• Title/Summary/Keyword: Solution flow

Search Result 3,119, Processing Time 0.039 seconds

A Study on Industrial Preparation Method of Ammonium Sulfate by Non-catalytic Oxidation (無觸媒酸化에 依한 黃酸암모늄의 工業的 製法에 關한 硏究)

  • Chung, Ki-Yong
    • Journal of the Korean Chemical Society
    • /
    • v.10 no.2
    • /
    • pp.76-90
    • /
    • 1966
  • Ammonium sulfate synthesized by the air oxidation methods without catalyst using the reaction vessel which was fitted with fritted glass at the bottom of it and introducing, through the bottom, ammonia and air with constant flow rates to sulfurous acid solution of constant concentrations at the given temperatures. The experiment showed that the oxidation process was accelerated in accord with the increase of the air flow rates when the ammonia flow rate was constantly kept at ca. 100ml/min. in high temperatures. When the pH of the solution reached 9.0, the oxidation was nearly completed. It is assumed that in the process of reaction, $[O_{2}{\to}HSO_{3}^-]^{\neq}$ would be produced as an activated complex and the reaction was thought to be first order. The experiment indicated that the 0.5M sulfurous solution could be oxidized up to 98.54% at the flow rates of ammonia and air, 100ml/min., and 4l/min., respectively at $50^{\circ}C$.

  • PDF

Electrochemical Degradation of Benzoquinone in a Flow through Cell with Carbon Fibers

  • Yoon, Jang-Hee;Yang, Jee-Eun;Shim, Yoon-Bo;Won, Mi-Sook
    • Bulletin of the Korean Chemical Society
    • /
    • v.28 no.3
    • /
    • pp.403-407
    • /
    • 2007
  • The anodic degradation of benzoquinone(BQ), a model compound for wastewater treatment was carried out using a home-made flow-through electrochemical cell with carbon fibers. To optimize the controlled current electrolysis condition of an aqueous BQ solution, the experimental variables affecting the degradation of BQ, such as the applying current, pH, reaction time, and flow rate of the BQ solution were examined. The degradation products of the oxidation reaction were identified by High Performance Liquid Chromatography and Inductively Coupled Plasma Atomic Emission Spectrometer. Low molecular weight aliphatic acids, and CO2 were the major products in this experiment. The removal efficiency of BQ from the solution increased with the applying current and time. 99.23% of 1.0 × 10-2 M BQ was degraded to aliphatic acids and CO2 when the applying current is 175 mA in a 12 hr electrolysis.

An Asymptotic Analysis on the Inviscid Plane Stagnation-flow Solidification Problem (비점성 평면 정체 유동 응고 문제에 대한 점근적 해석)

  • Yoo, Joo-Sik;Eom, Yong-Kyoon
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.24 no.6
    • /
    • pp.792-801
    • /
    • 2000
  • The problem of phase change from liquid to solid in the inviscid plane-stagnation flow is theoretically investigated. The solution at the initial stage of freezing is obtained by expanding it in powers of time, and the final equilibrium state is determined from the steady-state governing equations. The transient solution is dependent on the three dimensionless parameters, but the equilibrium state is determined by one parameter of (temperature ratio/conductivity ratio). The effect of the fluid flow on the growth rate of the solid in the pure conduction problem can be clearly seen from the solution of the initial stage and the final equilibrium state. The characteristics of the transient heat transfer at the surface of the solid and the liquid side of the solid-liquid interface for all the dimensionless parameters are elucidated.

Inviscid Rotational Flows Near a Corner and Within a Triangle

  • Suh, Yong-Kweon
    • Journal of Mechanical Science and Technology
    • /
    • v.15 no.6
    • /
    • pp.813-820
    • /
    • 2001
  • Solutions of inviscid rotational flows near the corners of an arbitrary angle and within a triangle of arbitrary shapes are presented. The corner-flow solutions has a rotational component as a particular solution. The addition of irrotatoinal components yields a general solution, which is indeterminate unless the far-field condition is imposed. When the corner angle is less than 90$^{\circ}$the flow asymptotically becomes rotational. For the corner angle larger than 90$^{\circ}$it tends to become irrotational. The general solution for the corner flow is then applied to rotational flows within a triangle (Method I). The error level depends on the geometry, and a parameter space is presented by which we can estimate the error level of solutions. On the other hand, Method II employing three separate coordinate systems is developed. The error level given by Method II is moderate but less dependent on the geometry.

  • PDF

Improvement of Continuation Power Flow System Applying the Optimal Load Shedding Algorithm (최적 부하절체 알고리듬을 적용한 연속조류계산의 향상)

  • Song, Hwa-Chang;Lee, Byong-Jun;Kwon, Sae-Hyuk
    • Proceedings of the KIEE Conference
    • /
    • 1998.07c
    • /
    • pp.899-901
    • /
    • 1998
  • Continuation power flow is a tool that can trace the path of the solution from the base stable solution. However, the base stable solution cannot be calculated when the initial system load is too large to operate at a stable operating point. This case is called as unsolvable case. This paper presents implementation of the optimal load shedding algorithm on continuation power flow. It performs steady-state analysis of power systems at unsolvable case that can occur in contingency analysis. Numerical simulation on 20-bus test system demonstrates that the continuation power flow applying the optimal load shedding algorithm is robust at solvable and unsolvable cases.

