• Title/Summary/Keyword: Solid-electrolyte

Search Result 698, Processing Time 0.035 seconds

Charge/Discharge Characteristics Analysis of Li-Polymer battery (리튬 폴리머 전지의 충방전 특성해석)

  • 최해룡;강병희;목형수;최규하;신우석
    • Proceedings of the KIPE Conference
    • /
    • 1999.07a
    • /
    • pp.222-225
    • /
    • 1999
  • Started upon it discovery by Wright et al in 1973, studies on the solid polymer electrolyte are being carried out vigorously. So, models of Li-polymer battery have been developed through R-L-C components combination and P-spice functional block in this paper. The impedance characteristics of Li-polymer battery with R-L-C components are presented. Simulation results using P-spice functional model are compared with measured charge/discharge characteristics.

  • PDF

State of Solid oxide fuel cell (고체산화물 연료전지 기술 현황)

  • Song, Rak-Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2002.05c
    • /
    • pp.1-5
    • /
    • 2002
  • 고체산화물 연료전지는 무공해 고효율의 에너지 발전 장치이다. 연료전지는 형태는 1 세대 알카리형 연료 전지부터 인산형, 고분자전해질형, 직접메탄올형, 용융탄산염형 그리고 3세대인 고체산화물형 연료전지들이 있다. 고체산화물 연료전지는 음극 및 양극 그리고 고온에서 작동되기 때문에 전해질 및 내부연결재 등이 많이 연구 개발되고 있다. 고체산화물 연료전지는 이동형으로부터 소형발전 시스템 및 대형 복합발전시스템에 걸쳐 많이 개발이 이루어지고 있다.

  • PDF

COIN형 리튬 폴리머전지의 충방전 특성

  • 박수길;박종은;손원근;이흥기;김상욱;이주성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1997.11a
    • /
    • pp.497-500
    • /
    • 1997
  • Conducting polymer is new material in lithium secondary battery. conducting polymer has a lot of merit which is flexible and good handing so that this material is used battery system, solid polymer electrolytes airs used PEO(Polyethylene oxide) and PEO/PMMA branding material adding by liquid plasticizer or lithium salt polymer electrolyte which is added liquid plasticizer, lithium salt decreased the crystallity and thermal stability is over than 13$0^{\circ}C$. it is very useful tn apply lithium secondary battery system.

  • PDF

Electrical Properties of Gadolinium-doped Ceria/Magnesia (CGO/MgO) Composite Electrolytes (Gadolinium-doped Ceria/Magnesia (CGO/MgO) 복합체 전해질의 전기적 특성 분석)

  • Jo, Seung-Hwan;Muralidharan, P.;Kim, Do-Kyung
    • Korean Journal of Materials Research
    • /
    • v.18 no.9
    • /
    • pp.470-474
    • /
    • 2008
  • Composites of gadolinium-doped ceria/magnesia(CGO/MgO) were synthesized and characterized for the electrolytes of intermediate temperature solid oxide fuel cells. XRD and SEM results revealed that composite electrolytes consisted of their own phases after sintering at $1400^{\circ}C$ without noticeable solid solution of Mg into CGO. As the MgO content increased, the total electrical conductivity decreased, which might be attributed to the decrease of grain boundary conductivity, possibly due to the lowering of the continuity of the CGO grains and blocking effects of the insulating MgO phase. The space charge effect may not be a significant factor to affect the electrical conductivity of the CGO/MgO composites.

고주파 유도결합 열플라즈마를 이용한 Gd Doped Cria 나노 분말 합성

  • Lee, Mi-Yeon;Kim, Jeong-Su;Seo, Jun-Ho;Hong, Bong-Geun
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2013.02a
    • /
    • pp.229-229
    • /
    • 2013
  • 저온작동형($500{\sim}700^{\circ}$) 고체산화물 연료전지의 전해질 재료의 응용이 기대되는 Gd doped ceria를 고주파 유도결합 열플라즈마 법으로 합성하고 그 특성을 조사하였다. 본 연구에서는 나노 ㄴCeO2 10~100 um의 CeO2와 1~20 um의 Gd2O3를 Ce:Gd이 9:1 mol%와 8:2 mol%의 비율로 혼합한 선구체를 140 kVA의 RF plate power와 O2/Ar 플라즈마 생성 가스 조건에서 형성된 고주파 유도결합 열 플라즈마에 주입하여 ~50 nm 이하의 입도와 fluorite 구조의 결정화된 CeO2 구조를 갖는 Gd doped ceria 나노 분말을 합성하였다. FE-SEM, TEM, XRD, ICP-OES, EDS, BET분석법을 이용하여, 합성된 분말의 입도, 미세구조, 결정 구조, 조성, 표면 등의 특성을 관찰하였다.

  • PDF

Fabrication of Conducting Polymer Actuators Operating in Air (공기 중에서 동작하는 전도성 고분자 엑추에이터의 제작)

  • An, Ho-Jeong;Cha, Seung-Eun;Lee, Sang-Jo;Pak, James-Jung-Ho;Lee, Seung-Ki
    • Proceedings of the KIEE Conference
    • /
    • 2001.07c
    • /
    • pp.1878-1880
    • /
    • 2001
  • In order to fabricate the stable conductive polymer actuators which are operated in air. Nafion with mixture of LiCl has been used as solid polymer electrolyte material. Based on these materials, beam type and sandwich type actuators have been fabricated and mechanical properties are measured. This kind of all-solid-polymer actuator can be used for practical applications.

  • PDF

Fine Powder Synthesis and It첨s Sintering Characteristics of CaO-Stabilized $ZrO_2$ by Coprecipitation Method (공침법에 의한 CaO 첨가 안정화 $ZrO_2$의 미분말 합성 및 그 소결특성)

  • 박정일;이주신;최태운
    • Journal of the Korean Ceramic Society
    • /
    • v.33 no.5
    • /
    • pp.563-571
    • /
    • 1996
  • In order to fabricate solid electrolyte CaO-stabilized ZrO2 of high density sintered body economically 13 mol% CaO-stabilized ZrO2 powders were synthesized by the coprecipitation method. The characteristics and sintering behavior of fine powder were investigated. The precipitates has the specific surface area of 193 m2/g and apperaed to be fine and spherical primary particles with a size of approximately 5nm. The crystalliza-tion temperture of CaO-stabilized ZrO2 was 462$^{\circ}C$. The tetragonal phase was stable in the low calcining tempe-rature regions and the cubic zirconia solid solution was formed from above 120$0^{\circ}C$ through an intermediate stage of formation of CaZrO3 By introducing fine powders washed with alcohol and ball-milling process after calcination the sintered body was possible to attain the value of above 92% of the theoretical density at low temperature of 120$0^{\circ}C$.

  • PDF

Grain Boundary Protonic Conductivity in Highly Dense Nano-crystalline Y-doped BaZrO3

  • Park, Hee-Jung;Munir, Zuhair A.;Kim, Sang-Tae
    • Journal of the Korean Ceramic Society
    • /
    • v.47 no.1
    • /
    • pp.71-74
    • /
    • 2010
  • We have investigated protonic conduction in highly dense (>98%) polycrystalline Y-doepd $BaZrO_3$ (BYZ) ceramic with an average grain size of ~85 nm. It is observed that the protonic conductivity across the grain boundaries in this nano-crystallilne BYZ (n-BYZ) is significantly higher than the microcrystalline counterpart. Such a remarkable enhancement in grain boundary conductivity results in high overall conductivity that may allow this chemically stable protonic conductor to serve as a solid electrolyte for low-temperature solid oxide fuel cell applications.