• 제목/요약/키워드: Solution flow

검색결과 3,119건 처리시간 0.025초

無觸媒酸化에 依한 黃酸암모늄의 工業的 製法에 關한 硏究 (A Study on Industrial Preparation Method of Ammonium Sulfate by Non-catalytic Oxidation)

  • 정기용
    • 대한화학회지
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    • 제10권2호
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    • pp.76-90
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    • 1966
  • Ammonium sulfate synthesized by the air oxidation methods without catalyst using the reaction vessel which was fitted with fritted glass at the bottom of it and introducing, through the bottom, ammonia and air with constant flow rates to sulfurous acid solution of constant concentrations at the given temperatures. The experiment showed that the oxidation process was accelerated in accord with the increase of the air flow rates when the ammonia flow rate was constantly kept at ca. 100ml/min. in high temperatures. When the pH of the solution reached 9.0, the oxidation was nearly completed. It is assumed that in the process of reaction, $[O_{2}{\to}HSO_{3}^-]^{\neq}$ would be produced as an activated complex and the reaction was thought to be first order. The experiment indicated that the 0.5M sulfurous solution could be oxidized up to 98.54% at the flow rates of ammonia and air, 100ml/min., and 4l/min., respectively at $50^{\circ}C$.

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Electrochemical Degradation of Benzoquinone in a Flow through Cell with Carbon Fibers

  • Yoon, Jang-Hee;Yang, Jee-Eun;Shim, Yoon-Bo;Won, Mi-Sook
    • Bulletin of the Korean Chemical Society
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    • 제28권3호
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    • pp.403-407
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    • 2007
  • The anodic degradation of benzoquinone(BQ), a model compound for wastewater treatment was carried out using a home-made flow-through electrochemical cell with carbon fibers. To optimize the controlled current electrolysis condition of an aqueous BQ solution, the experimental variables affecting the degradation of BQ, such as the applying current, pH, reaction time, and flow rate of the BQ solution were examined. The degradation products of the oxidation reaction were identified by High Performance Liquid Chromatography and Inductively Coupled Plasma Atomic Emission Spectrometer. Low molecular weight aliphatic acids, and CO2 were the major products in this experiment. The removal efficiency of BQ from the solution increased with the applying current and time. 99.23% of 1.0 × 10-2 M BQ was degraded to aliphatic acids and CO2 when the applying current is 175 mA in a 12 hr electrolysis.

비점성 평면 정체 유동 응고 문제에 대한 점근적 해석 (An Asymptotic Analysis on the Inviscid Plane Stagnation-flow Solidification Problem)

  • 유주식;엄용균
    • 대한기계학회논문집B
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    • 제24권6호
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    • pp.792-801
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    • 2000
  • The problem of phase change from liquid to solid in the inviscid plane-stagnation flow is theoretically investigated. The solution at the initial stage of freezing is obtained by expanding it in powers of time, and the final equilibrium state is determined from the steady-state governing equations. The transient solution is dependent on the three dimensionless parameters, but the equilibrium state is determined by one parameter of (temperature ratio/conductivity ratio). The effect of the fluid flow on the growth rate of the solid in the pure conduction problem can be clearly seen from the solution of the initial stage and the final equilibrium state. The characteristics of the transient heat transfer at the surface of the solid and the liquid side of the solid-liquid interface for all the dimensionless parameters are elucidated.

Inviscid Rotational Flows Near a Corner and Within a Triangle

  • Suh, Yong-Kweon
    • Journal of Mechanical Science and Technology
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    • 제15권6호
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    • pp.813-820
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    • 2001
  • Solutions of inviscid rotational flows near the corners of an arbitrary angle and within a triangle of arbitrary shapes are presented. The corner-flow solutions has a rotational component as a particular solution. The addition of irrotatoinal components yields a general solution, which is indeterminate unless the far-field condition is imposed. When the corner angle is less than 90$^{\circ}$the flow asymptotically becomes rotational. For the corner angle larger than 90$^{\circ}$it tends to become irrotational. The general solution for the corner flow is then applied to rotational flows within a triangle (Method I). The error level depends on the geometry, and a parameter space is presented by which we can estimate the error level of solutions. On the other hand, Method II employing three separate coordinate systems is developed. The error level given by Method II is moderate but less dependent on the geometry.

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최적 부하절체 알고리듬을 적용한 연속조류계산의 향상 (Improvement of Continuation Power Flow System Applying the Optimal Load Shedding Algorithm)

  • 송화창;이병준;권세혁
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1998년도 하계학술대회 논문집 C
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    • pp.899-901
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    • 1998
  • Continuation power flow is a tool that can trace the path of the solution from the base stable solution. However, the base stable solution cannot be calculated when the initial system load is too large to operate at a stable operating point. This case is called as unsolvable case. This paper presents implementation of the optimal load shedding algorithm on continuation power flow. It performs steady-state analysis of power systems at unsolvable case that can occur in contingency analysis. Numerical simulation on 20-bus test system demonstrates that the continuation power flow applying the optimal load shedding algorithm is robust at solvable and unsolvable cases.

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비점성 정체 유동 응고 문제에 대한 이론적 해석 (A theoretical analysis on the inviscid stagnation-flow solidification problem)

  • 유주식
    • 설비공학논문집
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    • 제12권1호
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    • pp.1-11
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    • 2000
  • This study investigates the problem of phase change from liquid to solid in the inviscid stagnation flow. The solution of dimensionless governing equations is determined by the three dimensionless parameters of (temperature ratio/conductivity ratio), Stefan number, and diffusi-vity ratio. The solution at the initial stage of freezing is obtained by expanding it in powers of time, and the final equilibrium state is determined from the steady-state governing equations. The equilibrium state is dependent on (temperature ratio/conductivity ratio), but is independent of Stefan number and diffusivity ratio. The effect of fluid flow on the pure conduction problem can be clearly seen from the solution of the initial stage and the final equilibrium state, and the characteristics of the solidification process for all the dimensionless parameters are elucidated.

