• Bulletin of the Korean Chemical Society
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• 제34권4호
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• pp.1153-1159
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• 2013

A novel solid-contact indium(III)-selective sensor based on bis-(1H-benzimidazole-5-methoxy-2-[(4-methoxy-3, 5-dimethyl-1-pyridinyl) 2-methyl]) thiosulfinate, known as an omeprazole dimer (OD) and a neutral ionophore, was constructed, and its performance characteristics were evaluated. The sensor was prepared by applying a membrane cocktail containing the ionophore to a graphite rod pre-coated with polyethylene dioxythiophene (PEDOT) conducting polymer as the ion-to-electron transducer. The membrane contained 3.6% OD, 2.3% oleic acid (OA) and 62% dioctyl phthalate (DOP) as the solvent mediator in PVC and produced a good potentiometric response to indium(III) ions with a Nernstian slope of 19.09 mV/decade. The constructed sensor possessed a linear concentration range from $3{\times}10^{-7}$ to $1{\times}10^{-2}$ M and a lower detection limit (LDL) of $1{\times}10^{-7}$ M indium(III) over a pH range of 4.0-7.0. It also displayed a fast response time and good selectivity for indium(III) over several other ions. The sensor can be used for longer than three months without any considerable divergence in potential. The sensor was utilized for direct and flow injection potentiometric (FIP) determination of indium(III) in alloys. The parameters that control the flow injection method were optimized. Indium(III) was quantitatively recovered, and the results agreed with those obtained using atomic absorption spectrophotometry, as confirmed by the f and t values. The sensor was also utilized as an indicator electrode for the potentiometric titration of fluoride in the presence of chloride, bromide, iodide and thiocyanate ions using indium(III) nitrate as the titrant.

• 오토저널
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• 제4권3호
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• pp.48-55
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• 1982

In the present the strain gauge type torque transducers consist of solid shaft as sensor, slip ring, brush and bridge circuit as detecting circuit. So in the case of measuring the low-capacity torque, the error caused by technical mistake in mounting stain gauge on the small sensor and especially by contact resistance between slip ring and brush takes place more than the large sensor. Therefore in this study constant voltage in order to have no effect of contact resistance is supplied to the hollow shaft and Schrobron Bridge Circuit. Through the experiment good results were obtained as follows; linearity, hysterisis and zero drift as static characteristics is within 1% F.S respectively. Also when loading, zero drift is about 2% F.S.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2002년도 춘계학술대회논문집
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• pp.549-553
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• 2002

Although the magnetostrictive sensors have received much attention in recent years. the investigations on the selection of a desired mode have not been reported. The purpose of this investigation is to present a technique to select a desired mode in a solid ferromagnetic cylinder using a non-contact magnetostrictive sensor. To achieve this goal. we propose new bias magnet configurations to select longitudinal and flexural waves. A few experimental results confirm the validity of the present investigation.

• 전기화학회지
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• 제21권4호
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• pp.80-87
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• 2018

웨어러블 디바이스, 전기자동차와 에너지저장시스템에 대한 전력 수요가 증가함에 따라 리튬이온 전지에 있어서 안전성은 가장 중요한 요소가 되었다. 이러한 문제를 해결하기 위해 가연성의 유기 액체전해질이 불연성의 고체전해질로 대체된 전고체 전지를 제조하려는 연구들이 진행되고 있다. 그러나 고체전해질은 자체 이온전도도가 상대적으로 낮고 전극/전해질 계면에서 높은 저항이 발생하므로 실질적인 활용에 제약이 있었다. 이에 유무기 소재로 구성된 복합전해질은 고체전해질의 단점을 극복할 수 있는 대안으로 떠오르고 있다. 본 연구에서는 PEO 전해질과 LLZO 고체전해질을 복합화하여 전해질을 제조하였고, LLZO 고체전해질 함량에 따라 결정성, 형상 및 전기화학 성능 분석을 진행하였다. 결과로부터 PEO 전해질 내에 LLZO 고체전해질의 최적 함량 및 균일한 분포가 전체 복합전해질의 이온전도도 향상에 중요한 요소임을 확인하였다.

