• Title/Summary/Keyword: Solute permeability

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Effect of cation on solute permeability of mitochondrial membrane (미토콘드리아막의 용질투과성에 미치는 양이온의 영향)

  • 이영녹;이종삼
    • Korean Journal of Microbiology
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    • v.9 no.4
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    • pp.145-148
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    • 1971
  • Mitochondria were isolated from Chlorella cells effects of cation on solute permeability of mitochondrial membrane were investigated using P$^{32}$ as a tracer. It was strikingly increased uptake of phosphate for NaCl, KCl, while evidently decreased phosphate uptake of mitochondrial membrane for $MgCl_2$, $CaCl_2$. This consider that uptake of monovalent cation were increased, but uptake of divalentcation were decreased for permeability of mitochondrial membrane as if the permeability of protoplasmic membrane.

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Transport Characteristics of Alcohol Solutes through Copolymer Hydrogel Membranes Containing Poly(2-Hydroxyethylmethacrylate) (Poly(2-Hydroxyethylmethacrylate)를 포함한 공중합체 수화겔막에 대한 알콜용질의 투과특성)

  • Park, Yu Mi;Kim, Eun Sik;Seong, Yong Gil
    • Journal of the Korean Chemical Society
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    • v.34 no.4
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    • pp.377-383
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    • 1990
  • Three kinds of hydrogel membranes were prepared by the copolymerization of 2-hydroxyethylmethacrylate (HEMA) with acrylamide, N, N-dimethylamide and methylmethacrylate in the presence of solvent and crosslinker respectively. The equilibrium water content, relative permeability and partition coefficient of the membranes for alcohol solutes were measured. It has been found that the permeation of organic solute occurs through the water-filled regions in the hydrogel membrane, and that the gpermeability coefficient of organic solute depends on the molecular size. But the permeability of organic solute was controlled by the interaction of solute-membrane at the low water content. By the partition data, it has been shown that the partition of solute is only controlled by hydrophobic interaction between solute and membrane. The diffusion coefficient data were interpreted on the basis of water-solute interaction. It has been found that the diffusion of organic solute is determined by the free volume of water in the membrane, and that hardly depends on polarity-polarizability and hydrogen bonding ability between water and solute.

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Evaluation of Forward Osmosis (FO) Membrane Performances in a Non-Pressurized Membrane System (비가압식 막 공정을 통한 정삼투막 성능 평가)

  • Kim, Bongchul;Boo, Chanhee;Lee, Sangyoup;Hong, Seungkwan
    • Journal of Korean Society on Water Environment
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    • v.28 no.2
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    • pp.292-299
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    • 2012
  • The objective of this study is to develop a novel method for evaluating forward osmosis (FO) membrane performances using a non-pressurized FO system. Basic membrane performance parameters including water (A) and solute (B) permeability coefficients and unique parameter for FO membrane such as the support layer structural parameter (S) were determined in two FO modes (i.e., active layer faces feed solution (AL-FS) and active layer faces draw solution (AL-DS)). Futhermore, these parameters were compared with those determined in a pressurized reverse osmosis (RO) system. Theoretical water flux was calculated by employing these parameters to a model that accounts for the effects of both internal and external concentration polarization. Water flux from FO experiment was compared to theoretical water fluxes for assessing the reliability of those parameters determined in three different operation modes (i.e., AL-FS FO, AL-DS FO, and RO modes). It is demonstrated that FO membrane performance parameters can be accurately measured in non-pressurized FO mode. Specifically, membrane performance parameters determined in AL-DS FO mode most accurately predict FO water flux. This implies that the evaluation of FO membrane performances should be performed in non-pressurized FO mode, which can prevent membrane compaction and/or defect and more precisely reflect FO operation conditions.

