• Journal of the Korean institute of surface engineering
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• v.56 no.5
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• pp.289-298
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• 2023

In this study, the effect of drying temperature on characteristics of the trivalent chromate film on electroplated zinc was investigated. An zinc-electroplated iron specimen with a thickness of 5 ㎛ was used for chromate treatment. Chromate treatment was conducted in a solution diluted 10 times from a mixture of Cr(NO₃)₃·9H₂0 360 g/L, Co(NO₃)₂·6H₂O 60 g/L, Na₂SO₄ 60 g/L, NH₄F·HF 25 g/L, and NaOH 20 g/L. The zinc electroplated specimen was treated using the chromate solution with pH 2.0 at 25 ℃ for 60 s. Subsequently, chromate-treated samples were dried in an electric furnace for 2h with temperature varied from 25 to 125 ℃. The corrosion rate increased with the increase in the drying temperature, and the surface morphology of the chromate-treated film was observed using FE-SEM. When the drying temperature changed, the color of the chromate film changed from green to yellow, and the thickness of the film changed from 362 to 241 nm, respectively. Additionally, corrosion resistance was evaluated via a salt spray test.

• Journal of the Korean institute of surface engineering
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• v.27 no.3
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• pp.158-165
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• 1994

Cu-Cr alloy thin film requires good quality of etching be used for TAB technology. The etched cross sec-tion was clean enough when the etching was performed in 0.1M $FeCl_3$ solution at $50^{\circ}C$. The etching rate was increased with the amount of $KMnO_4$. For enhanced profile of cross section and rate, the spray etchning was found to be superior compared to the immersion etching. A series of experiments were performed to improve the uniformity of the current distribution in electrodeposition onto the substrate with lithographic patterns. Copper was electrodeposited from quiescent-solution, paddle-agitated-solution, and air-bubbled-solution to in-vestigate the effect of the fluid flow. The thickness profile of the specimen measured by profilmetry has the non uniformity at feature scale in quiescent-solution, because of the longitudinal vortex roll caused by the natural convection. However, uniform thickness profile was achieved in paddle-agitated or air bubbled solu-tion.

• 한국전산유체공학회:학술대회논문집
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• 2009.04a
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• pp.363-367
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• 2009

Recently, the manufacturing of micro-cavity by means of laser surface texturing (LST) technique and low friction study by the LST have been in great progress. Most of current works have been dealing with the effect of cavity on friction and wear. The main objective of the present study was to investigate numerically two-dimensional lubrication characteristics of micro-dimple shapes fabricated on solid surfaces, and this study utilized the commercial CFD code (Fluent V.6.3). For the evaluation, preliminary simulation was conducted and numerical predictions were compared with the analytic solution obtained from the Reynolds's equation. Mainly, the present study investigated the influence of dimple depth, pattern shapes, and film thickness on lubrication characteristics related to the reduction of friction. It is found that the existence of micro-dimpled surface makes it possible to substantially reduce the friction forces exerted on the surfaces. In particular, substantial decrease in shear stresses was observed as the lubricant film thickness decreases. For instance, in the case of the film thickness of 0.01 mm, the estimated shear stress decreases up to about 40%. It indicates that the film thickness would be important factor in designing the micro-dimpled surfaces. Furthermore, it was observed that such a optimum dimple depth would be present because the dimple depth larger than the optimum value did no longer affect the reduction in shear stresses.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.12 no.7
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• pp.642-648
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• 2000

Falling film heat transfer analyses with aqueous lithium bromide solution were peformed to investigate the transfer characteristics of the copper tubes. Finned(knurled) tube and a smooth tube were selected as test specimens. Averaged generation fluxes of water and the heat transfer performances(heat flux, heat transfer coefficient) were obtained. The results of this work were compared with the data reported previously. As the film flow rate of the solution increased, the generation fluxes of water decreased for both tubes. The reason is estimated by the fact that the heat transfer resistance with the film thickness increased as the film flow rate increased. The effect of the enlarged surface area at the knurled tube was supposed to be dominant at a small flow rate. The generation fluxes of water increased with the increasing degree of tube wall superheat. Nucleate boiling is supposed to occur at a wall superheat of 20 K for a smooth tube, and at 10 K for a knurled tube. The heat transfer performance of the falling film was superior to pool boiling at a low wall superheat below 10 K for both tubes tested. The knurled tube geometry showed good performance than the smooth tube, and the increased performance was mainly came from the effect of the increased heating surface area.

• Journal of Biomedical Engineering Research
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• v.6 no.1
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• pp.13-18
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• 1985

A solution scheme for the squeeze film problem using the Newton-Raphson method with a tangential matrix is presented. The integration of elasticity equation is done with the aid of isoparametric elements and the film thickness under a sinusoidal load is obtained. A new squeeze-suction phenomenon which shoㅁvs the possibility oi maintaining fluid film under cyclic positive load conditions is observed for small load and Period and large compliance parameter cases. Thia could be an interesting result in applications like the viscous hydroplaning and the biological joints.