• 한국정밀공학회지
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• 제26권2호
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• pp.86-93
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• 2009

Elastomeric O-rings have been the most common seals due to their excellent sealing capacity, and availability in costs and sizes. One of the critical applications of O-ring seals is solid rocket motor joint seal where the operating hot gas must be sealed during the combustion. This has long been a design issue to avoid the system failure. For laterally constrained, squeezed and pressurized condition, deformed shape of O-ring was measured by computed tomography method and CCD laser sensor, compared with numerical calculations. As clearance gap changes, sealing performance had been evaluated on peak contact stresses at top, bottom and side contact surfaces. As clearance gap increases, peak contact stresses and contact widths in top and side contact surfaces increase, and the asymmetry of stress distributions is promoted due to pressure increase. It is suggested that peak stress of bottom contact surface can be approximated by simple superposition of peak ones due to squeeze and pressure. Under pressurized condition, sealing performance is dependent on not peak stresses of bottom and side contact surfaces but that of top.

• 한국응용과학기술학회지
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• 제30권2호
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• pp.356-361
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• 2013

Lead (II) ion selective poly(aniline) solid contact electrode based on Tetramethylthiuram monosulfide ionophore as a sulfur containing sensing material is successfully developed. The electrode exhibits good linear response of 25.6 mV / decade (at $20{\pm}0.2^{\circ}C$, r2=0.995) within the concentration range of $1.0{\times}10^{-1}{\sim}4.0{\times}10^{-7}$ M Pb (II). The composition of this electrode was Ionophore : PVC : dioctylphthalate : potassiumtetrakis(4-chlorophenyl)borate : Oleic acid = 5.0 : 20.0 : 25.0 : 4.0 : 5.0. When we consider the results of using different composition electrodes based on only one potassiumtetrakis(4-chlorophenyl)borate or Oleic acid liphophlic additive, poly(aniline) solid contact electrode based on Tetramethylthiuram monosulfide ionophore with potassiumtetrakis(4-chlorophenyl)borate and Oleic acid liphophlic additive had the best result in response characteristics. The electrode shows good selectivity for lead (II) ion in comparison with alkali, alkaline earth, transition and heavy metal ions. This electrode is suitable for use with aqueous solutions of pH 3.0 ~ 7.0 and their standard deviation in the measured emf differences was ${\pm}2.94$ mV at Tris buffered lead sample solution of $1.0{\times}10^{-2}$ M and ${\pm}2.82$ mV at Tris buffered lead sample solution of $1.0{\times}10^{-3}$ M. Their stabilization time was less than 710 s. and response time was less than 16 s.

• 센서학회지
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• 제24권3호
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• pp.175-180
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• 2015

Worldwide, studies on intelligent vehicles for the convenience of drivers have been actively conducted as the number of cars has increased. However, vehicle convenience enabled by buttons lowers the concentration on driving and hence poses as a huge threat to the safety of the driver. The use of one of the convenient features, impaired driving auxiliary equipment, is limited because of its complex usage, and this device also hinders the front view of the driver. This paper proposes a vehicle-control device for controlling the convenient features as well as changes in speed and direction using gestures and motions of the driver. This device consists of an ultrasonic sensor for recognizing movement, an arduino for accepting signal control functions and servo and DC motors apply to various vehicle parts. Firstly, the vehicle-control device was designed using a 3D CAD program known as Solid-works based on the size of the steering wheel. Then, through simulations, a suitable length for minimizing the absorbent between ultrasonic sensors was confirmed using a program known as COMSOL Multiphysics. Finally, simulation results were verified through experiments, and the optimal size of the device was identified through the number of errors.

