• Title/Summary/Keyword: Solid-state method

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Microstructure Evolution of Solid State Reacted HAp/β-TCP Composite Powders by Post-Treatment Processing (후처리공정에 따른 고상반응 β-TCP/HAp 복합분체의 미세구조 변화)

  • 박영민;양태영;박상희;윤석영;박홍채
    • Journal of the Korean Ceramic Society
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    • v.41 no.8
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    • pp.582-587
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    • 2004
  • Biphasic Calcium Phosphate (BCP) consisted of hydroxyapatite (HAp) and $\beta$-tricalcium phosphate (P-TCP) has been prepared by solid state reaction. The size reduction of the resultant BCP agglomerate was carried out by reaction with hot water under atmospheric condition uld also under high pressure using an autoclave. The influence of processing conditions on the change of crystalline phase and composition, relative amount of constituent, specific surface area, and microstructure was investigated by means of XRD, FT-IR, BET method using a nitrogen adsorption and SEM.

Speed Control of tne Induction Motor Using SCR (Trial Manufacturing of Solid-state Frequency Converter) (SCR를 이용한 유도전동기의 속도제어에 관한 연구)

  • Jong Swoo Won
    • 전기의세계
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    • v.19 no.4
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    • pp.1-11
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    • 1970
  • It is well known that solid-state devices like inverter and converter made by transistor and other semi-conductors are widely used for the purpose of motor speed control in industrial fields. This paper is devoted primarily to a study of Trial Manufacturing of Solid-state Frequency Converter by means of single-phase bridge-type SCR inverter. The principle of the trial product belongs to AC-DC-AC conversion system. The voltage to be impressed to the motor in case of speed control by frequency conversion method is necessary to be proportional to frequency. It also requires the frequency and voltage are independent to hte load variation. In order to meet above requests required to motor speed control., the trial product introduced the open loop system in the frequency setting and closed loop system in the voltage setting. The trial product showed the favorable performance characteristics in speed control of singlephase fractional horsepower motor from 45HZ through 80HZ.

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Development of Click Chemistry in Polymerization and Applications of Click Polymer

  • Karim, Md. Anwarul
    • Rubber Technology
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    • v.13 no.1
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    • pp.1-9
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    • 2012
  • Click chemistry had enjoyed a wealthy decade after it was introduced by K.B.Sharpless and his co-worker on 2001. Since there is no optimized method for synthesis of click polymer, therefore, this paper introduced three click reaction methods such as catalyst, non-catalyst and azide-end capping for fluorene-based functional click polymers. The obtained polymers have reasonable molecular weight with narrow PDI. The polymers are thermally stable and almost emitted blue light emission. The synthesized fluorene-based functional click polymers were characterized to compare the effect of click reaction methods on polymer electro-optical properties as well as device performance on quasi-solid-state dye sensitized solar cells (DSSCs) applications. The DSSCs with configuration of $SnO_2:F/TiO_2/N719$ dye/quasi-solid-state electrolyte/Pt devices were fabricated using these click polymers as a solid-state electrolyte components. Among the devices, the catalyzed click polymer composed device exhibited a high power conversion efficiency of 4.62% under AM 1.5G illumination ($100mW/cm^2$).These click polymers are promising materials in device application and $Cu^I$-catalyst 1, 3-dipolar cycloaddition click reaction is an efficient synthetic methodology.

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Solid State Diffusion Brazing of the Aluminum Alloy Castings According to the Heat Treatment Conditions (열처리온도 및 시간에 따른 알루미늄 주조재의 고상확산 접합 특성)

  • Sun, J.H.;Shin, S.Y.;Hong, J.W.
    • Journal of the Korean Society for Heat Treatment
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    • v.21 no.6
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    • pp.300-306
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    • 2008
  • Solid state diffusion brazing of aluminum castings (AC4C) and wrought alloys (Al6061) was conducted in order to improve thermal conductivity and temperature uniformity of the aluminum heater which was generally fabricated by casting method. Tensile strength and thermal conductivity are raised with increasing brazing temperature, obtaining 122.5 MPa and $206W/m{\cdot}K$ at $540^{\circ}C$ 5hrs brazing conditions, respectively. The diffusion brazed heater, shows maximum temperature difference of $4^{\circ}C$, exhibits a enhanced temperature uniformity compared with the cast heater having the maximum temperature difference of $11^{\circ}C$.

Study on Electrochemical Performance of Solid-State-Electrode on Steel bar in Chloride Solution (염화물 수용액 중의 철근에 대한 고체전극의 전기화학적 성능 연구)

  • Park, Dong-Jin;Park, Jang-Hyun;Lee, Han-Seung;Subbiah, Karthick
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.147-148
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    • 2018
  • In order to compare the electrochemical performance with that of Calomel Electrode, MnO2 solid-state-electrode was fabricated and its potential and impedance were measured in chloride aqueous solution. As a result, the SCPS without chloride ions showed a potential of -200 mV or more and an impedance over 2000 Ωcm, but the potential below -600 mV and the impedance below -200 Ωcm showed as the chloride concentration in the solution increased. It is considered electrochemical studies on the corrosion of rebar are necessary for the MOE, which shows the same tendency as SCE and exhibits electrochemical performance, over the Mortar level in the future.