Effects of Dimethipin on the Osmotic Ground Value and Passive Permeability of Onion Epidermal Cells (Dimethipin이 양파 표피세포의 Osmotic Ground Value 및 Passive Permeability에 미치는 영향)

  • 문병용
    • Journal of Plant Biology
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    • v.31 no.2
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    • pp.113-119
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    • 1988
  • The effects of the defoliant and desiccant dimethipin(2,3-dihydro-5,6-dimethyl-1,4-dithiin-1,1,4,4-tetraoxide) on the passive permeability and osmotic ground value of onion(Allium cepa L.) epidermal cells were investigated by plasmometric method. The osmotic ground value and the water permeability of onion epidermal cells were decreased by 9.8% and 41.2%, respectively, and the passive permeabilities of nonelectrolytesurea, methylurea, ethylurea and malonamide-were also decreased by the range of 15.7%∼57.8% after treatment with 10-3M dimethipin. After treatment with 10-4M dimethipin, the osimotic ground value and the solute permeability of onion epidermal cells were also decreased by 3.7% and 24.5%∼48.8%, respectively, but the water permeability of onion epidermal cells was increased by 8.3%. It was suggested that dimethipin treatment modified the cell membrane of onion epidermis.

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Rejection Properties of Aromatic Pesticides by a Hollow Fiber NF Membrane (중공사 나노여과막을 이용한 방향족 농약의 배제 특성)

  • Jung, Yong-Jun;Kiso, Yoshiaki;Park, Soon-Gil;Kim, Jong-Yong;Min, Kyung-Sok
    • Journal of Korean Society on Water Environment
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    • v.20 no.3
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    • pp.296-300
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    • 2004
  • The rejection properties of 6 aromatic pesticides were evaluated by a continuous flow system equipped with a hollow fiber NF membrane. Different from the separation experiment of batch cell, the rejection and the removal could be calculated exactly because the concentration of feed, permeate and retentate was separately obtained. The lowest and the highest rejection were found in carbaryl(54.8%) and methoxychlor(99.2%), respectively, and the removals were always shown higher than rejections. This may be caused by some reasons such as the solute adsorption on the membrane, the variation of feed concentration. Although molecular weight, molecular width regarded as solute characteristics and log P(n-octanol/water partition coefficient) as hydrophobicity could be applied to explain the rejection property, these factors should be considered together for better analysis. According to the higher relationship between log B(solute permeability) and molecular weight, it was revealed that the solute separation with this membrane was influenced more by molecular weight.

The Effect of Storage Conditions on the Permeability of Porcine Buccal Mucosa

  • Lee, Jae-Hwi;Lww, Sang-Kll;Choi, Young-Wook
    • Archives of Pharmacal Research
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    • v.25 no.4
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    • pp.546-549
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    • 2002
  • The impact of storage conditions on the permeability of porcine buccal mucosa to [$^3H$]water and [$^{14}C$]mannitol was assessed. The fresh pocine buccal tissue (fresh tissue) was obtained by utilizing pig heads within 24 hours of slaughter. The stored and frozen porcine buccal tissues (stored tissue and frozen tissue) were obtained after the storage of the tissue intact in the pig heads at $4^{\circ}C$ or -$20^{\circ}C$, respectively, for 24 h. The results demonstrated that the barrier properties of the porcine buccal mucosa were maintained with regard to [$^3H$]water permeability when stored at $4^{\circ}C$ for 24 h. However, freezing the tissue resulted in tissue damage illustrated by a significant increase in [$^3$H]water permeability. [$^{14}C$]Mannitol does not appear to be a suitable model solute to assess the ex vivo permeability of porcine buccal mucosa due to its extremely low permeability.

A Study on the Groundwater Flow and Solute Transport in Discontinuous Rock Mass Using Fracture Network Analysis : An Estimation of Equivalent Permeability on Discontinuous Rock Mass (균열망 해석법을 이용한 불연속 암반의 지하수 유동 및 용질이동 연구 : 불연속 암반의 등가 투수계수 추정)

  • Ju, Kwang-Su
    • Proceedings of the Korean Society for Rock Mechanics Conference
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    • 2000.09a
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    • pp.129-137
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    • 2000
  • This paper presents groundwater flow characteristics in discontinuous rock mass using fracture network program(NAPSAC) by statistical approach. Equivalent permeability coefficients are estimated from borehole data around Mabuk test tunnel site and fracture map on the arch of the tunnel. The reliability of fracture network model is obtained from determination of input data for statistical fracture network analysis from the real data(data of fracture network, data of hydraulic tests). The variation of permeability and mean anisotropic permeability coefficients are calculated from the realized model by increasing the size. As a result of analysis, a strong anisotropy of permeability is observed according to the direction of the fracture sets around the test tunnel.

