• Title/Summary/Keyword: Solidification

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Studies on the Forage Production and Utilization on Paddy Field in Korea (한국에 있어서 답리작을 이용한 양질 조사료 생산기술)

  • Seo, Sung;Yook, W.B.
    • Proceedings of the Korean Society of Grassland Science Conference
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    • 2002.09b
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    • pp.5-56
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    • 2002
  • The problems in the current domestic forage production were evaluated, and the prospective improvement was suggested in this paper. Grassland development in forest, production of high quality forages in upland and paddy land, efficient utilization of rice straw, development of new varieties of forages suitable for our environmental conditions and imported forages were described Among them, preferential production and utilization of forages using paddy field after rice harvest . should be enlarged for domestic supply of forages in Korea. Several studies were carried out to select the promising forage crops and barley cultivars for whole crop silage production, to determine productivity, nutritive value and production cost of forages produced in paddy field, and feeding effect of forages with Hanuwoo and milking cow for whole crop silage with forages produced in paddy field, 1999 to 2001, and also discussed restraint factors and activation plans for enlargement of forage production in paddy land. The promising forage crops in paddy field were rye and barley for Middle region, and rye, barley, early maturing Italian ryegrass and wheat for Southern region. The promising barley cultivars for whole crop silage in paddy field were Albori in Suwon, Keunalbori, Milyang 92, Saessalbori, and Naehanssalbori in Iksan, and Keunalbori, Albori, Naehanssalbori, and Saegangbori in Milyang, respectively. Silage production, quality and animal palatability of silage by trench and round bale were also compared. The production yields of whole crop barley silage(WBS) were 17,135kg as a fresh matter, and 6,011kg as a dry matter per ha, and the quality of WBS was 2∼3 grade, while that of rice straw silage was 4 grade as a farm basis. The production cost of WBS per kg was 83won as a fresh matter, and 238won as a dry matter. Feeding of WBS as forages on Hanwoo was very desirable for the improvement of live-weight gain, beef quality and farm income, particularly in growing stage of Hanwoo. Milk production and income were also increased, and feed cost was decreased by feeding of WBS. The daily voluntary intake of WBS in milking cow was 26.3kg as a fresh matter(DM 7.7kg) per head. Milk production when WBS was fed, was very similar to that of imported hay feeding such as Kentucky bluegrass or domestic corn silage. The issues to be solved in near future f3r stable forage production and supply in paddy land are sustainable livestock-forages policy, development & seed production of new varieties of barley, rye, Italian ryegrass and other promising forages, efficient demand & supply system of forages, solidification for mass production and utilization of forages, efficient application management of animal slurry on paddy field considering environmental agriculture/livestock industry, and break k development of bottleneck technique in production field. Domestic production & supply of high cost agricultural machine (round baler, wrapper, handler and so on), plastic wrapping film, and silage additives are also important.

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Arsenic removal from artificial arsenic water using CaAl-monosulfate and CaAl-ettringite (CaAl-monosulfate와 CaAl-ettringite를 이용한 인공비소폐수의 비소 제거 연구)

  • Shim, Jae-Ho;Kim, Ki-Baek;Choi, Won-Ho;Park, Joo-Yang
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.1
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    • pp.141-148
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    • 2012
  • The objective of this study is to remove arsenate from artificially contaminated wastewater using CaAl-ettringite and CaAl-monosulfate which were synthesized in laboratory. The study was carried on the basis of solidification/stabilization of waste using cement. Monosulfate and ettringite are constituents of cement paste. The CaAl-ettringite has a chemical formula of $Ca_6Al_2O_6(SO_4)_3{\cdot}32H_2O$ and has a needle like morphology. Whereas CaAl-monosulfate $Ca_4Al_2O_6(SO_4){\cdot}12H_2O$ has layered double hydroxide structure (LDH) in which the mainlayer consists of Ca and Al and S as interlayer. Ettringite and monosulfate were synthesized by reaction of tricalcium aluminate and gypsum and hydrating this mixture at elevated temperature. The synthesized mineral were characterized by PXRD and FESEM to ensure purity. It was found that concentrations of As(V) in contaminated water were reduced from initial concentration of 1.335 mmol/L to 0.054 mmol/L and 0.300 mmol/L by CaAl-monosulfate and CaAl-ettringite respectively. The post experimental results of PXRD and FESEM analysis indicate that arsenate removal was by ion exchange.