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An Experimental Study on the Frost Prevention using Micro Liquid Film of an Antifreeze Solution

  • Chang Young-Soo;Yun Won-Nam
    • International Journal of Air-Conditioning and Refrigeration
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    • 제14권2호
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    • pp.66-75
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    • 2006
  • The effect of antifreeze solution liquid film on the frost prevention is experimentally investigated. It is desirable that the antifreeze solution spreads widely on the heat exchanger surface forming thin liquid film to prevent frost nucleation while having small thermal resistance across the film. A porous layer coating technique is adopted to improve the wettability of the antifreeze solution on a parallel plate heat exchanger. The antifreeze solution spreads widely on the heat exchanger surface with $100{\mu}m$ thickness by the capillary force resulted from the porous structure. It is observed that the antifreeze solution liquid film prevents a parallel plate heat exchanger from frosting. The reductions of heat and mass transfer rate caused by the thin liquid film are only $1{\sim}2%$ compared with those for non-liquid film surface.

A Study on Inactivation of Pathogenic Bacteria for Nutrient Solution Recycling Using Advanced Oxidation Processes

  • Jang, Gwan-Soon;Nam, Yi
    • 한국토양비료학회지
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    • 제50권5호
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    • pp.489-496
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    • 2017
  • This study was conducted to test the applicability of hydroxy radical reactor system, which applied advanced oxidation processes, to sterilize pathogenic bacteria for nutrient solution recycling in closed hydroponics. Removal efficiency was tested on 25 L of nutrient solution maxed with 10 mL culture solution of bacteria, E. coli, and R. solanacearum in a pilot tank. The testing conditions included various levels of hydroxy radicals resulting from air flow rates of 40, 80, and $120L\;min^{-1}$, and 12 hours processing time. The removal of bacteria, E. coli, and R. solanacearum by hydroxy radical in nutrient solution was significantly increased with an increase in the flow rate of the air from $40L\;min^{-1}$ to $120L\;min^{-1}$. The optimum removal efficiency was achieved at an air flow rate of $120L\;min^{-1}$ for 2 hours treatment. There were no significant differences in removal efficiency among bacteria, E. coli, and R. solanacearum for tested level and time of hydroxy radical. These results verified the efficiency of hydroxy radical in removing the pathogenic bacteria and the applicability of hydroxy radical reactor system in the field.

수경재배 온실의 양액냉각시스템 개발 (Development of Nutrient Solution Cooling System in Hydroponic Greenhouse)

  • 남상운;김문기
    • 한국농공학회지
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    • 제36권3호
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    • pp.113-121
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    • 1994
  • Since it is difficult to expect the normal production of plants in greenhouses during hot summer season in Korea, certain provisions on the control of extreme environmental factors in summer should be considered for the year-round cultivation in greenhouses. This study was carried out to find a method to suppress the temperature rising of nutrient solution by cooling, which is able to contribute to the improvement of the plant growth environment in hydroponic greenhouse during hot summer season. A mechanical cooling system using the counter flow type with double pipe was developed for cooling the nutrient solution efficiently. Also the heat transfer characteristics of the system was analysed experimentally and theoretically, and compared with the existing cooling systems of nutrient solution. The cooling capacities of three different Systems, which used polyethylene tube in solution tank, stainless tube in solution tank, and the counter flow type with double pipe, were evaluated. The performance of each cooling system was about 41 %, 70% and 81 % of design cooling load in hydroponic greenhouse of 1 ,000m$^2$ on the conditions that the flow rate of ground water was 2m$^3$/hr and the temperature difference between two liquids was 10 ˚C According to the results analysed as above, the cooling system was found to have a satisfactory cooling capability for regions where ground water supply is available. Fer the other regions where ground water supply is restricted, more efficient cooling System should be developed.

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흐름과 진행파에 의한 해저지반 내 잔류간극수압의 해석해 (An Analytical Solution of Flow and Progressive Wave-Induced Residual Pore Water Pressure in Seabed)

  • 이광호;김동욱;강기천;김도삼;김태형
    • 한국지반공학회논문집
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    • 제31권7호
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    • pp.13-28
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    • 2015
  • 본 연구에서는 잔류간극수압의 추정에 관한 기존의 해석해에서 지적된 오류를 수정한 Lee et al.(2015a)의 연구결과를 진행파와 흐름의 공존장으로 확장한다. 이 때, 흐름이 없는 경우를 대상으로 한 Lee et al.(2015a)의 이론결과에 흐름에 의한 입사파의 주기와 파장의 변화를 고려하여야 한다. 검증에서는 Laplace 변환법으로부터 무한 두께의 경우에 대해서만 해를 제시한 Jeng and Seymour(2007)의 해석해와 Fourier 급수전개법에 의한 본 해석해의 두 결과를 비교하여 각각 상이한 형태를 갖는 두 해석해의 결과가 완전히 동일하다는 것을 확인할 수 있었다. 따라서, 유한, 무한 및 얕은 두께의 해저지반에 대한 각 해석해에 흐름속도의 크기와 방향, 지반두께 및 입사파 주기 등을 변화시켜 잔류간극수두의 변화특성을 면밀히 분석 검토하였다. 제시되는 각 해석해에서 지반두께의 변화에 의해 유한 두께의 토층에서 얕은 두께로의 점근적인 접근은 가능하지만, 무한 두께로의 접근은 불가능하며, 유한 두께와 무한 두께의 사이에는 동일한 토층 두께에 대해서도 서로의 결과가 일치하지 않는 경우가 있다는 것을 확인할 수 있었다.