• Title/Summary/Keyword: Solute resistivity for diffusion

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Structure Parameter Change Estimation of a Forward Osmosis Membrane Under Pressurized Conditions in Pressure-assisted Forward Osmosis (PAFO) (가압형 정삼투 시 압력에 따른 정삼투막의 Structure Parameter 변화양상 예측)

  • Kook, Seungho;Kim, Sung-Jo;Lee, Jinwoo;Hwang, Moonhyun;Kim, In S.
    • Membrane Journal
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    • v.26 no.3
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    • pp.187-196
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    • 2016
  • Pressure-assisted forward osmosis (PAFO) process has recently been under spotlight for its potential to improve forward osmosis (FO) process performance by applying low hydraulic pressure on the feed side. Structure parameter, one of the governing factors in estimating water flux and solute flux across FO membranes in the solution-diffusion model (S-D model), determines solute resistivity in FO and PAFO processes. This study aims to estimate the trend of structure parameter change with respect to varying additional hydraulic pressure condition in PAFO.

Evaluation of Forward Osmosis (FO) Membrane Performances in a Non-Pressurized Membrane System (비가압식 막 공정을 통한 정삼투막 성능 평가)

  • Kim, Bongchul;Boo, Chanhee;Lee, Sangyoup;Hong, Seungkwan
    • Journal of Korean Society on Water Environment
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    • v.28 no.2
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    • pp.292-299
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    • 2012
  • The objective of this study is to develop a novel method for evaluating forward osmosis (FO) membrane performances using a non-pressurized FO system. Basic membrane performance parameters including water (A) and solute (B) permeability coefficients and unique parameter for FO membrane such as the support layer structural parameter (S) were determined in two FO modes (i.e., active layer faces feed solution (AL-FS) and active layer faces draw solution (AL-DS)). Futhermore, these parameters were compared with those determined in a pressurized reverse osmosis (RO) system. Theoretical water flux was calculated by employing these parameters to a model that accounts for the effects of both internal and external concentration polarization. Water flux from FO experiment was compared to theoretical water fluxes for assessing the reliability of those parameters determined in three different operation modes (i.e., AL-FS FO, AL-DS FO, and RO modes). It is demonstrated that FO membrane performance parameters can be accurately measured in non-pressurized FO mode. Specifically, membrane performance parameters determined in AL-DS FO mode most accurately predict FO water flux. This implies that the evaluation of FO membrane performances should be performed in non-pressurized FO mode, which can prevent membrane compaction and/or defect and more precisely reflect FO operation conditions.

InP crystal growth by modified SSD method (변형된 SSD법에 의한 InP결정 성장)

  • 송복식;정성훈;문동찬;김선태
    • Electrical & Electronic Materials
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    • v.8 no.3
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    • pp.291-297
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    • 1995
  • The InP crystals have been grown by modified synthesis solute diffusion (SSD) method and its properties have been investigated. The crystals have been grown by lowering the crucible quartz for growth in the furnace and crystal growth rate is 1.8mm/day. The lattice constant a. of the grown crystals is 5.867.angs.. Etch pits density along growth direction of crystal changes from 3.0*10.sup 3/cm$\^$-2/ of first freeze part to 6.7*10$\^$4/cm$\^$-2/ of last freeze part and the radial direction of wafer shows nearly uniform distribution. The resistivity and the carrier concentration of the grown crystals are 1.43*10$\^$-1/.ohm.-cm, 7.7*10$\^$15/cm$\^$-3/ at room temperature, respectively. In the photolurninescence at 10K, the radiation transitions are observed by the near band edge recombination, a pair recombination due to Si donor - Zn acceptor and its phonon replica in the InP. The activation energy by Zn diffusion in undoped n-InP crystals is 1.22eV.

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