• 한국재료학회지
• /
• 제14권5호
• /
• pp.368-373
• /
• 2004

To improve the conventional cathode-supported tubular solid oxide fuel cell (SOFC) from the viewpoint of low cell power density, expensive fabrication process and high operation temperature, the anode-supported tubular solid oxide fuel cell was investigated. The anode tube of Ni-8mol% $Y_2$O$_3$-stabilized $ZrO_2$ (8YSZ) was manufactured by extrusion process, and, the electrolyte of 8YSZ and the multi-layered cathode of $LaSrMnO_3$(LSM)ILSM-YSZ composite/$LaSrCoFeO_3$ were coated on the surface of the anode tube by slurry dip coating process, subsequently. Their cell performances were examined under gases of humidified hydrogen with 3% water and air. In the thermal cycle condition of heating and cooling rates with $3.33^{\circ}C$/min, the anode-supported tubular cell showed an excellent resistance as compared with the electrolyte-supported planar cell. The optimum hydrogen flow rate was evaluated and the air preheating increased the cell performance due to the increased gas temperature inside the cell. In long-term stability test, the single cell indicated a stable performance of 300 mA/$\textrm{cm}^2$ at 0.85 V for 255 hr.

• 한국세라믹학회지
• /
• 제52권5호
• /
• pp.308-314
• /
• 2015

The electrochemical performance and Cr poisoning behavior of $La_{1-x}Ba_xCo_{0.9}Fe_{0.1}O_{3-{\delta}}$ (LBCF, x = 0.3, 0.4, 0.5) and $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_{3-{\delta}}$ (LSCF) cathodes were investigated for solid oxide fuel cells (SOFCs). The polarization resistance of the LBCF/GDC/LBCF symmetrical cell was found to decrease with increasing Ba content (x value). This phenomenon might be associated with the high oxygen vacancy concentration in the LBCF sample, with x = 0.5. In addition, there was no chromium poisoning in the LBCF cathode. On the other hand, the polarization resistance of the LSCF cathode was found to significantly increase after exposure to gaseous chromium species; it appears that this result stemmed from the formation of $SrCrO_4$ phase. Therefore, it can be expected that LBCF can be a durable potential cathode material for intermediate-temperature solid oxide fuel cells (IT-SOFC).

• 신재생에너지
• /
• 제19권4호
• /
• pp.61-71
• /
• 2023

The necessity of energy utilization using livestock manure has been proposed with the decrease in domestic agricultural land. Livestock manure solid fuel has been investigated as a promising energy resource owing to its convenient storage and use in agricultural and livestock fields. Additional electricity production is possible through the integration of a biomass combustion boiler with the organic Rankine cycle (ORC). In this study, a mathematical system model of the cattle manure solid fuel boiler integrated with the ORC was developed to analyze the components' performance under variable operating conditions. A sensitivity analysis was conducted to confirm the electrical efficiency of the ORC turbine and the applicability of this system. The minimum required waste heat recovery rate was derived considering the system marginal price and levelized cost of electricity of the ORC. The simulation results showed that, in Korea, more than 77.98% of waste heat recovery and utilization in ORC turbines is required to achieve economic feasibility through ORC application.

• 한국연소학회지
• /
• 제9권3호
• /
• pp.1-9
• /
• 2004

This study is aimed to characterize the combustion behavior of solid fuel in the various types of the combustors: stoker, rotary kiln and fluidized bed type combustors. Three different types of reduced-scale combustors are introduced, and temperatures and flue gas compositions are measured for various fuel sizes, water contents, initial temperature, and air flow rates. In case of the rotary kiln combustor, effects of rotating speed of the combustor are also investigated. Mean carbon conversion time (MCCT) and flame propagation rate (FPR) are used for the quantitative analysis. It is revealed that the reaction rates of the fuel are significantly influenced by the fuel characteristics, type of the combustors and air flow rate. Major design parameters for each type of the combustors are summarized through the reduced-scaled model analysis.

