• Title/Summary/Keyword: Solidification.

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A Study on the Properties of Grout Materials Based on Cement Type (시멘트계 주입재의 주입특성에 관한 연구)

  • 천병식;최중근
    • Journal of the Korean Geotechnical Society
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    • v.18 no.5
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    • pp.229-236
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    • 2002
  • In this study, the characteristics of chemical grouting, such as solidification, penetrability, were analyzed experimentally by grain size of grout materials and permeability, relative density of the ground. For evaluating applicability of grout material, solidification tests and permeability tests were peformed. From the results of the tests, effective solidification ratio and penetrability ratio of Micro Cement were 75% and 86% respectively when ground permeability was in the range of 10$^{-4}$ to 10$^{-2}$cm/sec. On the other hand, effective solidification ratio and penetrability ratio of Ordinary Portland Cement (OPC) were both lower than 50%. When penetrability of grout material is needed for improvement of dam foundation and soft ground, application of Micro Cement is much superior to that of the other materials. The results of the grouting tests in the hydrodynamic ground show that the solidification effect of long gel-time grout material is excellent as injection pressure increases when groundwater velocity is relatively low. But when groundwater velocity is relatively high, the solidifcation effect of long gel-time grout material is very poor because most grout materials are outflowed.

A Study on Microstructure Formation during Directional Solidification of a Hypoeutectic Al-11.3Si-3.5Cu alloy (아공정 Al-11.3Si-3.5Cu 합금의 응고조직 형성거동에 관한 연구)

  • Seo, Heesik;Gu, Jiho;Park, Kyungmi;Lee, Jeongseok;Lee, Jehyun;Chung, Wonsub
    • Korean Journal of Metals and Materials
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    • v.50 no.12
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    • pp.897-905
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    • 2012
  • Directional solidification experiments were carried out in a hypoeutectic Al-11.3Si-3.5Cu system to investigate the microstructural evolution with the solidification rate. At a fixed temperature gradient, a dendritic microstructure was observed at a constant speed of more than $25{\mu}ms^{-1}$, a cellular interface developed at $5{\mu}ms^{-1}$ and the growth rate of $0.5{\mu}ms^{-1}$ led to the stability of the planar interface. The results revealed that primary silicon phases formed among cells, even though the studied Al-Si alloy system formed the composition within a hypoeutectic silicon composition. This suggests that the liquid concentration among cells during solidification reached a higher concentration, i.e., the eutectic concentration. It is, however, interesting that primary silicon phases did not form during a dendritic growth of more than $25{\mu}ms^{-1}$. These experimental observations are explained using the theoretical models on the interface temperatures.

Segregation Phenomenon of As-Cast and Heat Treatment Microstructures in Investment Casting of IN738LC Superalloy (IN738LC 초내열합금 정밀 주조의 주조 및 열처리 미세조직에 구성되는 성분 편석 현상)

  • Choe, Byung Hak;Han, Sung Hee;Kim, Dae Hyun;Ahn, Jong Kee;Lee, Jae Hyun
    • Korean Journal of Materials Research
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    • v.31 no.7
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    • pp.409-419
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    • 2021
  • The effect of solidification rate on micro-segregation in investment casting of IN738LC superalloy was studied. In Ni-based superalloys, the micro-segregation of solute atoms is formed due to limited diffusion during cast and solidification. The microstructure of cast Ni-based superalloys is largely divided into dendrite core of initial solidification and interdendrite of final solidification. In particular, mosaic shaped eutectic γ/γ' and carbides are formed in the interdendrite of the final solidification region in some cases. The micro-segregation phenomena formed in regions of dendrite core and interdendrite including eutectic γ/γ' and carbides were analyzed using OM, SEM/EDS and micro Vickers hardness. As a result of analysis, the lack of (Cr, W) and the accumulation of Ti were measured in the eutectic γ/γ', and the accumulation of (Cr, Mo) and the lack of Ti were measured in the interdendrite between dendrite and eutectic. Carbides formed in interdendritic region were composed of (Ti, W, Mo, C). The segregation applied to each microstructure is mainly due to the formation of γ' with Ni3(Al,Ti) composition. The Ni accumulation accompanied by Cr depletion, and the Ti accumulated in the eutectic region as a γ' forming elements. The Mo tends to diffuse out from the dendrite core to the interdendrite, and the W diffuse out from the interdendrite to the dendrite core. Therefore, the accumulation of Mo in the interdendrite and the deficiency of W occur in the eutectic region located in the interdendrite. Heat treatment makes the degree of the micro-segregation decrease due to the diffusion during solid solution. This study could be applied to the heat treatment technology for the micro-segregation control in cast Ni-based superalloys.

