat treatment at 300 ℃ is more effective in minimizing the chlorine content. When lithium chloride is used as the precursor of Li ions, the LiCl powders are agglomerated with an inhomogeneous distribution. When Li2S is used, the Li-Ge-S powders are distributed more uniformly and the orthorhombic GeS2 phase dominates in the powders.

인삼 추출물 처리에 의한 천연 염색 면직물의 기능성 연구 (A Study on Dyeability of Cotton Fabrics using Ginseng Extracts)

  • 김월순
    • 복식문화연구
    • /
    • 제19권2호
    • /
    • pp.324-333
    • /
    • 2011
  • This study was accomplished for the purpose of developing a textile processing ingredient that is harmless to the human body and environment. The research method consists of dyeing cotton textiles by extracting the dye solution from ginseng. Then, chrominance, after treatment, antibacterial ratio and deodorization ratio of cotton fabrics dyed with ginseng extracts were tested and results were examined. The research procedure involved first extracting the dye solution from the ginseng's by-product (fine roots) and then dyeing was effectuated differently according to the test samples temperature and dyeing time requirements. Brightness in all dye substances was lower in pre-mordanting. Beige color could be extracted from pre-mordanted samples. And dark orange from postmordanted samples. Color-festness was high in all samples. Most of samples show a big antibacterial ratio and deodorization ratio. Through this research it has been discovered that, when applied to textiles, Korea's ginseng extract possessed reproducibility features as a natural dye and a possibility to be used in cutting which plays a crucial role in hygienic processing. In addition, by using ginseng's by-product for dyeing processing as the dye solution, efficient application of resources and occurrences of no water waste damages were demonstrated and thus, proved to be environmentally-friendly. Specifically, through this experiment, it was found that saponin, ginseng's special characteristics, possessed excellent antibacterial odor repelling functions to clothing as well as the capability to prevent skin disease.

GPU를 이용한 효율적인 비압축성 자유표면유동 해석 (AN EFFICIENT INCOMPRESSIBLE FREE SURFACE FLOW SIMULATION USING GPU)

  • 홍환의;안형택;명훈주
    • 한국전산유체공학회지
    • /
    • 제17권2호
    • /
    • pp.35-41
    • /
    • 2012
  • This paper presents incompressible Navier-Stokes solution algorithm for 2D Free-surface flow problems on the Cartesian mesh, which was implemented to run on Graphics Processing Units(GPU). The INS solver utilizes the variable arrangement on the Cartesian mesh, Finite Volume discretization along Constrained Interpolation Profile-Conservative Semi-Lagrangian(CIP-CSL). Solution procedure of incompressible Navier-Stokes equations for free-surface flow takes considerable amount of computation time and memory space even in modern multi-core computing architecture based on Central Processing Units(CPUs). By the recent development of computer architecture technology, Graphics Processing Unit(GPU)'s scientific computing performance outperforms that of CPU's. This paper focus on the utilization of GPU's high performance computing capability, and presents an efficient solution algorithm for free surface flow simulation. The performance of the GPU implementations with double precision accuracy is compared to that of the CPU code using an representative free-surface flow problem, namely. dam-break problem.

MoO3 침출공정 폐액으로부터 치환반응 시스템을 이용한 구리 분말 회수에 대한 연구 (Recovery of Copper Powder form MoO3 Leaching Solution Using Cementation Reaction System)

  • 김건홍;홍현선;정항철
    • 한국분말재료학회지
    • /
    • 제19권6호
    • /
    • pp.405-411
    • /
    • 2012
  • Recovery of copper powder from copper chloride solution used in $MoO_3$ leaching process was carried out using a cementation method. Cementation is a simple and economical process, necessitating less energy compared with other recovery methods. Cementation utilizes significant difference in standard reduction potential between copper and iron under standard condition. In the present research, Cementation process variables of temperature, time, and added amount of iron scraps were optimized by using design of experiment method and individual effects on yield and efficiency of copper powder recovery were investigated using bench-scale cementation reaction system. Copper powders thus obtained from cementation process were further characterized using various analytical tools such as XRF, SEM-EDS and laser diffraction and scattering methods. Cementation process necessitated further purification of recovered copper powders and centrifugal separation method was employed, which successfully yielded copper powders of more than 99.65% purity and average $1{\mu}m$ in size.

