• 제목/요약/키워드: Solid type

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급속응고기술에 의한 p-type 25% $Bi_{2}Te_{3}+75% Sb_{2}Te_{3}$ 열간압축제의 열전특성 (Thermoelectric Properties of p-type 25% $Bi_{2}Te_{3}+75%Sb_{2}Te_{3}$ Materials Prepared by Rapid Solidification Process and Hot Pressing)

  • 김익수
    • 한국분말재료학회지
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    • 제3권4호
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    • pp.246-252
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    • 1996
  • $Bi_{2}Te_{3}-Sb_{2}Te_{3}$, $Bi_{2}Te_{3}-Bi_{2}Se_{3}$ solid solutions are of great interest as materials for thermoelectric energy conversion. One of the key technologies to ensure the efficiency of thermoelectric device is to obtain chemically homogeneous solid solutions. In this work, the new process with rapid solidification followed by hot pressing was investigated to produce homogeneous thermoelectric materials. Characteristics of the materials were examined with XRD, SEM, EPMA-line scan and bending test. Property variations of the materials were investigated as a function of variables, such as excess Te quantity and hot pressing temperature. Quenched ribbons are very brittle and consisted of homogeneous $Bi_{2}Te_{3}$, $Sb_{2}Te_{3}$ solid solutions. When the process parameters were optimized, the maximum figure of merit was 3.073$\times$$10^{-3}K^{-4}$. The bending strength of the material, hot pressed at 45$0^{\circ}C$, was 5.87 kgf/${mm}^2$.

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초소형 고체 추진제 추력기의 내탄도 성능연구 (Internal Ballistic Analysis of Solid Propellant Micro-Thruster)

  • 양준서;이종광;권세진
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2007년도 제29회 추계학술대회논문집
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    • pp.215-218
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    • 2007
  • 고체추진제를 사용한 초소형 추력기의 내탄도 모델링과 성능예측에 관하여 기술하였으며, 특히 초소형화 되면서 고려해야하는 연소실 내의 열손실을 고려하였다. 추진제는 일반 HTPB-AP계열을 선택하였으며, 계산 모델은 간단한 1차원 축대칭 end-burner 모델로 정하였다. 연소실내의 화염에 노출되는 표면과 체적에 대한 비율을 변화시키면서 연소실 가스 온도, 압력, 추력을 계산하여 본 논문의 경우 열손실효과로 약 3%의 총역적 감소가 있음을 확인하였다.

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1kW 평판형 SOFC 스택제작 및 성능평가 (Fabrication and Performance Test in Stacks up to 1kW Planar Solid Oxide Fuel Cell)

  • 조남웅;황순철;한상무;김영우;김승구;전재호;김도형;전중환
    • 신재생에너지
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    • 제3권3호
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    • pp.5-13
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    • 2007
  • Stacks of solid oxide fuel cell with 1kW max power performance were designed on planar type employing anode-supported cells and metallic interconnects. The stacks composed of 3-cells, 8-cells, and 16-cells were fabricated and tested in serials by using anode-supported cells purchased from Indec, and sealants/interconnects prepared at RIST. In the performance test of the final 16-cells stack, OCV was recorded to be 16.7V. The peak power and the power density showed 1 kW, $0.77W/cm^2$ at $820^{\circ}C$, respectively. In addition, the long-term degradation rate of the power exhibited 2.25 % during 500h at $750^{\circ}C$.

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유동 해석을 이용한 평판형 고체 산화물 연료전지의 성능 특성 분석 (II) - 비등온 모델 - (Performance Predictions of the Planar-type Solid Oxide Fuel Cell with Computational Flow Analysis (II) - Non-isothermal Model -)

  • 현희철;손정락;이준식;노승탁
    • 대한기계학회논문집B
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    • 제27권7호
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    • pp.963-972
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    • 2003
  • Performance characteristics of the planar-type solid oxide fuel cell (SOFC) are investigated by the analysis of flow fields coupled with heat and mass transfer phenomena in anode and cathode channels. For these purposes, performance analysis of the SOFC is conducted based on electrochemical reaction phenomena in electrodes and electrolyte coupled with flow fields in anode and cathode channels. In the present study, the isothermal model adopted in the previous paper prepared by the same authors is extended to the non-isothermal model by solving energy equation additionally with momentum and mass transfer equations using CFD technique. It is found that the difference between isothermal and non-isothermal models come from non-uniform temperature distribution along anode and cathode electrodes by solving energy equation in non-isothermal model. Non-uniform temperature distribution in non-isothermal model contributes to the increase of average temperature of the fuel cell and influences its performance characteristics.