• The Korean Journal of Ceramics
• /
• 제4권2호
• /
• pp.72-77
• /
• 1998

A defect model for UO$_2$ fuel containing soluble fission products was devised based on the defect structure of pure and doped uranias. Using the equilibrium between fuel solid-solution and fission-products and the material balance within the fuel, a tracing method to get the stoichiometry change of urania fuel with burnup was made. This tracing method was applied to high burnup urania fuel and DUPIC fuel. The oxygen potential of urania fuel turned out to increase slightly with burnup. The stoichiometry change was calculated to be negligible due to the buffering role f Mo. The oxygen potential of DUPIC fuel out to be sensitive to the initial chemical state of Mo in the fuel.

• 대한기계학회논문집B
• /
• 제36권4호
• /
• pp.439-447
• /
• 2012

출력 규모가 다른 세가지 상용 가스터빈들을 바탕으로 고체산화물 연료전지/가스터빈 하이브리드 시스템을 구성하고 성능을 비교하였다. 각 가스터빈을 사용할 때 연료전지와 가스터빈의 출력 비중 및 효율을 비교, 분석하였고 연료전지 설계온도를 변화시키면서 출력 비중의 변화와 시스템 효율 변화를 분석하였다. 수십 kW 급 소형 가스터빈을 사용한 하이브리드 시스템에서는 연료전지 온도가 변하여도 효율은 거의 변화가 없었지만 MW 급 및 수백 MW 급 등 중,대형 가스터빈을 사용하는 경우에는 연료 전지 작동온도가 높아질수록 시스템 효율이 높아짐을 확인하였다. 또한 연료전지로 공급되는 공기량을 조절하여 연료전지 출력 비중을 변화시키는 것에 대해서도 해석하였다.

• 한국수소및신에너지학회논문집
• /
• 제31권5호
• /
• pp.436-443
• /
• 2020

The performance prediction model of a solid oxide fuel cell stack has been developed using deep neural network technique, one of the machine learning methods. The machine learning has been received much interest in various fields, including energy system mo- deling. Using machine learning technique can save time and cost requried in developing an energy system model being compared to the conventional method, that is a combination of a mathematical modeling and an experimental validation. Results reveal that the mean average percent error, root mean square error, and coefficient of determination (R2) range 1.7515, 0.1342, 0.8597, repectively, in maximum. To improve the predictability of the model, the pre-processing is effective and interpolative machine learning and application is more accurate than the extrapolative cases.

• 한국수소및신에너지학회논문집
• /
• 제32권1호
• /
• pp.11-40
• /
• 2021

Solid oxide fuel cell (SOFC) has received significant attention recently because of its potential for the clean and efficient power generation. The current manufacturing processes for the SOFC components are somehow complex and expensive, therefore, new and innovative techniques are necessary to provide a great deal of cell performance and fabricability. Three-dimensional (3D) printing processes have the potential to provide a solution to all these problems. This study reviews the literature for manufacturing the SOFC components using 3D printing processes. The technical aspects for fabrication of SOFC components, 3D printing processes optimization and material characterizations are discussed. Comparison of the SOFC components fabricated by 3D printing to those manufactured by conventional ceramic processes is highlighted. Further advancements in the 3D printing of the SOFC components can be a step closer to the cost reduction and commercialization of this technology.

• 한국수소및신에너지학회논문집
• /
• 제33권5호
• /
• pp.557-565
• /
• 2022

The effect of flow configuration in ammonia-fed solid oxide fuel cell are investigated by using a three-dimensional numerical model. Typical flow configurations including co-flow and counter-flow are considered. The ammonia is directly fed into the stack without any external reforming process, resulting in an internal decomposition of NH3 in the anode electrode of the stack. The result showed that temperature profile in the case of counter-flow is more uniform than the co-flow configuration. The counter-flow cell, the temperature is highest at the middle of the channel while in the case of co-flow, the temperature is continuously increased and reached maximum value at the outlet area. This leads to a higher averaged current density in counter-flow compared to that of co-flow, about 5%.

• 한국원자력학회:학술대회논문집
• /
• 한국원자력학회 2004년도 추계학술발표회 발표논문집
• /
• pp.1028-1029
• /
• 2004