Influence of Processing Conditions on PVDF Properties

  • Lebedev, S.M.;Gefle, O.S.;Semenikhin, M.V.
    • 한국분말재료학회지
    • /
    • 제18권2호
    • /
    • pp.176-180
    • /
    • 2011
  • Study of the main properties of PVDF films produced by two processing technologies such as hot pressing from a melt or solution casting was the aim of this paper. All samples were prepared of as-received PVDF powder. First group of samples was prepared by the hot pressing. Second group of samples was prepared by the solution casting method. PVDF powder was dissolved in dimethylformamide. To characterize properties of samples, different experimental methods such as FRA (dielectric spectroscopy), IR-spectroscopy and DSC/TGA analysis were used in this work. It was found that IR-spectra of both studied groups do not change compared to that for virgin PVDF powder. It confirms that molecular structure is practically independent on the processing technology of samples. The only difference has been found that new band centered at $1723\;cm^{-1}$ appears for samples prepared by the hot pressing method. This absorption band is related with formation of C=C bonds in samples prepared by the hot pressing method in contrast both to PVDF powder and samples prepared by the solution casting method.

전력계통의 고장진단을 위한 전문가 시스템의 연구 (An Expert System for Foult Diagnosis in a System)

  • 박영문;이흥재
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 1989년도 하계종합학술대회 논문집
    • /
    • pp.241-245
    • /
    • 1989
  • A knowledge based expert system is a computer program that emulates the reasoning process of a human expert in a specific problem domain. This paper presents an expert system to diagnose the various faults in power system. The developed expert system is represented considering two points; the possibility of solution and the fast processing speed. As uncertainties exist in the facts and rules which comprise the knowledge base of the expert system, Certainty Factor, which is based on the confirmation theory is used for the inexact reasoning. Also, as the diagnosis problem requires the inductive reasoning process in nature, the solution is imperfect and not unique in general. So the expert system is designed to generate all the possible hypothesis in order of the possibility and also it can explain the propagation procedure of the faults for each solution using the built in backtracking mechanism. In realization of the expert system, the processing speed is greatly dependent upon the problem representation, reasoning scheme and search strategy. So, in this paper the fault diagnosis problem itself is analysed from the view point of Artificial Intelligence and as a result, the expert system has the following basic features. 1) The certainty factor is adopted in the inference engine for inexact reasoning. 2) Problem apace is represented using the problem reduction technique. 3) Bidirectional reasoning scheme is used. 4) Best first search strategy is adopted for rapid processing. The expert system was developed us ing PROLOG language.

  • PDF

화학적으로 변형된 전구용액을 이용한 YBCO 박막 제조 (Fabrication of YBCO films in MOD processing via chemically modified precursor solution)

  • 김영국;유재무;정국채;고재웅;김영준;한봉수
    • Progress in Superconductivity
    • /
    • 제7권2호
    • /
    • pp.158-161
    • /
    • 2006
  • Superconducting YBCO films were successfully fabricated by MOD process using chemically modified precursor solution. In this study, a chemically modified precursor solution for MOD processing was synthesized using metal-organic salts and organic additives. It was shown that crack-free and uniform precursor films were formed after calcination in humidified Oxygen atmosphere. Less than 3 hours are required to finish the calcination process. XRD measurement shows that $BaF_2,\;CuO,\;Y_2O_3$ are major constituent of precursor films. Furthermore, YBCO films without any secondary phases were successfully fabricated after annealing in wet $Ar/O_2$ atmosphere. The YBCO film prepared on a $LaAlO_3$ single crystal substrate ($10mm{\times}10mm$) gives transport $I_c$ of 10A at 77K. This chemical modification approach is a possible candidate for improving MOD-processing of YBCO coated conductor.

