• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 1998.11a
• /
• pp.41-47
• /
• 1998

The solvent flushing apparatus for soil remediation was manufactured. After the soil around nuclear facilities was sampled and was compulsorily contaminated by Co, the remediation characteristics by solvent flushing were analyzed. Meanwhile, one-dimensional solute transport within nonequilibrium sorption code was developed for modelling of the soil remediation, input parameters for modelling were measured by laboratory experiment. Experimental results are as follows : When water was used as a solvent, the higher was the hydraulic conductivity, the higher the efficiency of soil remediation was. When EDTA solution was used as a solvent, the soil remediation efficiency of EDTA solution showed higher than that of water.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 1997.05a
• /
• pp.79-82
• /
• 1997

토양내에서 오염유기물질이 불포화토양내에 유입될 때의 dispersion coefficient를 adsorption과 desorption과정에 대해 알아보았다. apparent dispersion coefficient를 측정하기 위해 일상적인 상대습도(46%)조건에서 parametric analysis를 행하였다. 실험에 사용된 토양은 fine sand와 silt-clay혼합시료였고, 흐름방향은 상향과 하향으로 하였다. 그리고, Freon gas를adsorbing solute로 사용하였다. 오염물질로는 DCM, TCE, DCB를 사용하였다. 분석을 위해서 linear와 probability scale의 breakthrough curve를 사용하였다. 공기에서의 diffusion coefficient의 예측을 위하여 Graham's law를 계산에 사용하였고, DCM diffusion coefficient는 0.098$\textrm{cm}^2$/s로 계산되었다. 연구결과, adsorption과 desorption의 속도는 차이가 있는 것으로 나타났으며, diffusion이 flow regime을 좌우하는 것으로 나타났다. 그리고, desorption에서의 D$^{a}$ D$^{o}$ 는 1보다 클수도 있다. 또한, dispersion은 silt-clay혼합시료에서의 속도와 함께 증가한다. dispersion은 Freon의 sorption방향에 크게 의존한다.

• Journal of Environmental Impact Assessment
• /
• v.11 no.3
• /
• pp.173-187
• /
• 2002

토양 속에서 발생될 수 있는 용질과 용매의 복합 수송시스템을 대상으로 한 연구 중 회석상태로부터 포화상태에 이르기까지의 넓은 농도분포를 가지는 토양 용액에 적용될 수 있는 물리 화학적 이론에 입각한 지배방정식을 발표한 연구는 전무한 실정이다. 본 연구는 용매와 토양기체간 그리고 용질과 결정간의 상변화를 고려한 연립물질수지방정식을 제시하고, 여기에 타율적 대류를 포함하는 상호확산 분산수송방정식을 도입하여 대류와 확산에 관한 프럭스를 분리, 결정하는 것을 목적으로 한다. 대류 플럭스의 결정은 타율적으로 이루어지는 것이 이론적으로 타당하며, 이러한 타율적 대류 플럭스가 제공된다면 본 연구에서 제시된 지배방정식을 이용해서 토양용액의 복합수송 시스템을 범용적으로 해석, 예측할 수 있을 것으로 판단된다.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2005.04a
• /
• pp.316-319
• /
• 2005

Contaminated area should be identified for designing polluted groundwater cleanup plan. A methodology was suggested to identify a contaminant plume distribution geostatistically. James & Gorelick (1994) suggested a methodology to evaluate data worth as expected reducing remediation cost. In this study, their methodology was modified to evaluate data worth as expected reducing uncertainty of the contaminant plume distribution. In suggested methodology, the source identification model by Mahar & Datta (2001) using a forward solute transport model is integrated. Suggested methodology was assessed by two simple example problems and its result represented reducing uncertainties of contaminant plume distribution successfully.

• Water Engineering Research
• /
• v.1 no.3
• /
• pp.171-185
• /
• 2000

A mathematical model to adequately predict complex mixing characteristics of sorptive polluants in natural streams with pools-and-riffes has been developed. In this model, sorption of pollutants onto the bed sediment as well as mass storage and exchange in the storage zones were incorporated into one-dimensional mass balance equatins. The geometric and hydraulic characteristics of the pool-riffle sequences were properly conceptualized. Simulations with parameters of pool-and-riffle streams better fit the measured data in overall shape and peak concentration than simulations with parameters for uniform channels. The analyses on the characteristics of the storage zone model parameters reveal that a linear relationship between the logrithm of the storage zone volume ratio and a function of the friction factor exists. A linear relatiohship might also be tenatively assumed between the logarithm of the dimensionless mass exchange coefficient and the logarithm of the aspect ratio of the storage zone if some of the high values of the dimensionless mass exchange coefficient collected on the successive bed forms are excluded.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2007.05a
• /
• pp.403-407
• /
• 2007

본 연구에서는 개수로 흐름에서의 오염물질 거동 특성에 대해 분석하였다. 이를 위해 개수로 흐름을 등류상태로 가정하여 3차원의 수직모형을 구성하고 운동량 방정식과 스칼라 수송방정식에서의 난류 폐합을 위해 레이놀즈응력 모형 및 GGDH 모형을 사용하였다. 개발된 모형을 이용하여 복단면 수로에서 오염물질이 점으로 주입된 경우에 대해 난류 흐름 및 오염물질의 농도 분포를 수치모의 하고 기존의 실험 데이터와 비교하였다. 그 결과 개발된 모형이 개수로 흐름에서의 평균유속 및 난류구조, 오염물질의 농도 분포 등을 잘 모의하는 것으로 나타났다. 특히, 이차흐름의 영향으로 인해 최대 농도 값의 위치가 거리에 따라 이동하는 것으로 나타났으며, 농도 분포 역시 정규분포에서 거리에 따라 점차 왜곡되는 것으로 확인되었다.