Magnetic resonance images of ameloblastoma

  • Kim Jae-Duk;Kim Jin-Soo
    • Imaging Science in Dentistry
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    • 제35권4호
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    • pp.207-213
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    • 2005
  • Purpose: To classify and describe the characteristic features of MRI of some ameloblastoma variants. Materials and Methods: The MR images, CT images, and panoramic radiographs in 5 cases were retrospectively examined as follows. First, the contents of ameloblastomas were devided into two portions of either solid or cystic components on the basis of MR signal intensities. The signal intensity within the solid or cystic portions was classified as homogeneous or heterogeneous. Next, the characteristic internal feature of the lesion on T1W1 or T2WI was described. The signal intensities were classified into low, intermediate, slightly high, high, and strong high signal intensity. Results: Unicystic lesion showed homogeneous high signal intensity (SI) on T2W2 and the rim enhancement of the surrounding area including the mural nodule and the thick wall except the central portion on Gd- T1W1. Solid type revealed heterogeneous and high SI area with strong high SI area on T2W2. On Gd- T1W1, the area corresponding to the low signal spot on T1W1 and the strong high signal spot on T2W1 showed low SI. Hybrid type showed slightly enhanced capsular structures and low SI for the round bony septa and the areas connecting the mixed and cystic lesions on T2Wl and Gd-T1W1. Conclusion: MRI could easily assess the relationship between the mixed and cystic findings in ameloblastoma.

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Solid State NMR Study of PAZO-6 and Related Materials

  • Han, Oc Hee;Jin, Jung-Il;Kim, Jong-Sung;Yoon, Yong-Kook;Huh, Sung-Mu
    • 분석과학
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    • 제8권4호
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    • pp.493-498
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    • 1995
  • PAZO-6 is a new combined type liquid crystalline polymers (LCP) which has two types of mesogens combined non linearly. Ordering of branch mesogen azo group, in PAZO-6 is an important parameter to observe as well as the substitution effect on the backbone. The related small molecules sllch as monomers as well as the polymer itself are studied by solid state NMR techniques. Preliminary $^{13}C$ CP/MAS (cross polarization/ magic angle spinning) spectral results suggest that the azo groups in the monomers are not aligned with themselves. Azo groups in the monomers seem to be poorly ordered between well ordered p-phenylene terephthalate moeities. Similar disordering tendency of the azo group in PAZO-6 is deduced from the overall aromatic carbon peak positions which are not much different from those of the monomer.

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급속응고한 Al-Be합금의 미세조직 및 인장특성 (Microstructure and Tensile Property of Rapidly Solidified Al-Be alloy)

  • 이인우;박현호;김명호
    • 한국주조공학회지
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    • 제15권5호
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    • pp.459-468
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    • 1995
  • For high performance aerospace structures, the properties of highest priority are low density, high strength, and high stiffness(modulus of elasticity). Addition of beryllium decrease the density of the aluminum alloy and increase the strength and the stiffness of the alloy. However it is very difficult to produce the Al-Be alloy having useful engineering properties by conventional ingot casting, because of the extremely limited solid solubility of beryllium in aluminum. So, rapid solidification processing is necessary to obtain extended solid solubility. In this study, rapidly solidified Al-6 at% Be alloy were prepared by twin roll melt spinning process and single roll melt spinning process. Twin roll melt spun ribbons were extruded at $450^{\circ}C$ with reduction in area of 25 : 1 after vacuum hot pressing at $550^{\circ}C and 375^{\circ}C$. The microstructure of melt spun ribbon exhibited a refined cellular microstructure with dispersed Be particles. As advance velocity of liquid/solid interface increase, the morphology of Be particle vary from rod-like type to spherical type and the crystal structure of Be particle from HCP to BCC. These microstructural characteristics of rapidly solidified Al-6at.%Be alloy were described on the basis of metastable phase diagram proposed by Perepezko and Boettinger. The extruded ribbon consisted of recrystallized grains dispersed with Be particles and exhibited improved tensile property compared with that of extruded ingot.