  • PDF

A theoretical analysis on the inviscid stagnation-flow solidification problem (비점성 정체 유동 응고 문제에 대한 이론적 해석)

  • 유주식
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
    • /
    • v.12 no.1
    • /
    • pp.1-11
    • /
    • 2000
  • This study investigates the problem of phase change from liquid to solid in the inviscid stagnation flow. The solution of dimensionless governing equations is determined by the three dimensionless parameters of (temperature ratio/conductivity ratio), Stefan number, and diffusi-vity ratio. The solution at the initial stage of freezing is obtained by expanding it in powers of time, and the final equilibrium state is determined from the steady-state governing equations. The equilibrium state is dependent on (temperature ratio/conductivity ratio), but is independent of Stefan number and diffusivity ratio. The effect of fluid flow on the pure conduction problem can be clearly seen from the solution of the initial stage and the final equilibrium state, and the characteristics of the solidification process for all the dimensionless parameters are elucidated.

  • PDF

An Experimental Study on the Frost Prevention using Micro Liquid Film of an Antifreeze Solution

  • Chang Young-Soo;Yun Won-Nam
    • International Journal of Air-Conditioning and Refrigeration
    • /
    • v.14 no.2
    • /
    • pp.66-75
    • /
    • 2006
  • The effect of antifreeze solution liquid film on the frost prevention is experimentally investigated. It is desirable that the antifreeze solution spreads widely on the heat exchanger surface forming thin liquid film to prevent frost nucleation while having small thermal resistance across the film. A porous layer coating technique is adopted to improve the wettability of the antifreeze solution on a parallel plate heat exchanger. The antifreeze solution spreads widely on the heat exchanger surface with $100{\mu}m$ thickness by the capillary force resulted from the porous structure. It is observed that the antifreeze solution liquid film prevents a parallel plate heat exchanger from frosting. The reductions of heat and mass transfer rate caused by the thin liquid film are only $1{\sim}2%$ compared with those for non-liquid film surface.

A Study on Inactivation of Pathogenic Bacteria for Nutrient Solution Recycling Using Advanced Oxidation Processes

  • Jang, Gwan-Soon;Nam, Yi
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.50 no.5
    • /
    • pp.489-496
    • /
    • 2017
  • This study was conducted to test the applicability of hydroxy radical reactor system, which applied advanced oxidation processes, to sterilize pathogenic bacteria for nutrient solution recycling in closed hydroponics. Removal efficiency was tested on 25 L of nutrient solution maxed with 10 mL culture solution of bacteria, E. coli, and R. solanacearum in a pilot tank. The testing conditions included various levels of hydroxy radicals resulting from air flow rates of 40, 80, and $120L\;min^{-1}$, and 12 hours processing time. The removal of bacteria, E. coli, and R. solanacearum by hydroxy radical in nutrient solution was significantly increased with an increase in the flow rate of the air from $40L\;min^{-1}$ to $120L\;min^{-1}$. The optimum removal efficiency was achieved at an air flow rate of $120L\;min^{-1}$ for 2 hours treatment. There were no significant differences in removal efficiency among bacteria, E. coli, and R. solanacearum for tested level and time of hydroxy radical. These results verified the efficiency of hydroxy radical in removing the pathogenic bacteria and the applicability of hydroxy radical reactor system in the field.

Development of Nutrient Solution Cooling System in Hydroponic Greenhouse (수경재배 온실의 양액냉각시스템 개발)

  • 남상운;김문기
    • Magazine of the Korean Society of Agricultural Engineers
    • /
    • v.36 no.3
    • /
    • pp.113-121
    • /
    • 1994
  • Since it is difficult to expect the normal production of plants in greenhouses during hot summer season in Korea, certain provisions on the control of extreme environmental factors in summer should be considered for the year-round cultivation in greenhouses. This study was carried out to find a method to suppress the temperature rising of nutrient solution by cooling, which is able to contribute to the improvement of the plant growth environment in hydroponic greenhouse during hot summer season. A mechanical cooling system using the counter flow type with double pipe was developed for cooling the nutrient solution efficiently. Also the heat transfer characteristics of the system was analysed experimentally and theoretically, and compared with the existing cooling systems of nutrient solution. The cooling capacities of three different Systems, which used polyethylene tube in solution tank, stainless tube in solution tank, and the counter flow type with double pipe, were evaluated. The performance of each cooling system was about 41 %, 70% and 81 % of design cooling load in hydroponic greenhouse of 1 ,000m$^2$ on the conditions that the flow rate of ground water was 2m$^3$/hr and the temperature difference between two liquids was 10 ˚C According to the results analysed as above, the cooling system was found to have a satisfactory cooling capability for regions where ground water supply is available. Fer the other regions where ground water supply is restricted, more efficient cooling System should be developed.

  • PDF

An Analytical Solution of Flow and Progressive Wave-Induced Residual Pore Water Pressure in Seabed (흐름과 진행파에 의한 해저지반 내 잔류간극수압의 해석해)

  • Lee, Kwang-Ho;Kim, Dong-Wook;Kang, Gi-Chun;Kim, Do-Sam;Kim, Tae-Hyung
    • Journal of the Korean Geotechnical Society
    • /
    • v.31 no.7
    • /
    • pp.13-28
    • /
    • 2015
  • This study extended the Lee et al.'s (2015a) solution which improved the existing analytical solution for prediction of the residual pore water pressure into progressive wave and flow coexisting field. At this time, the variation of incident wave period and wave length should be incorporated to Lee et al.'s (2015a) analytical solution, which does not consider flow. For the case of infinite thickness, the new analytical solution using Fourier series was compared to the analytical solution using Laplace transformation proposed by Jeng and Seymour (2007). It was verified that the new solution was identical to the Jeng and Seymour's solution. After verification of the new analytical solution, the residual pore water pressure head was examined closely under various given values of flow velocity's magnitude, direction, incident wave's period and seabed thickness. In each proposed analytical solution, asymptotic approach to shallow depth with the changes in the soil thickness within finite soil thickness was found possible, but not to infinite depth. It is also identified that there exists a discrepancy case between the results obtained from the finite and the infinite seabed thicknesses even on the same soil depth.