• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 2008년도 춘계학술대회논문집
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• pp.369-372
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• 2008

An experimental study is carried out to study two-phase vertically upward hydraulic transport of solid particles by water in a vertical and inclined (0${\sim}$60 degree) concentric annulus with rotation of the inner cylinder. Rheology of particulate suspensions in shear-thinning fluids is of importance in many applications such as particle removal from surfaces, transport of proppants in fractured reservoir and cleaning of drilling holes, and so on. Annular fluid velocities varied from 0.2 m/s to 1.5 m/s for the actual drilling operational condition. Macroscopic behavior of solid particles, averaged flow rate, and particle rising velocity are observed. Main parameters considered in this study were radius ratio, inner-pipe rotary speed, fluid flow regime, and particle injection rate. For both water and CMC solutions, the higher the concentration of the solid particles is, the larger the pressure gradients become

• 대한기계학회논문집B
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• 제24권6호
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• pp.792-801
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• 2000

The problem of phase change from liquid to solid in the inviscid plane-stagnation flow is theoretically investigated. The solution at the initial stage of freezing is obtained by expanding it in powers of time, and the final equilibrium state is determined from the steady-state governing equations. The transient solution is dependent on the three dimensionless parameters, but the equilibrium state is determined by one parameter of (temperature ratio/conductivity ratio). The effect of the fluid flow on the growth rate of the solid in the pure conduction problem can be clearly seen from the solution of the initial stage and the final equilibrium state. The characteristics of the transient heat transfer at the surface of the solid and the liquid side of the solid-liquid interface for all the dimensionless parameters are elucidated.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 추계학술대회
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• pp.79-84
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• 2003

In this study we propose an unsteady I-dimensional model of an iron ore sintering bed with multiple solid phases, which confers a phase on each solid material. This model contains coke combustion, limestone decomposition, gaseous reaction, heat transfers between each phase, and geometric changes of the solid particles. Simulation results are compared with the limited experimental data set of various coke contents and air supply rates. Effect of the coke diameter is also evaluated. They predict the experimental results well and show applicabilities to the various system of the fuel bed with various solid materials.

• 한국전산유체공학회지
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• 제14권4호
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• pp.1-6
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• 2009

In the present study, numerical simulations were performed in a stirred solid/liquid system by using Eulerian multi-phase model. The transient flow field of liquid and distribution of solid particles were predicted in the stirred tank with pitched paddle impeller and baffles. The Frozen rotor method is adopted to consider the rotating motion of the impeller. The effects of number and width of baffles on the mixing time and the quality of solid suspension in the stirred tank are presented numerically. The result shows that the mixing time decreases as the width and number of baffles increase. The present numerical methodology can be applied to optimizing mixing condition of industrial mixer.

• 방사성폐기물학회지
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• 제19권3호
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• pp.353-366
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• 2021

The solubilities of different multicomponent lanthanide oxide (Ln₂O₃) solid solutions including binary (Ln₁ and Ln₂ = La, Nd, Eu, or Tm), ternary (Ln₁, Ln₂, and Ln₃ = La, Nd, Eu, or Tm), and higher systems (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu) were studied after aging for four weeks at 60℃. Our recent study revealed that the phase transformations in binary ((La, Nd) and (La, Eu)) and ternary (La, Nd, Eu) systems are responsible for the formation of (La, Nd)(OH)₃, (La, Eu)(OH)₃, and (La, Nd, Eu)(OH)₃ solid solutions, respectively. The variations in the mole fractions of La³⁺, Nd³⁺, and Eu³⁺ in the sample solutions of these hydroxide solid solutions indicated that a thermodynamic equilibrium might account for the apparent La, Nd, and Eu solubilities. Conversely, the binary and ternary systems containing Tm₂O₃ as the heavy lanthanide oxide retained the oxide-based solid solutions, and their solubility behaviors were dominated by their congruent dissolutions. In the higher multicomponent system, the X-ray diffraction patterns of the solid phases, before and after contact with the aqueous phase indicated the formation of a stable oxide solid solution and their solubility behavior was explained by its congruent dissolution.

• Applied Biological Chemistry
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• 제40권1호
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• pp.1-11
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• 1997

• 한국전기화학회:학술대회논문집
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• 한국전기화학회 2001년도 춘계총회 및 학술발표회
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• pp.3-4
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• 2001

• Bulletin of the Korean Chemical Society
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• 제28권1호
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• pp.108-114
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• 2007

The lyotropic behaviors to form the structure of distearoylphosphatidylcholine (DSPC)-based liquid crystal (LC) hydrated by only propylene glycol (PG) without water were examined by differential scanning calorimetry (DSC), X-ray diffractions (XRD), polarized microscope (PM) and transmission electron microscope (TEM). By increasing the amount of PG instead of water, it showed the phase transition to be gradually changed from anisotropic structures to other structures more close to isotropic ones and their appearance to be changed from solid-like states to liquid-like ones with more fluidity. Below 50% w/w PG, the mixtures of DSPC and PG resulted in no direct observation of LC structure through PM because they were very close to solid-states. From 55% w/w to 90% w/w of PG, the dense lamella crystalline structures were observed through PM, and their thickness and area decreased as the content of PG increased. Measured by DSC with heating process, the main phase transition from α -lamella phase to isotropic phase appeared from 52.89 °C to 47.41 °C to show linearly decreasing behaviors because PG affects the hydrophobic region of DSPC-based lamella phase. The repeating distance of the lamella phase and the interlayer distance between bilayers were calculated with XRDs and the average number of bilayers related to the thickness in LC structure was approximately estimated by combining with TEM results. The WAXS and DSC measurements showed that all of PG molecules contributed to swelling both the lipid layer in the edge region of lamella phase close to phosphate groups and the interlayer between bilayers below 90% w/w of PG. The phase and thermal behaviors were found to depend on the amount of PG used by means of dissolving DSPC as a phospholipid and rearranging its structure. Instead of water, the inducement of PG as a polar solvent in solid-lamella phase is discussed in terms of the swelling effect of PG for DSPC-based lamella membrane.

• Archives of Pharmacal Research
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• 제10권1호
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• pp.18-24
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• 1987

Mouse monocolonal antibodies to Hepatitis B surface antien (HBsAg) were prepared and their functional capabilities tested by the method of solid phase enzyme linked immuno sorbent assay (ELISA). HBsAg binding studies inicated that one monoclonal antibody 6E-1-1 bound more HBsAg at a faster rate than the other monoclonal antibodies. Also, for the binding inhibition studies with the selected monoclonal antibody 6E-1-1, one monoclonal antibody 8D-3-6 didn't exhibit binding inhibition for HBsAg. Then, a simultaneous ELISA method was developed for the immunodiagnosis of HBsAg. Different combinations of two monoclonal antibodies as solid phase and horseradish peroxidase (HRPO) labeled phase were studied. The combination of monoclonal antibody of higher affinity constant (6E-1-1) immobilized in a solid phase and monoclonal antibody of lower affinity constant (8D-3-6) as a HRPO laeled phase was more sensitive when two monoclonal antibodies of different affinity constants for HBsAg were prepared.

• 대한기계학회논문집
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• 제16권1호
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• pp.142-155
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• 1992

본 연구에서는 실제 빙축열 시스템의 해석을 위한 기초 모델로서 수직원관 주 위의 응고과정에 대하여 밀도차와 자연대류 효과 및 최대 밀도점을 나타내는 밀도-온 도 관계식을 도입한 수치해석과 실험을 통하여 여러가지 매개변수들이 상변화에 미치 는 영향을 알아 보았다.