  • PDF

F-free 구리 전구용액을 이용한 YBCO 박막 제조 (Fabrication of YBCO films in MOD processing using F-free Cu precursor solution)

  • 김영국;유재무;고재웅;정국채;김영준;한봉수
    • 한국초전도ㆍ저온공학회논문지
    • /
    • 제7권3호
    • /
    • pp.5-8
    • /
    • 2005
  • Superconducting YBCO films were successfully fabricated by MOD process using F-free Cu precursor solution. In this study. a chemically modified precursor solution for MOD Processing was synthesized using metal-organic salts and F-free Cu precursor. It was shown that crack-free and uniform precursor films were formed after calcination in humidified oxygen atmosphere. Less than 3 hours are required to finish the calcination process. XRD measurement shows that $BaF_2,\;CuO,\;Y_2O_3$ are major constituent of precursor films. Furthermore. YBCO films without any secondary phases were successfully fabricated after annealing in wet $Ar/O_2$ prepared on a $LaA1O_3$ single crystal substrate $(10mm{\times}10mm)$ gives transport Ic of 10A at 77K. This chemical modification approach is a possible candidate for improving MOD-processing of YBCO coated conductor.

차체용 알루미늄합금의 인산염피막 처리액의 특성 관한 연구 (A study on the characteristics of phosphating solution for automobile-aluminum-body sheets)

  • 이규환;노병호;김만
    • 한국표면공학회지
    • /
    • 제27권4호
    • /
    • pp.207-214
    • /
    • 1994
  • In consideration of global environmental protection and fuel saving, aluminum alloy sheets for auto body panels such as hood, fender etc., are expected one of the most promising materials for weight saving of cars. The chemical conversion coating is required to prevent the filiform corrosion occurring on painted aluminum. However the conventional process for the composited material mixed with aluminum and steel is complexs; aluminum part is chromated and assembled to the body, and then the steel body undergoes Zn phosphating. In order to overcome the low productivity due to the complex process and the environmental problem with a conventional process, a simultaneous zinc phosphating process for alsuminum and steel in an assembled condition is demanded. Newly developed phosphate solution has been investigated to characterize the phosphating behavior under various conditions. The optimum conditions of the phosphating solution for the application of the paint treatment derived as follows : about 0.3 for the ratio of Zn to $PO_4$, , 200~500 ppm for the concentration of fluoride ion, and 2.5~4.0 for pH. The concentration of dissolved aluminum ion must be kept below 2--ppm and suitable accelerator is found to be a mixture of 1g/$\ell$ $NO_2\;^-$, and 6g/$\ell$ $NO_3\;^-$.

  • PDF

반응표면 분석법을 이용한 마늘 열풍건조 공정의 최적화 (Development of Optimum Processing Conditions in Air Dried Garlics Using Response Surface Methodology)

  • 김명환;김병용
    • 한국식품영양과학회지
    • /
    • 제19권3호
    • /
    • pp.234-238
    • /
    • 1990
  • The effects of salt concentration immersion time in a salt solution prior to air dehydration and heating of air temperature during dehydration upon the browning reaction and pyruvic acid content of air dried garlics to a 6.5% moisture content(wet basis) were analyzed by a response surface methodology(RSM), Those values were also predicted by using a second degree polynomial regression model. Heating of air temperature was the most significant factor affecting the both browning reaction and pyruvic acid content. Salt concentration had more influence to browning reaction than immersion time whereas immersion time was more impor-tant factor than salt concentration on a retention of pyruvic acid sugested different processing conditions. While the processing conditions to minimize the browning reaction(O.D=0.009) were 0.3% of salt solution 9 min of immersion time and 5$0^{\circ}C$ of air temperature compared to control(O.D=0.022) of air dehydration at 5$0^{\circ}C$ Pyruvic acid contents were maximized(174 $\mu$mole/g garlic solid) at the 0.1% of salt solution 3 min of immersion time and 5$0^{\circ}C$ of air temperature compared to control(147 $\mu$mole/g garlic solid) of air dehydration at 5$0^{\circ}C$

  • PDF