Physiochemical properties of Seok-jang (석장(간장소금)의 이화학적 특성)

  • Hwang, Su Jung;Kim, Ye-Seul;Jiang, Gui-Hun;Eun, Jong-Bang
    • Food Science and Preservation
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    • v.23 no.4
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    • pp.495-501
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    • 2016
  • Seok-jang is one of traditional seasonings prepared by solidification of the mixture of say sauce and salt for long period of aging time. In this study, the physiochemical properties of Seok-jang were investigated for the substitution of solar salt. Seok-jang exhibited highest mineral (P, Na, Fe, Mn, and Al) contents than those of solar salt and soy sauce, while showed lower soluble solids content than that of soy sauce. Seok-jang also exerted the highest pH value 7.70 compared to solar salt and soy sauce. Whereas magnesium and calcium contents of solar salts were 2.90 and 0.26 ppm, which were significantly higher than those of Seok-jang. In color values, $L^*$ value was highest in solar salt and lowest in say sauce, While the highest $a^*$ and $b^*$value were 6.19 and 18.2 observed in Seok-jang followed by a solar salt and soy sauce. On the other hand, less amount of insoluble solid and sand powder content were 0.03 and 0.07% found in Seok-jang, respectively. In conclusion, Seok-jang was suitable for the potentional substitution of natural salt ingredient.

Thermoelectric properties of unidirectionally solidified $Bi_{2}Te_{3}-PbBi_{4}Te_{7}$ eutectic alloys (일방향응고된 $Bi_{2}Te_{3}-PbBi_{4}Te_{7}$ 공정합금의 열전특성)

  • Park, Chang-Geun;Min, Byeong-Gyu;Lee, Dong-Hui
    • Korean Journal of Materials Research
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    • v.5 no.2
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    • pp.251-258
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    • 1995
  • In an effort to increase the thermoelectric figure of merit by reducing the thermal conductivity, the unidirectionally solidified n-type (Bi, Pb)-Te based alloys which form a $Bi_{2}Te_{3}-PbBi_{4}Te_{7}$eutectic lamellar structure were investigated with the microstructural control at various solidification conditions. PbBi_{4}Te_{7}$ lamellae were grown on cleavage plane(0001) of $Bi_{2}Te_{3}$ and the interlamellar spacing decreased from 10.4 $\mu \textrm{m}$to 3.2$\mu \textrm{m}$ with growth velocity variation from 1.4 \times 10^{-4}$cm/sec to $8.3 \times 10^{-4}$cm/sec. Seebeck coefficient was constant, $\mid$$\alpha$$\mid$=29 $\mu$ V/K regardless of growth direction, growth velocity and temperature gradient. Electrical conductivity showed a tendency to decrease slightly with growth velocity and it parallel to growth direction was about three times as large as perpendicular direction. The figures of merit were varied differently from Seebeck coefficients and electrical conductivities depending on the growth direction, growth velocity and temperature gradients. They showed the relative increase in case of perpendicular direction compared with parallel to growth direction. It is believed to be due to the reduction of the thermal conductivity according to decrease of the interlamellar spacing.

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Microstructure and Magnetic Properties of Rapidly Solidified Nd-Fe(-Co) and Sm-Co(-Fe) Laves Compounds (급속냉각된 Nd-Fe(-Co)와 Sm-Co(-Fe)계 Laves 화합물의 미세조직과 자기특성)

  • 이우영;최승덕;양충진
    • Journal of the Korean Magnetics Society
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    • v.1 no.1
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    • pp.17-24
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    • 1991
  • Laves phases of $NdFe_2$, $Nd{(Fe_{0.5})}_2$, $SmCo_2$ and $Sm{(Fe_{0.5}Co_{0.5})}_2$ stoichiometry were prepared using a rapid solidification technology. Low temperature magnetic properties show ferromagnetic behaviors for the $Nd{(Fe_{0.5}Co_{0.5})}_2$, $SmCo_2$ and $Sm{(Fe_{0.5}Co_{0.5})}_2$Nd(Feo,Coo,) Laves compounds while a sort of spin reorientation has been suggested for the supposed composition of $NdFe_2$ alloy. This rapidly solidified $NdFe_2$ alloy is believed to consist of metastable rhombohedral $NdFe_7$ phase plus fine particles of Nd-rich phase. Some evidence of phase transition from the mixture of unstable $NdFe_7$ compound plus Nd-rich to $Nd_2Fe_{17}$ plus Fe-Nd-O phase was obtained after annealing the $NdFe_2$, alloy. The pseudo-binary Laves compound, $Sm{(Fe_{0.5}Co_{0.5})}_2$ exhibits a high coercivityof 4 kOe at room temperature with Curie temperature of $400^{\circ}C$ while the $Nd{(Fe_{0.5}Co_{0.5})}_2$ compound shows a magnetic moment of $2.8\;{\mu}_B/f.u.$.