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A Study on the Groundwater Flow and Solute Transport in Discontinuous Rock Mass Using Fracture Network Analysis: An Estimation of Equivalent Permeability on Discontinuous Rock Mass (균열망 해석법을 이용한 불연속 암반의 지하수 유동 및 용질이동 연구: 불연속 암반의 등가 투수계수 추정)

  • 주광수
    • Tunnel and Underground Space
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    • v.10 no.3
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    • pp.378-386
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    • 2000
  • This paper presents groundwater flow characteristics in discontinuous rock mass using fracture network program(NAPSAC) by statistical approach. Equivalent permeability coefficients are estimated from borehole data around Mabuk test tunnel site and fracture map on the arch of the tunnel. The reliability of fracture network model is obtained from determination of input data for statistical fracture network analysis from the real data(data of fracture network, data of hydraulic tests). The variation of permeability and mean anisotropic permeability coefficients are calculated from the realized model by increasing the size. As a result of analysis, a strong anisotropy of permeability is observed according to the direction of the fracture sets around the test tunnel.

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Potassium Pentane-1,3,3,5-tetracarboxylate Draw Solute Synthesis and Application of Forward Osmosis Process (Potassium Pentane-1,3,3,5-tetracarboxylate 유도용질 합성 및 이를 이용한 정삼투 공정 응용)

  • Lee, Hye-Jin;Choi, Jin-Il;Kwon, Sei;Kim, In-Chul
    • Membrane Journal
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    • v.29 no.2
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    • pp.111-121
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    • 2019
  • An organic citrate series draw solute was synthesized using diethyl malonate for forward osmosis. The structure of the final compound potassium pentane-1,3,3,5-tetracarboxylate was confirmed by $^1H-NMR$ and $^{13}C-NMR$ analysis. Osmotic pressure, solubility, water permeability and reverse salt flux were measured for the properties of the draw solute. Forward osmosis results showed that the draw solute exhibited higher water flux than other draw solutes of trisodium citrate and tripotassium citrate. Reverse salt flux of all the organic daw solutes was much lower than that of NaCl. The osmotic pressure of the synthesized draw solute was 25% lower than that of NaCl. The solubility of the draw solute was 317 g/ 100 g water, which is 8.8 times higher than that of NaCl. A commercialized nanofiltration membrane was used for the recovery of the draw solute. The draw solute could be effectively recovered at low pressure.

The Transport Phenomena of Some Solutes through the Copolymer Membranes of 2-hydroxyethylmethacrylate (HEMA) with Selected Hydrophobic Monomers

  • Kim, Whan-Gun;Jhon, Mu-Shik
    • Bulletin of the Korean Chemical Society
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    • v.6 no.3
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    • pp.128-131
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    • 1985
  • A series of copolymer membranes of 2-hydroxyethylmethacrylate (HEMA) with selected hydrophobic monomers were prepared without crosslinking agents. The equilibrium water content, the partition coefficient, and the permeability of the solutes such as urea, methylurea, 1,3-di-methylurea, and acetamide via these membranes were measured. The partition coefficient data show that as the hydrophobicity of solutes increased, the partition of solutes were dictated by hydrophobic interaction between solute and polymer matrix. Diffusion coefficients obtained in these experiments decrease as the water content of polymer membrane decreases. This decrease is blunt as the excess heat capacities, ${\phi}C^0_p$ (excess) in aqueous solution at infinite dilution of solute increases. To investigate the relationship between water content and diffusion coefficient, the results of the diffusion experiments were examined in light of a free-volume model of diffusive transport. The remarkable increase of urea mobility in the polymer network containing relatively larger bulk water can be considered as water structure breaking effect.