• Korean Membrane Journal
• /
• v.5 no.1
• /
• pp.54-60
• /
• 2003

The rejection properties and flux rates of silica nanoparticles in ultrafiltration membranes has been investigated. Cross-flow permeation experiments were conducted using polycarbonate track-etch flat membranes with pore sizes of 30 and 50 nm, and a silica nanoparticle solute with particle sizes of 5 and 18 nm with narrow size distributions. The fluxes and rejection factors were investigated at various particle concentrations, cross-flow velocities, pH, and ionic strengths of solution. Even though the size of the silica nanoparticles was much smaller than that of the membrane pores, the observed rejection rates were very high compared with those for a similar-sized polymer (dextran). The observed rejection rate decreased with increasing ionic strength, which implies that the transport mechanism of the silica nanoparticles is significantly influenced by electrostatic repulsion between particles and membranes.

• Nuclear Engineering and Technology
• /
• v.30 no.6
• /
• pp.485-495
• /
• 1998

Migration characteristics of tracers in a rock fracture in a case of line-source and line-collection was studied. The fracture plane was discretized into a square mesh to which variable apertures were assigned. The spatially varying apertures of a fracture were generated using a geostatistical method, based on a given aperture probability density distribution and a specified spatial correlation length. The flow potential and pressure at each node were computed. Calculations showed that fluid flow occurs predominantly through a few preferred paths. Hence, the large range of apertures in the fracture gives rise to flow channeling. The solute transport was calculated using a particle tracking method. The migration plumes of tracer between injection line and withdrawal line are displayed in contour plots. The elution curves are shown to be controlled by the aperture density distribution and to be insensitive to statistical realization and spatial correlation length.

• Korean Journal of Soil Science and Fertilizer
• /
• v.43 no.3
• /
• pp.275-282
• /
• 2010

The laboratory column experiments were used to transport of metal elements by infiltration-related dispersion and/or diffusion in mine tailing of the Guryong gold mine. The mine tailing shows the neutral pH (for a pore water) and contains quartz, chlorite, pyrite and calcite. Both a non-reactive solute ($Cl^-$ of 100 mg $L^{-1}$) and a reactive solute (1N HCl), were injected continuously through columns. The breakthrough curve in the non-reactive experiment reached at a maximum under 1.5 pore volumes (PV). The longitudinal dispersion (0.607 cm) and hydrodynamic dispersion coefficient ($1.96{\times}10^{-7}cm^{2}sec^{-1}$) were calculated by the slope. In the reactive experiment, the plateau curve was appeared in the pH values of 5.3, 4.5 and 1.7. The releases of metal elements such as Fe, Mn, Al, Cu, Zn, Pb, and Cd were observed to be related to the pH buffering. High concentrations of Mn, Cd and Zn were observed at the first pH plateau (4 PV and pH 5.3), whereas Fe, Cu, Al and Pb were released as the pH decreased to 4.0 or less. The resulting order of metals mobility, based on the effluent water, is Mn=Cd>Zn>Cu>Fe>Al>Pb.

• Proceedings of the Korea Water Resources Association Conference
• /
• 1998.05b
• /
• pp.3-3
• /
• 1998

In this pressentation it is argued that the heterogeneity of a hydrologic attribute which may seem to be nonstationary at one scale, may become stationary at a larger scale. The fundamental reason for transformation from nonstationarity to stationarity whith the increase in scale is the phenomenon of coarse-graining of the hydrologic processes with increasing scale. Due to the phenomenon of aliasing, a particular scale hydrologic process heterogeneity which is observed as a nonstationary process at that scale, may be observed as a stationary process at a higher(larger) scale whose size is bigger than the stationary extent of the lower scale heterogeneity. As one goes through a hierarchical sequence of larger and larger scales for observations, one would eliminate nonstationarities which emerge at some lower scales at the expense of losing information on the high frequency fluctuations of the lower scale heterogeneities which will no longer be observed at the larger sampling scales. We call this phenimenon as the "coarse-graining in hydrologic observations". In this presentation, it is also argued that by the coarse-graining of hydrologic processes due to the averaging and aliasing operations at increasing scales, the conservation laws corresponging to these scales may still be quite parsimonious, and need not be more complicated as the scales get larger. It is shown that shen a higher(larger) scale process is formed by averaging a lower(smaller) scale process in time or space, the high frequency components of the lower scale process will be eliminated by the averaging operation. Thereby, the resuliiting average hydrologic dynamics, free from the effects of the high frequency components of the lower scale process, can still be quite simple in form. This is demonstrated by means of some recent upscaling work on the solute teansport conservation equation for hetergeneous aquifers. By means of this solute transport example, it is also shown that for the ensemble average form of a hydrologic conservation equation to be equivalent to its volume-average form at any scale, the parameter functions of that conservation equation at the immediately lower scale must be ergodic.