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Magnetic Hardening of Rapidly Solidified $SmFe_{7+x}M_{x}(M=Mo,\;V,\;Ti)$ Compounds (급속냉각된 $SmFe_{7+x}M_{x}(M=Mo,\;V,\;Ti)$ 화합물에서 생성된 신 강자성상)

  • Choong-Jin Yang;E. B. Park;S. D. Choi
    • Journal of the Korean Magnetics Society
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    • v.4 no.3
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    • pp.226-232
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    • 1994
  • Rapidly solidified $SmFe_{7+x}M_{x}(M=Mo,\;V,\;Ti)$ compound were found to crystallize in the ${Sm(Fe,\;M)}_{7}$ based stable magnetic phase by introducing a second transition element into the Sm-Fe binary system. The ${Sm(Fe,\;M)}_{7}$ phase exhibits the highest Curie temperatuer ($T_{c}=355^{\circ}C$) ever Known in the Sm-Fe magnetic systems with a quite high intrinsic coercivity($_{i}H_{c}=3~6\;kOe $). The ${Sm(Fe,\;M)}_{7}$ phase remains stable even after annealing if once form during the rapid solidification. The primary reason for the high coercive force is due to the fine grain size($2000~8000\;{\AA}$)of the magnetic ${Sm(Fe,\;M)}_{7}$ matrix phase, and the enhanced Curie temperature is attributed to the extended solid-solubility of the additive transition elements in Fe matrix, which leads to volume expansion of the ${Sm(Fe,\;M)}_{7}$ cell causing an enhanced coupling constant of Fe atoms.

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Behavior Characteristics of Underground Flexible Pipe Backfilled with Lightweight Foamed Soil (경량기포혼합토로 뒷채움된 연성매설관의 거동특성)

  • Lee, Yong-Jae;Yea, Geu-Guwen;Park, Sang-Won;Kim, Hong-Yeon
    • Journal of the Korean Geosynthetics Society
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    • v.14 no.1
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    • pp.43-50
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    • 2015
  • Lightweight Foamed Soil (LWFS) is a useful material for underground pipe backfill because of reusability of excavated soil and no compaction effect. In this research, a pilot test is carried out and monitoring results are analyzed to investigate behaviors of a flexible pipe, when LWFS is applied as a backfill material. Simultaneously, they are compared with another test case which is backfilled with Saemangeum dredged soil. As a result, the vertical earth pressure of the case backfilled with LWFS slurry presents that decreases as much as 25.6% in comparison with dredged soil and it is only within 10% after solidification. In case backfilled with dredged soil, the horizontal earth pressure is more than 3.6 times of the case used by LWFS and the vertical and horizontal deformation is more than 3.2 and 2.6 times of the case, respectively. It presents excellent effects on earth pressure and deformation reduction of LWFS. The stresses measured at the upper side of the pipe generally present compressive aspects in case backfilled with dredged soil. However, they present tensile aspects in case of LWFS. It is because of negative moment occurred at the center of the pipe due to the buoyancy from LWFS slurry. Conclusively, LWFS using Saemangeum dredged soil is very excellent material to use near the area in comparison with the dredged soil. However, the countermeasure to prevent the buoyancy is required.