• 센서학회지
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• 제22권3호
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• pp.185-190
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• 2013

We report on direct finding of how the morphology (i.e. filopodia width) of $CD4^+$ T lymphocytes correlates with the size of the quartz nanohohole arrays (QNHAs, 140, 200, 270, and 550 nm in diameter) via scanning electron microscopy (SEM). This research exhibits that the filopodia of $CD4^+$ T-lymphocytes extended on the QNHA substrates were observed to increase in width by increasing the size of QNHA in diameter from 140 to 550 nm. This strong linear response ($R^2$=0.988, n = 6) in filopodia's width of surface-bound $CD4^+$ T-cells with topographical structures of QNHA can be explained by contact guidance between the cells and solid-state substrates. Furthermore, this research suggests that the protruded filopodia of surface-bound T-lymphocytes can be used as a biosensor for sensing the topographical information of the nano-patterned substrates.

• 대한임상검사과학회지
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• 제38권1호
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• pp.59-64
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• 2006

The pH-ISE(ion selective electrode) based on tribenzylamine as a hydrogen ion carrier was prepared and its electrochemical characterization was studied. It responded linearly to hydrogen ions in the range of pH 3.1 - pH 11.0 and the Nernstian slope showed 55.0 mV/pH (at $20{\pm}0.2^{\circ}C$), it also showed a fast response time of 8 sec. When it was directly applied to human blood(pH 6.0-8.5), we could get the same satisfying results. A good reproducibility and stability were shown with the precision of 2 mV (${\pm}0.1$). The pH-ISE based on tribenzylamine exhibited biocompatibility in clinical applications.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.480-480
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• 2011

양극산화(anodization)는 금속을 전기화학적으로 산화시켜 금속산화물로 만드는 기술로서 최근 다양한 크기의 나노 구조를 제조하는 기술로 각광받고 있으며, 이러한 기술에 의하여 얻어지는 anodic aluminum oxide(AAO)는 magnetic data storage, optoelectronic device, sensor에 적용될 수 있는 nano device 뿐만 아니라 nanostructure를 제조하기 위한 template 및 mask로써 최근 광범위 하게 연구되고 있다. 또한, AAO는 Al2O3의 단단한 구조를 가진 무기재료이므로 solid mask로써 다른 porous materials 보다 뛰어난 특성을 갖고 있다. 또한 electron-beam lithography 및 block co-polymer 에 의한 patterning 과 비교하여 매우 경제적이며, 재현성이 우수할 뿐만 아니라 대면적에서 나노 구조의 크기 및 형상제어가 비교적 쉽기 때문에 널리 사용되고 있다. 그러나, AAO 형성 시 생기게 되는 반구형 모양의 barrier layer는 물질(substance)과 기판과의 direct physical and electrical contact을 방해하기 때문에 해결해야 할 가장 큰 문제점 중 하나로 알려져 있다. 따라서 본 연구에서는 실리콘 기판위의 형성된 AAO의 barrier layer를 Cl/BCl3 gas mixture에서 Neutral Beam Etching (NBE)과 Ion Beam Etching (IBE) 로 각각 식각한 후 그 결과와 비교하였다. NBE와 IBE 모두 Cl2/BCl3 gas mixture에서 BCl3 gas의 첨가량이 60% 일 경우 etch rate이 가장 높게 나타났고, optical emission spectroscopy (OES)로 Cl2/BCl3 플라즈마 내의 Cl radical density와 X-ray photoelectron spectroscopy (XPS)로 AAO 표면 위를 관찰한 결과 휘발성 BOxCly의 형성이 AAO 식각에 크게 관여함을 확인 할 수 있었다. 또한, NBE와 IBE 실험한 다양한 Cl2/BCl3 gas mixture ratio 에서 AAO가 식각이 되지만, 이온빔의 경우 나노사이즈의 AAO pore의 charging에 의해 pore 아래쪽의 위치한 barrier layer를 어떤 식각조건에서도 제거하지 못하였다. 하지만, NBE에서는 BCl3-rich Cl2/BCl3 gas mixture인 식각조건에서 AAO pore에 휘발성 BOxCly를 형성하면서 barrier layer를 제거할 수 있었다.