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고체산화물 연료전지 스택 열화 방지를 위한 전해질 기술 (Bi-layer Electrolyte for Preventing Solid Oxide Fuel Cell Stack Degradation)

  • 박미영;배홍열;임형태
    • 한국세라믹학회지
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    • 제51권4호
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    • pp.289-294
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    • 2014
  • The stability of a solid oxide fuel cell (SOFC) stack is strongly dependent on the magnitude and profile of the internal chemical potential of the solid electrolyte. If the internal partial pressure is too high, the electrolyte can be delaminated from the electrodes. The formation of high internal pressure is attributed to a negative cell voltage, and this phenomenon can occur in a bad cell (with higher resistance) in a stack. This fact implies that the internal chemical potential plays an important role in determining the lifetime of a stack. In the present work, we fabricate planar type anode-supported cells ($25cm^2$) with a bi-layer electrolyte (with locally increased electronic conduction at the anode side) to prevent high internal pressure, and we test the fabricated cells under a negative voltage condition. The results indicate that the addition of electronic conduction in the electrolyte can effectively depress internal pressure and improve the cell stability.

혼성방파제의 무공 및 유공 케이슨의 수리특성에 관한 실험 (An Experimental Investigation for Hydraulic Characteristics of Solid and Perforated-wall Caissons of a Mixed Type Breakwater)

  • 서경덕;오영민;전인식;이달수
    • 한국해안해양공학회지
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    • 제4권4호
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    • pp.243-249
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    • 1992
  • 혼성방파제의 무공 및 유공 케이슨의 수리특성을 비교하기 위하여 파고 및 주기가 다른 여러 규칙파를 대상으로 수리실험을 실시하였다. 반사율, 전달률, 케이슨 전면에서의 쳐올림 높이 등 수리특성 면에서 모두 유공케이슨이 무공케이슨보다 유리한 것으로 나타났으며, 본 실험 결과가 기존의 이론식 또는 경험식들과 대체로 잘 일치함을 보였다. 특히, 유공케이슨의 반사율은 유수실 내에서의 공진현상과 밀접한 관계가 있어서 유수실의 폭이 유수실 내에서의 파장의 약 1/4 정도가 될 때 반사율이 최소가 됨을 알 수 있었다.

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고상 확산 법에 의한 P-type Zn 확산과 $GaAs_{0.60}P_{0.40}$의 전계발광 특성 (p-type Zn Diffusion using by Solid State Method of $GaAs_{0.60}P_{0.40}$ and the Properties of Electroluminescence)

  • 표진구;임근영;소병문;박춘배
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 추계학술대회 논문집 Vol.16
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    • pp.481-485
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    • 2003
  • To diffuse Zn at solid-state, the $SiO_2/ZnO/SiO_2$ wafers was made by PECVD and RF Spotter. Thicknesses of bottom $SiO_2$ and cap $SiO_2$ was about $500{\AA}$ and about $3500{\AA}$. First test was Diffusion temperatures were $760^{\circ}C$, $780^{\circ}C$, and $800^{\circ}C$, and diffusion times were 1, 2, 3, 4, 5, and 6 hr and 2nd test was Diffusion temperatures were $760^{\circ}C$, $720^{\circ}C$, and $680^{\circ}C$, and diffusion times were 1, 2, 3, 4, 5, and 6 hr. LED chips were fabricated by the diffused wafers at Fab. The peak wavelength of all chips showed about $625{\sim}650\;nm$ and red color Main reason for Iv change was by diffusion temperature not diffusion time. The lower temperature was the higher Iv. We thick that these properties is because of the very high diffusion temperature.

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