Characterization of the PVDF Fibers Fabricated by Hybrid Wet Spinning (하이브리드 습식 공정을 통한 PVDF 섬유의 제조 및 특성에 관한 연구)

  • Jeong, Kun;Kim, Seong-Su
    • Composites Research
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    • v.29 no.4
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    • pp.145-150
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    • 2016
  • Polyvinylidene fluoride (PVDF) as a representative polymer with the piezoelectric property has been studied since the 1960s. Crystalline structure of poly(vinylidene fluoride) polymer is composed of five different crystal structure of the polymer as a semi-crystalline. Among the various crystal structures, ${\beta}-type$ crystal exhibits a piezoelectricity because the permanent dipoles are aligned in one direction. Generally ${\beta}-form$ crystal structure can be obtained through the transformation of the ${\alpha}-form$ crystal structure by the stretching and it can increase the amount through the after treatment as poling process after stretching. ${\beta}-form$ crystal structure the PVDF fibers produced by wet spinning is formed through a diffusion mechanism of a polar solvent in the coagulation bath. However, it has a disadvantage that the diffusion path of the solvent remains as pores in the fiber because the fiber solidification occurs simultaneously with the diffusion of the polar solvent. These pores play a role in reducing effect of poling process owing to effect of disturbances acting on the polarization by the electric field. In this work, the drying method using the microwave was introduced to remove more effectively the residual solvent and the pore within PVDF fibers produced through wet-spinning process and piezoelectric PVDF fibers was produced by transformation of the remaining ${\alpha}$ form crystal structure into ${\beta}-crystal$ structure through the stretching process.

Combination of Different Numerical Methods for Efficient Thermal Stress Analysis of Casting Process (주조공정에서의 효율적인 열응력 해석을 위한 이종해석기법의 연계)

  • Kwak, Si-Young;Lim, Chae-Ho
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.8
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    • pp.1051-1057
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    • 2010
  • This paper proposes a method that involves a combination of FDM and FEM for analyzing casting process. At present, many numerical analysis methods such as FDM, FEM, and BEM are used for solving engineering problems. For a given problem, a specific method that is suited to the problem is adopted; in general, FDM or FVM is favored for problems related to fluid flow or heat transfer, and FEM is adopted in stress analysis. However, there is an increasing need for using a combined method for complex and coupled phenomena analysis. Hence, we proposed a method in which FDM and FEM are coupled in three-dimensional space, and we applied this method to analyze casting process. In the proposed method, solidification and heat transfer was analyzed by using FDM. The field data such as temperature distribution were converted into a format suitable for FEM analysis that was used for calculating thermal stress distribution. Using the proposed method, we efficiently analyzed the analysis process from the viewpoints of work and time.

The Effect of Ca Addition on Creep Behavior of As-cast Mg-8.0Zn-1.6Y Alloys with Icosahedral Phase (Icosahedral 상을 갖는 Mg-8Zn-1.6Y 합금의 크리프 거동에 미치는 Ca 첨가 영향)

  • Jung, Young-Gil;Yang, Wonseok;Kim, Shae K.;Lim, Hyunkyu;Oh, Gun-Young;Kim, Youngkyun;Kim, Do Hyang
    • Journal of Korea Foundry Society
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    • v.40 no.2
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    • pp.7-15
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    • 2020
  • The high-temperature stability of Mg-8.0Zn-1.6Y (wt.%) alloys upon the addition of Ca has been investigated by characterizing the ignition temperature, microstructure, tensile and creep properties. The ignition temperature increases with an increase in the Ca content, indicating that an addition of Ca enhances the ignition resistance of the Mg-Zn-Y alloy. The as-cast microstructures of all tested alloys mainly consisted of the dendritic α-Mg matrix and I-phase (Mg3Zn6Y) at the grain boundaries. In the Ca-added Mg-8.0Zn-1.6Y alloys, the Ca2Mg6Zn3 phase forms, with this phase fraction increasing with an increase in the Ca contents. However, a high volume fraction of the Ca2Mg6Zn3 phase rather deteriorates the mechanical properties. Therefore, a moderate amount of Ca element in Mg-8.0Zn-1.6Y alloys is effective for improving the tensile and creep properties of the Mg-Zn-Y alloy. The Mg-8.0Zn-1.6Y-0.3Ca alloy exhibits the highest tensile strength and the lowest creep strain among the alloys investigated in the present study. The creep resistance of Mg-Zn-Y-Ca alloys depends on the selection of the secondary solidification phase; i.e., when Ca2Mg6Zn3 forms in an alloy containing a high level of Ca, the creep resistance deteriorates because Ca2Mg6Zn3 is less stable than the I-phase at a high temperature.