Effect of Initial Solidification Condition During Directional Solidification on the Grain Growth and the Tensile Properties of Superalloy CM247LC (초내열합금 CM247LC의 조직 및 인장특성에 미치는 초기 일방향응고 조건의 영향)

  • Jeong, Jae Jun;Kwon, Seok Hwan;Jeong, Eui Seok;Jo, Chang Yong;Lee, Je Hyun
    • Journal of Korea Foundry Society
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    • v.42 no.2
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    • pp.77-82
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    • 2022
  • Initial solidification condition during directional solidification of superalloy CM247LC was controlled with various cooling methods such as insertion of alumina disc or Ni foil or inoculant, and direct pouring of melt onto chill plate. Rapid cooling with direct pouring of melt onto chill plate resulted in generation of many fine grains and precipitation of fine γ' particles, as well as small dendrite arm spacing. Tensile properties of directionally solidified superalloy CM247LC were closely related to microstructure which was governed by initial solidification conditions. Directionally solidified CM247LC with small dendrite arm spacing and fine precipitates showed good tensile properties.

Analysis of Physical and Chemical Properties of CFBC Fly Ash in Vietnam for Solidification (고화재 활용을 위한 베트남 CFBC 플라이애시의 물리적·화학적 특성 분석)

  • Min, Kyongnam;Lee, Jaewon;Lee, Dongwon;Kim, Jinhee;Jung, Chanmuk
    • The Journal of Engineering Geology
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    • v.27 no.3
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    • pp.245-253
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    • 2017
  • Vietnam CFBC fly ash has high CaO content and can be used as a solidification agent for soft ground improvement. However, most fly ash is treated as landfill or waste. In order to utilize fly ash as a solidification agent for soil improvement, the characteristics of fly ash must be accurately determined. In this study, laboratory tests were conducted on fly ash from four CFBC power plants to evaluate the utility of Vietnam fly ash as a solidification agent. As a result of analyzing the physical properties, it was analyzed that all four samples were suitable as material for solidification agent and have suitable particle size for the improvement of soft ground. As a result of analysis of chemical characteristics, it was analyzed that the fly ash of one place could be used as a solidification agent because of the high content of free-CaO. The remaining three fly ash was not suitable for use as a solidification agent due to low Free-CaO content. However, it has a chemical composition similar to that of general fly ash in Korea, so it can be recycled in various ways.

Numerical analysis of melt migration and solidification behavior in LBR severe accident with MPS method

  • Wang, Jinshun;Cai, Qinghang;Chen, Ronghua;Xiao, Xinkun;Li, Yonglin;Tian, Wenxi;Qiu, Suizheng;Su, G.H.
    • Nuclear Engineering and Technology
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    • v.54 no.1
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    • pp.162-176
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    • 2022
  • In Lead-based reactor (LBR) severe accident, the meltdown and migration inside the reactor core will lead to fuel fragment concentration, which may further cause re-criticality and even core disintegration. Accurately predicting the migration and solidification behavior of melt in LBR severe accidents is of prime importance for safety analysis of LBR. In this study, the Moving Particle Semi-implicit (MPS) method is validated and used to simulate the migration and solidification behavior. Two main surface tension models are validated and compared. Meanwhile, the MPS method is validated by the L-plate solidification test. Based on the improved MPS method, the migration and solidification behavior of melt in LBR severe accident was studied furthermore. In the Pb-Bi coolant, the melt flows upward due to density difference. The migration and solidification behavior are greatly affected by the surface tension and viscous resistance varying with enthalpy. The whole movement process can be divided into three stages depending on the change in velocity. The heat transfer of core melt is determined jointly by two heat transfer modes: flow heat transfer and solid conductivity. Generally, the research results indicate that the MPS method has unique advantage in studying the migration and solidification behavior in LBR severe accident.