• Transactions of the Korean Society of Automotive Engineers
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• v.3 no.6
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• pp.55-68
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• 1995

Approximately 30 to 70 % of the mechanical losses in a reciprocating engine are contributed by the friction at the piston ring-cylinder interface. The friction characteristics of the piston ring during engine operation is known to as mixed lubrication experimentally. The mixed lubrication models based on the Average Reynolds Equation have been used by this time in order to study the tribological performance of the ring. However, the Average Reynolds Equation contains the expected value term(${\bar{h}}_r$) of local film thickness as well as nominal film thickness(h), so that the work of numerically solving ${\bar{h}}_r$ must be included to obtain the pressure in the oil film. The process of solving ${\bar{h}}_T$ causes a greater multiplying in the numerical solution. In this paper the mixed lubrication analysis using the Simplified Average Reynolds Equation in the piston ring is presented. This equation has only h as oil film thickness term. Therefore the tedious numerical procedure required to obtain ${\bar{h}}_T$ is not needed, and also, computation time can be reduced.

• Transactions of the Korean Society of Mechanical Engineers
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• v.15 no.1
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• pp.120-126
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• 1991

An expanded scheme of a direct numerical solution method for solving the Navier-Stokes equation considering the modified boundary conditions for gas lubrication with ultra low clearance at high .LAMBDA. region is presented. Many examples are calculated by this scheme and their results are compared to the previous solutions using P$^{2}$H$^{[-992]}$ . This scheme has the advantages of fast calculation time and stable convergence in high .LAMBDA. region, and gives very good results in the case of fluid film thickness discontinuity.

• Journal of the Korean institute of surface engineering
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• v.53 no.2
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• pp.59-66
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• 2020

Effects of Na₂SiO₃ concentration added into 0.1 M NaOH + 0.05 M NaF solution on the formation behavior and properties of PEO films on AZ91 Mg alloy were investigated under 1200 Hz of alternating current (AC) by voltage-time curves, in-situ observation of arc generation behavior and measurements of film thickness, surface roughness and micro vickers hardness. In the absence of Na₂SiO₃ in the 0.1 M NaOH + 0.05 M NaF solution, about 4 ㎛ thick PEO film was formed within 1 min and then PEO film did not grow but white spots were formed by local burning. Addition of Na₂SiO₃ up to 0.2 M caused more increased formation voltage and growth of PEO film with uniform generation of arcs. Addition of Na₂SiO₃ from 0.2 M to 0.4 M showed nearly the same voltage-time behavior and uniform arc generation. Addition of Na₂SiO₃ more than 0.5 M resulted in a decrease of formation voltage and non-uniform arc generation due to local burning. PEO film growth rate increased with increasing added Na₂SiO₃ concentration but maximum PEO film thickness was limited by local burning if added Na₂SiO₃ concentration is higher than 0.5 M. Surface roughness of PEO film increased with increasing added Na₂SiO₃ concentration and appeared to be proportional to the PEO film thickness. PEO film hardness increased with increasing added Na₂SiO₃ concentration and reached a steady-state value of about 930 H_V at more than 0.5 M of added Na₂SiO₃ concentration.

• Proceedings of the KSME Conference
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• 2003.11a
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• pp.90-96
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• 2003

Numerical analyses have been performed to obtain the absorption heat and mass transfer coefficients and the absorption mass flux from a falling film of LiBr solution. In the present study, the behavior of laminar-wavy falling film in the vertical absorber was studied analytically and experimentally. The change of absorption performance on mean film thickness, wave amplitude, wave celerity was analysed. The heat and mass transfer equations are solved simultaneously to give the temperature and concentration variations at the LiBr solution/refrigeration vapor interface and at the wall. Effects of uniform film, wavy film and film Reynolds number on the heat and mass transfer coefficients have been estimated. The analytical results of the uniform and wavy falling film in the bare tube was higher than experimental result for $Rd_{t}<100$. The absorption performance showed the maximum at the wavy film by the insert device(spring).

• Corrosion Science and Technology
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• v.7 no.1
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• pp.40-44
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• 2008

Passive metal forms an interfacial diffuse layer on the surface of passive film by its reaction with $H^+$ or $OH^-$ ions in solution depending on solution pH. There is a critical pH, called pH point of iso-selectivity ($pH_{pis}$) at which the nature of the diffuse layer is changed from the anion-permeable at pH<$pH_{pis}$ to the cation-permeable at pH>$pH_{pis}$. The $pH_{pis}$ for a passivated Fe was determined by examining the effects of pH on the thickness of passive film and on the dissolution reaction occurring on the passive film under a gavanostatic reduction in borate-phosphate buffer solutions at various pH of 7~11. The steady-state thickness of passive film formed on Fe showed the maximum at pH 8.5~9, and further the nature of film dissolution reaction was changed from a reaction producing $Fe^{3+}$ ion at $pH\leq8.5$ to that producing $FeO_2{^-}$ at $pH\geq9$, suggesting that the $pH_{pis}$ of Fe is about pH 8.5~9. In addition, the passive film formed at pH 8.5~9, $pH_{pis}$, was found to be the most protective with the lowest defect density as confirmed by the Mott-Schottky analysis. Pitting potential was decreased with increasing $Cl^-$ concentration at $pH\leq8.5$ due probably to the formation of anion permeable diffuse layer, but it was almost constant at $pH\geq9$ irrespective of $Cl^-$ concentration due primarily to the formation of cation permeable diffuse layer on the film, confirming again that $pH_{pis}$ of Fe is 8.5~9.