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A Study on Multi-level Converter Based on Distribution Active Hybrid Solid State Transformer (멀티레벨 컨버터 기반 배전용 능동형 하이브리드 반도체 변압기에 대한 연구)

  • Yun, Chun-gi;Cho, Younghoon
    • Proceedings of the KIPE Conference
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    • 2018.07a
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    • pp.84-86
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    • 2018
  • Active hybrid solid state transformer(AHSST) is newly emerging as a device to maintan the power quality of power distribution. AHSST has a simple structure in which a power electronics device is connected in series to a conventional distribution transformer. The connected power electronics device maintains the constant voltage regardless of the primary grid voltage fluctuation through the secondary voltage control to improve the power quality. It also has a simple structure compare to conventional solid state transformer system and can achieve the same performance with fractionally-rated converter. This paper proposes an multi-level converter based on AHSST system that has a simpler control method and wider voltage control range than the conventional AHSST. The proposed system is verified by simulations.

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Measurement of the Radiative Quantum Efficiency of a Solid-State Laser Using Photoacoustic Spectroscopy (광음향 분광을 이용한 고체레이저의 방사양자효율 측정)

  • Kim, Byung-Tai
    • Korean Journal of Optics and Photonics
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    • v.26 no.2
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    • pp.98-102
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    • 2015
  • The radiative quantum efficiency of a solid-state laser was measured by photoacoustic spectroscopy with a PZT as the detector. The radiative quantum efficiency was about 58.3 % for a laser-diode pumped Nd:S-VAP laser under lasing conditions. The measurement of radiative quantum efficiency was presented as an effective method for the optimization of a laser resonator.

Effects of Density Change and Cooling Rate on Heat Transfer and Thermal Stress During Vertical Solidification Process (수직응고 시스템에서 밀도차와 냉각률이 열전달 및 열응력에 미치는 영향)

  • 황기영;이진호
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.4
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    • pp.1095-1101
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    • 1995
  • Numerical analysis of vertical solidification process allowing solid-liquid density change is performed by a hybrid method between a winite volume method (FVM) and a finite element method (FEM). The investigation focuses on the influence of solid-liquid density change and cooling rates on the motion of solid-liquid interface, solidified mass fraction, temperatures and thermal stresses in the solid region. Due to the density change of pure aluminium, solid-liquid interface moves more slowly but the solidified mass fraction is larger. The cooling rate of the wall is shown to have a significant influence on the phase change heat transfer and thermal stresses, while the density change has a small influence on the motion of the interface, solidified mass fraction, temperature distributions and thermal stresses. As the cooling rate increases, the thermal stresses become higher at the early stage of a solidification process, but it has small influence on the final stresses as the steady state is reached.

A Study on Material Characterization of Semi-Solid Materials(II) -Determination of Flow Stress For Semi-Solid Materials Using Backward Extrusion Experiment with Model Material and Upper Bound Analysis- (반용융 재료의 물성치 평가에 관한 연구(II) -모델재료의 후방압출 실험과 상계해석을 통한 반용융 재료의 유동응력식 결정-)

  • 이주영;김낙수
    • Transactions of Materials Processing
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    • v.8 no.4
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    • pp.374-383
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    • 1999
  • To determine the flow stress of semi-solid materials, a new combined method has been studied by experimental and analytic technique in the current approach. Using backward extrusion experiment and its numerical analysis, the characterization scheme of semi-solid materials according to the change of initial solid volume fraction has been proposed. Because that solid volume fraction is sensitive to temperature change, it is required to precisely control the temperature setting. Model materials can guarantee the establishment of material characterization technique from the noise due to temperature change. Thus, clay mixed with bonded abrasives was used for experiment and the change of initial solid fraction was copied out through the variation of mixing ratio. Upper bound method was adapted to increase in efficiency of the calculation in numerical analysis and new kinematically admissible velocity field was employed to improve the accuracy of numerical solution. It is thought that the material characterization scheme proposed in this study can be applied to not only semi-solid materials, but also other materials that is difficult to obtain the simple stress state.

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Dissolution Enhancement of Fenticonazole Nitrate from Hydrophilic Polymer Solid Dispersions (친수성 고분자와의 고체분산체로부터 질산펜티코나졸의 용출 증가)

  • Kim, Young-Il;Kim, Seung-In;Choi, Jae-Yoon
    • Journal of Pharmaceutical Investigation
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    • v.19 no.2
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    • pp.109-116
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    • 1989
  • Solid dispersion of fenticonazole nitrate (FN) with poloxamer 407, polyethylene glycol 6000, povidone (K-90) were prepared by the solvent method. To characterize the state of the drug in solid dispersions, the x-ray diffractometry and differential scanning calorimetry were carried out. The identification of these systems suggested that FN in the poloxamer 407 system remained in crystalline state, and the drug in the PVP system was amorphous. A marked increase in the dissolution rate of FN was attained by dispersing the drug in the hydrophilic polymers used, and the dispersion with poloxamer 407 was superior to the other two carriers in releasing the drug into solution.

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