Characterization of Cement Solidification for Enhancement of Cesium Leaching Resistance (세슘 침출 저항성 증진 시멘트 고화체의 제조 및 특성 평가)

  • Kim, Gi Yong;Jang, Won-Hyuk;Jang, Sung-Chan;Im, Junhyuck;Hong, Dae Seok;Seo, Chel Gyo;Shon, Jong Sik
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.2
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    • pp.183-193
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    • 2018
  • Currently, the Korea Atomic Energy Research Institute (KAERI) is planning to build the Ki-Jang Research Reactor (KJRR) in Ki-Jang, Busan. It is important to safely dispose of low-level radioactive waste from the operation of the reactor. The most efficient way to treat radioactive waste is cement solidification. For a radioactive waste disposal facility, cement solidification is performed based on specific waste acceptance criteria such as compressive strength, free-standing water, immersion and leaching tests. Above all, the leaching test is important to final disposal. The leakage of radioactive waste such as $^{137}Cs$ causes not only regional problems but also serious global ones. The cement solidification method is simple, and cheaper than other solidification methods, but has a lower leaching resistance. Thus, this study was focused on the development of cement solidification for an enhancement of cesium leaching resistance. We used Zeolite and Loess to improve the cesium leaching resistance of KJRR cement solidification containing simulated KJRR liquid waste. Based on an SEM-EDS spectrum analysis, we confirmed that Zeolite and Loess successfully isolated KJRR cement solidification. A leaching test was carried out according to the ANS 16.1 test method. The ANS 16.1 test is performed to analyze cesium ion concentration in leachate of KJRR cement for 90 days. Thus, a leaching test was carried out using simulated KJRR liquid waste containing $3000mg{\cdot}L^{-1}$ of cesium for 90 days. KJRR cement solidification with Zeolite and Loess led to cesium leaching resistance values that were 27.90% and 21.08% higher than the control values. In addition, in several tests such as free-standing water, compressive strength, immersion, and leaching tests, all KJRR cement solidification met the waste acceptance or satisfied the waste acceptance criteria for final disposal.

Experimental Study of Flow and Solidification Simulation for Thin Wall Stainless Steel Castings (박육 스테인리스 주강에 대한 유동 및 응고해석의 실험적 고찰)

  • Choi, Hak-Kyu;Park, Heung-Il;Jeong, Hae-Yong;Bae, Cha-Hurn;Choi, Byung-Kang
    • Journal of Korea Foundry Society
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    • v.20 no.5
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    • pp.344-353
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    • 2000
  • In order to find out the casting conditions of the thin wall stainless steel exhaust manifold for automobile, the melt flow and solidification behavior simulated by the Z-CAST program were evaluated, and experimental casting result on the test casting and exhaust manifold of SSC13 alloy were investigated. From the results of this study, it was shown that the calculated results on fluid flow were in good agreement with practical thin wall test castings under the same casting conditions, as pouring metal is austenitic stainless steel(SSC13) and pouring temperature is 1575, 1630, and $1665^{\circ}C$ respectively. That calculated result with designed thin wall exhaust manifold was predicted filling up into the mold cavity, and practical casting was sound. The solidification simulation was predicted shrinkages at the bosses for original exhaust manifold, and designed it without bosses was predicted no defect. Therefore practical exhaust manifold casting was sound and in good agreement with calculated solidification results.

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Post Process Associated with the Electrochemical Reduction Process - Smelting of a Metal Product and Solidification of a Molten Salt (전해환원공정 관련 후처리공정 - 금속전환체 Smelting 및 용융염 고화)

  • 허진목;정명수;이원경;조수행;서중석;박성원
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.278-284
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    • 2004
  • The processes for the smelting of a metal product and the solidification of a molten salt were developed respectively to treat the products from the electrochemical reduction process. The method for the separation of a metal product in a magnesia container from the residual. salt and consequent smelting of it to a metal ingot by the multi step heating in vacuum was proposed. The new concept using a dual vessel and a salt valve was also suggested for the solidification of a molten salt into a regular size and shape which is suitable for the transport and measurement. The results obtained in the study will be applied to the design of the hot cell demonstration system of the Advanced Spent Fuel Conditioning Process of KAERI.

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